Metal organic framework-derived carbon aerogel, preparation method thereof and application in lithium ion batteries
US-12183924-B2 · Dec 31, 2024 · US
US9343241B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9343241-B2 |
| Application number | US-201213569411-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 8, 2012 |
| Priority date | Aug 26, 2011 |
| Publication date | May 17, 2016 |
| Grant date | May 17, 2016 |
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A power storage device with high output is provided, in which the specific surface area is increased while keeping the easy-to-handle particle size of its active material. The power storage device includes a positive electrode including a positive electrode current collector and a positive electrode active material layer, a negative electrode including a negative electrode current collector and a negative electrode active material layer, and an electrolyte. The negative electrode active material layer includes a negative electrode active material having a plurality of graphite particles. Each of the graphite particles consists of graphite layers that are overlapped with each other with a gap of 1 nm to 10 nm therebetween. It is preferable that the grain diameter of the particle be 1 μm to 50 μm. Further, the specific surface area of the particles is 20 m 2 /g to 200 m 2 /g.
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The invention claimed is: 1. An electrode comprising: a current collector; and an active material layer, wherein the active material layer comprises an active material exclusively of a plurality of graphite particles, wherein each graphite particle of the plurality of graphite particles consists of a plurality of graphite layers overlapping with each other with a gap between each respective graphite layer, wherein the gap is 1 nm to 10 nm, wherein a grain diameter of the particle is 1 μm to 50 μm, and wherein a specific surface area of the particle is 20 m 2 /g to 200 m 2 /g. 2. A power storage device comprising: a positive electrode comprising a positive electrode current collector and a positive electrode active material layer; a negative electrode comprising a negative electrode current collector and a negative electrode active material layer; and an electrolyte, wherein the negative electrode active material layer comprises an active material exclusively of a plurality of graphite particles, wherein each graphite particle of the plurality of graphite particles consists of a plurality of graphite layers overlapping with each other with a gap between each respective graphite layer, wherein the gap is 1 nm to 10 nm wherein a grain diameter of the particle is 1 μm to 50 μm, and wherein a specific surface area of the particle is 20 m 2 /g to 200 m 2 /g. 3. The power storage device according to claim 2 , wherein the electrolyte is in contact with the gap. 4. The power storage device according to claim 2 , wherein the power storage device is a lithium ion capacitor. 5. The power storage device according to claim 2 , wherein the positive electrode active material layer comprises a graphite particle, and wherein the graphite particle comprises a plurality of graphite layers overlapping with each other with a gap between each respective graphite layer. 6. A power storage device comprising: a positive electrode comprising a positive electrode current collector and a positive electrode active material layer; a negative electrode comprising a negative electrode current collector and a negative electrode active material layer; and an electrolyte, wherein the positive electrode active material layer comprises an active material exclusively of a plurality of graphite particles, wherein each graphite particle of the plurality of graphite particles consists of a plurality of graphite layers overlapping with each other with a gap between each respective graphite layer, wherein the gap is 1 nm to 10 nm, wherein a grain diameter of the particle is 1 μm to 50 μm, and wherein a specific surface area of the particle is 20 m 2 /g to 200 m 2 /g. 7. The power storage device according to claim 6 , wherein the electrolyte is in contact with the gap. 8. The power storage device according to claim 6 , wherein the power storage device is a lithium ion capacitor. 9. The electrode according to claim 1 , wherein the gap is formed using zinc chloride. 10. The electrode according to claim 1 , wherein the gap includes space, and wherein a transition metal chloride is removed from the space. 11. The power storage device according to claim 2 , wherein the gap is formed using zinc chloride. 12. The power storage device according to claim 2 , wherein the gap includes space, and wherein a transition metal chloride is removed from the space. 13. The power storage device according to claim 6 , wherein the gap is formed using zinc chloride. 14. The power storage device according to claim 6 , wherein the gap includes space, and wherein a transition metal chloride is removed from the space.
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