Lithium compensation for full cell operation

Patent metadata

Field	Value
Publication number	US-9343736-B2
Application number	US-201414231058-A
Country	US
Kind code	B2
Filing date	Mar 31, 2014
Priority date	Mar 31, 2014
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

Disclosed herein are embodiments of a lithium-ion battery system comprising an anode, an anode current collector, and a layer of lithium metal in contact with the current collector, but not in contact with the anode. The lithium compensation layer dissolves into the electrolyte to compensate for the loss of lithium ions during usage of the full cell. The specific placement of the lithium compensation layer, such that there is no direct physical contact between the lithium compensation layer and the anode, provides certain advantages.

First claim

We claim:

1. A device, comprising:
a lithium battery full cell, comprising
a cathode;
a separator;
an anode current collector having a first surface and a second surface;
an anode located on the second surface of the anode current collector;
a lithium compensation layer located on the first surface of the anode current collector; and
wherein there is an absence of direct physical contact between the anode and the lithium compensation layer.

2. The device of claim 1 , wherein the lithium compensation layer is in direct physical contact with the first surface of the anode current collector.

3. The device of claim 1 , wherein the anode is in direct physical contact with the second surface of the anode current collector.

4. The device of claim 1 , wherein there is an absence of direct physical contact between the lithium compensation layer and the second surface of the anode current collector.

5. The device of claim 1 , wherein the lithium compensation layer comprises lithium foil.

6. The device of claim 1 , wherein the lithium compensation layer is deposited by a method selected from plating, chemical solution deposition, spin coating, chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition, thermal evaporation, electron beam evaporation, molecular beam epitaxy, sputtering (DC, rf, magnetron), pulsed laser deposition, cathode arc deposition, electrohydrodynamic deposition, atmospheric pressure CVD (APCVD), low-pressure CVD (LPCVD), ultrahigh vacuum CVD (UHVCVD), microwave assisted CVD (MACVD), plasma-enhanced CVD (PECVD) or metal-organic CVD (MOCVD), closed space sublimation (CSS), closed spaced vapor transport (CSVT), liquid deposition, ink-jet deposition, slot die coating, capillary coating, or a combination thereof.

7. The device of claim 1 , wherein the anode comprises graphite, Li 4 Ti 5 O 12 , silicon, tin, tin alloy, silicon alloy, silicon oxide, lithium alloy, tin oxide, zinc oxide, iron oxide, cobalt oxide, nickel oxide, germanium, graphene, activated carbon, carbon nanotubes, silicon/boron carbide/graphite composite, or combinations thereof.

8. The device of claim 1 , wherein the lithium compensation layer has a preselected mass value selected to substantially compensate for lithium ion loss during use of the device.

9. The device of claim 1 , wherein the cathode comprises a high-voltage cathode.

10. The device of claim 9 , wherein the high-voltage cathode comprises LiNiO 2 , LiNi 1/3 Co 1/3 Mn 1/3 O 2 , LiNi 0.5 Mn 1.5 O 4 , LiNi 0.5-x Cr x Mn 1.5 O 4 , LiNi 0.5-x Co x Mn 1.5 O 4 , LiNi 0.5-x Al x Mn 1.5 O 4 , LiNi 0.5-x Fe x Mn 1.5 O 4 , LiNi 0.5 Mn 1.5 O 4-z F z or combinations thereof, x is from greater than 0 to less than 0.5, and z is from 0 to less than 4.

11. The device of claim 1 , wherein the anode comprises a high-capacity silicon anode.

12. A device, comprising:
a lithium battery full cell, comprising
a high-voltage cathode;
a separator;
an anode current collector having a first surface and a second surface;
a lithium compensation layer in direct physical contact with the first surface of the anode current collector; and
an anode in direct physical contact with the second surface of the anode current collector, and not in direct physical contact with the lithium compensation layer.

13. The device of claim 12 , wherein the high-voltage cathode comprises LiNiO 2 , LiNi 1/3 Co 1/3 Mn 1/3 O 2 , LiNi 0.5 Mn 1.5 O 4 , LiNi 0.5-x Cr x Mn 1.5 O 4 , LiNi 0.5-x Co x Mn 1.5 O 4 , LiNi 0.5-x Al x Mn 1.5 O 4 , LiNi 0.5-x Fe x Mn 1.5 O 4 , LiNi 0.5 Mn 1.5 O 4-z F z or combinations thereof, x is from greater than 0 to less than 0.5, and z is from 0 to less than 4.

14. The device of claim 12 , wherein the lithium compensation layer comprises lithium foil.

15. The device of claim 12 , wherein the lithium compensation layer is deposited by a method selected from plating, chemical solution deposition, spin coating, chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition, thermal evaporation, electron beam evaporation, molecular beam epitaxy, sputtering (DC, rf, magnetron), pulsed laser deposition, cathode arc deposition, electrohydrodynamic deposition, atmospheric pressure CVD (APCVD), low-pressure CVD (LPCVD), ultrahigh vacuum CVD (UHVCVD), microwave assisted CVD (MACVD), plasma-enhanced CVD (PECVD) or metal-organic CVD (MOCVD), closed space sublimation (CSS), closed spaced vapor transport (CSVT), liquid deposition, ink-jet deposition, slot die coating, capillary coating, or a combination thereof.

16. A device, comprising:
a lithium battery comprising
an anode current collector having a first surface and a second surface;
a lithium compensation layer in direct physical contact with the first surface of the anode current collector; and
an anode in direct physical contact with the second surface of the anode current collector, and not in direct physical contact with the lithium compensation layer.

17. The device of claim 16 , wherein the lithium compensation layer comprises lithium foil.

18. The device of claim 16 , wherein the lithium compensation layer is deposited by a method selected from plating, chemical solution deposition, spin coating, chemical vapor deposition (CVD), physical vapor deposition (PVD), atomic layer deposition, thermal evaporation, electron beam evaporation, molecular beam epitaxy, sputtering (DC, rf, magnetron), pulsed laser deposition, cathode arc deposition, electrohydrodynamic deposition, atmospheric pressure CVD (APCVD), low-pressure CVD (LPCVD), ultrahigh vacuum CVD (UHVCVD), microwave assisted CVD (MACVD), plasma-enhanced CVD (PECVD) or metal-organic CVD (MOCVD), closed space sublimation (CSS), closed spaced vapor transport (CSVT), liquid deposition, ink-jet deposition, slot die coating, capillary coating, or a combination thereof.

Assignees

• Battelle Memorial Institute

Inventors

• Xiao Jie
• Zheng Jianming
• Chen Xilin
• Lu Dongping
• Liu Jun
• Zhang Jiguang

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/04

  Processes of manufacture in general · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M2004/027

  Negative electrodes · CPC title