Anode for lithium metal battery, and electrochemical device comprising same
US-12176528-B2 · Dec 24, 2024 · US
US9343712B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9343712-B2 |
| Application number | US-201314104863-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 12, 2013 |
| Priority date | Apr 10, 2013 |
| Publication date | May 17, 2016 |
| Grant date | May 17, 2016 |
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A secondary battery is disclosed. In one aspect, the battery includes an electrode assembly including i) a positive electrode plate on which a positive active material is formed, ii) a negative electrode plate on which a negative active material is formed, and iii) a separator separating the positive and negative electrode plates. The battery also includes a can accommodating the electrode assembly, wherein the can has an inner surface facing the electrode assembly, an inner active material layer formed on the inner surface of the can and a securing layer covering the inner active material layer.
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What is claimed is: 1. A secondary battery, comprising: an electrode assembly comprising i) a positive electrode plate on which a positive active material is formed, ii) a negative electrode plate on which a negative active material is formed, and iii) a separator separating the positive and negative electrode plates; a can accommodating the electrode assembly, wherein the can has an inner surface facing the electrode assembly; an inner active material layer formed on the inner surface of the can; and a securing layer covering the inner active material layer. 2. The battery of claim 1 , wherein the securing layer is formed of a material comprising a ceramic. 3. The battery of claim 1 , wherein the inner active material layer is formed of a material substantially similar to one of the positive and negative active materials. 4. The battery of claim 1 , wherein the inner active material layer has a substantially uniform thickness. 5. The battery of claim 1 , wherein the thickness of the securing layer is in the range from about 2 μm to about 6 μm. 6. The battery of claim 1 , wherein the surface of the inner active material layer is non-planar. 7. The battery of claim 1 , wherein the surface of the inner active material layer has a wave shape. 8. The battery of claim 1 , wherein the inner active material layer is \ discontinuous. 9. The battery of claim 1 , wherein the securing layer is formed of a material comprising at least one of a metal oxide, a metal nitride, a metal hydroxide, and a metal phosphide. 10. The battery of claim 9 , wherein each of the metal oxide, the metal nitride, the metal hydroxide and the metal phosphide comprises at least one of Al, Ti, Cr, Zr, Ca, Si, and Mg. 11. The battery of claim 1 , wherein the separator is formed on the outermost surface of the electrode assembly. 12. The battery of claim 1 , wherein the securing layer is formed of a material comprising a heat resistant resin. 13. The battery of claim 12 , wherein the heat resistant resin comprises at least one of the following: aramid resin, polyamideimide resin and polyimide resin. 14. The battery of claim 12 , wherein the ratio of the heat resistant resin and the remaining component of the securing layer is in the range from about 50 wt %:about 50 wt. % to about 90 wt. %:about 10 wt. %. 15. The battery of claim 12 , wherein the ratio of the heat resistant resin and the remaining component of the layer is in the range from about 60 wt. %:about 40 wt. % to about 80 wt. %:about 20 wt. %. 16. A secondary battery, comprising: an electrode assembly having a first portion which is coated with a positive active material and a second portion which is coated with a negative active material, and wherein the first portion is separated from the second portion; a can accommodating the electrode assembly, wherein the can has an inner surface facing the electrode assembly, and wherein the inner surface is coated with one of the positive and negative active materials; and a securing layer at least partially covering the coated inner surface of the can. 17. The battery of claim 16 , wherein the securing layer has a surface contacting the inner surface of the can, and wherein a plurality of concave portions and a plurality of convex portions are alternately formed on the surface of the securing layer. 18. A secondary battery, comprising: a can accommodating an electrode assembly, wherein the can has an inner surface facing the electrode assembly, and wherein the can has an electrical polarity, wherein the inner surface of the can is coated with a positive active material or a negative active material; and a securing layer covering the inner coated layer. 19. The battery of claim 18 , wherein the securing layer has a surface contacting the inner surface of the can, and wherein a plurality of concave portions and a plurality of convex portions are alternately formed on the surface of the securing layer. 20. The battery of claim 18 , wherein the inner positive or negative active material layer is discontinuous.
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