Fuel cell separator and fuel cell stack and reactant gas control method thereof

Patent metadata

Field	Value
Publication number	US-9343756-B2
Application number	US-6708607-A
Country	US
Kind code	B2
Filing date	May 23, 2007
Priority date	Aug 24, 2006
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

A fuel cell separator, a fuel cell stack having the fuel cell separator, and a reactant gas control method of the fuel cell stack are provided. That is, even when the fuel cell stack operates under the low load operation condition, a reactant gas is supplied to the reactant gas passages of the fuel cell separator, and thus, the length of the passage can be shortened by 50% as compared with the prior art having only one reactant gas passage. Therefore, the reactant gas can be effectively supplied without experiencing pressure loss. Further, in the high load operation of the fuel cell stack, the reactant gas is introduced into the first reactant gas passage of the fuel cell separator and utilized in half of the whole electrode area. Subsequently, the reactant gas is introduced into the second reactant gas passage and utilized in the remaining half of the electrode area. The flow rate of the reactant gas flowing along the passage channels is increased by two times, even when the reactant gas utilizing rate is identical as compared with the reactant gas flow in the low load operation. As a result, the moisture existing in the passage channels can be more effectively discharged and the flooding phenomenon occurring in the high load operation can be prevented. By controlling the reactant gas supply in accordance with an operation condition of the fuel cell stack without experiencing pressure loss and deterioration of the utilizing rate, the flooding phenomenon and concentration polarization phenomenon that occur in the fuel cell stack can be prevented.

First claim

The invention claimed is:

1. A fuel cell stack comprising:
a plurality of unit cells stacked with one another, each unit cell including a membrane-electrode assembly and a pair of separation plates; and
end plates that are located on opposite ends of a body formed by the stacked plurality of unit cells, the end plates including a first end plate coupled to one end of the body and a second end plate coupled to the other end of the body,
wherein the pair of separation plates of each unit cell form a fuel cell separator, the fuel cell separator comprising;
reactant gas inlet through holes for introducing reactant gases; and
reactant gas outlet through holes for discharging the reactant gases,
wherein the reactant gas inlet through holes and the reactant gas outlet through holes are alternately formed along a first side edge of the fuel cell separator and one or more passages are formed on at least one of opposite surfaces of the fuel cell separator to connect the reactant gas inlet through holes to the respective reactant gas outlet through holes,
wherein the end plates are provided with:
reactant gas inlet ports installed on the first end plate for supplying the reactant gases and corresponding to the reactant gas inlet through holes;
reactant gas outlet ports installed on the first end plate for discharging residual reactant gases and reaction by-product and corresponding to the reactant gas outlet through holes; and
valves which are installed on pipes connecting the reactant gas inlet ports to the reactant gas outlet ports to control reactant gas flow, the pipes including a first pipe and a second pipe which are installed on the first end plate and a third pipe which is installed on the second end plate,
wherein the reactant gas inlet ports and the reactant gas outlet ports are alternately formed on the first end plate,
wherein one of the reactant gases is an oxidizing gas,
wherein the reactant gas inlet ports include:
first and second oxidizing agent inlet ports installed on the first end plate for supplying the oxidizing gas; and
a third oxidizing agent inlet port installed on the second end plate and sharing a first manifold with the second oxidizing agent inlet port,
wherein the reactant gas outlet ports include:
first and second oxidizing agent outlet ports installed on the first end plate for discharging residual oxidizing gas and the reaction by-product; and
a third oxidizing agent outlet port installed on the second end plate and sharing a second manifold with the first oxidizing agent outlet port,
wherein the valves include:
an oxidizing agent inlet valve installed on the first pipe interconnecting the first and second oxidizing agent inlet ports to control flow of the oxidizing gas;
an oxidizing agent outlet valve installed on the second pipe interconnecting the first and second oxidizing agent outlet ports to control flow of the oxidizing gas; and
an oxidizing agent intermediate valve installed on the third pipe interconnecting the third oxidizing agent inlet port and the third oxidizing agent outlet port to control oxidizing gas flow, and
wherein the oxidizing agent intermediate valve is structured to be opened when the oxidizing agent inlet valve and the oxidizing agent outlet valve are closed in a high load operation condition,
wherein the third oxidizing agent outlet port and the first oxidizing agent inlet port are fluidly connected through the second manifold, and the third oxidizing agent inlet port and the second oxidizing agent inlet port are fluidly connected through the first manifold, and
wherein the first oxidizing agent inlet port, the second oxidizing agent inlet port, the third oxidizing agent outlet, and the third oxidizing agent inlet port are structured such that the oxidizing gas is supplied through the first oxidizing agent inlet port and discharged through the third oxidizing agent outlet port, and then the discharged oxidizing gas is supplied through the third oxidizing agent inlet port and discharged through the second oxidizing agent outlet port in the high load operation condition.

2. The fuel cell stack of claim 1 , wherein:
one of the reactant gases is a fuel gas;
the reactant gas inlet ports are first and second fuel inlet ports for supplying the fuel gas; and
the reactant gas outlet ports are first and second fuel outlet ports for discharging residual fuel gas.

3. The fuel cell stack of claim 2 , wherein one of the valves is a fuel inlet valve, which is installed on a pipe interconnecting the first and second fuel inlet ports to control flow of the fuel gas.

4. The fuel cell stack of claim 2 , wherein one of the valves is a fuel outlet valve, which is installed on a pipe interconnecting the first and second fuel outlet ports to control flow of the fuel gas.

5. The fuel cell stack of claim 2 , wherein:
the reactant gas inlet ports further include a third fuel inlet port sharing a manifold with the second fuel inlet port; and
the reactant gas outlet ports further include a third fuel outlet port sharing a manifold with the first fuel outlet port.

6. The fuel cell stack of claim 5 , wherein the valves further include a fuel intermediate valve, which is installed on a pipe interconnecting the third fuel inlet and outlet ports to control fuel gas flow.

7. The fuel cell stack of claim 1 , wherein the oxidizing agent intermediate valve is configured and structured to be opened in the high load operation condition, such that the oxidizing gas supplied through only the first oxidizing agent inlet port is not output via the first oxidizing outlet port, but passes through the third oxidizing agent outlet port, the oxidizing agent intermediate valve, and the third oxidizing agent inlet port, before finally being discharged through the second oxidizing agent outlet port in the high load operation condition.

8. The fuel cell stack of claim 1 , wherein the oxidizing agent inlet valve and the oxidizing agent outlet valves are configured and structured to be opened, and the oxidizing agent intermediate valve is configured and structured to be closed in a low load operation condition.

9. The fuel cell stack of claim 8 , wherein the oxidizing gas is uniformly supplied to the first and second oxidizing agent inlet ports in the low load operation condition such that the oxidizing gas is discharged through the first and second oxidizing agent outlet ports in the low load operation condition.

Assignees

• Oh Sung-Jin
• Lee Kyoung-Hwang
• Baek Seung-Ho
• Lee Sung-Hoon
• Park Il-Tae
• Hong Byung-Sun
• Shinn Mee-Nam
• Doosan Corp

Inventors

• Oh Sung-Jin
• Lee Kyoung-Hwang
• Baek Seung-Ho
• Lee Sung-Hoon
• Park Il-Tae
• Hong Byung-Sun
• Shinn Mee-Nam

Classifications

• H01M8/04029

  Heat exchange using liquids · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M8/04201 Primary

  Reactant storage and supply, e.g. means for feeding, pipes · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/2485

  Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack · CPC title