Ammonia-engine system

Patent metadata

Field	Value
Publication number	US-9341111-B2
Application number	US-200913130201-A
Country	US
Kind code	B2
Filing date	Nov 19, 2009
Priority date	Nov 19, 2008
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

An ammonia-engine system is capable of supplying an ammonia cracking catalyst with a temperature necessary to promote a reaction even during low load operation in which a temperature of an exhaust gas from an ammonia engine is lower than an operating temperature of the ammonia cracking catalyst. In an ammonia-engine system provided with an ammonia engine ( 2 ) using ammonia as fuel and an ammonia cracking device ( 5 ) including an ammonia cracking catalyst that cracks ammonia and cracking ammonia to produce hydrogen, an ammonia oxidizing device ( 4 ) is provided between the ammonia engine ( 2 ) and the ammonia cracking device ( 5 ).

First claim

The invention claimed is:

1. An ammonia-engine system, comprising:
an ammonia engine employing ammonia supplied from a NH 3 tank directly used as fuel;
an ammonia cracking device comprising an ammonia cracking catalyst that cracks ammonia from the NH 3 tank to produce hydrogen,
wherein the temperature of the ammonia supplied therein and the ammonia cracking catalyst increase due to heat exchange between the exhaust gas from the ammonia engine and the ammonia,
wherein the hydrogen-containing ammonia-cracked gas produced in the ammonia cracking device is supplied to the ammonia engine as a combustion improver for the ammonia engine; and

an ammonia oxidizing device, provided between the ammonia engine and the exhaust gas introduction side of the ammonia cracking device, to provide heat to the ammonia cracking device at start-up of the ammonia engine by oxidizing ammonia according to the following formula:
NH 3 +3/4O 2 →1/2N 2 +3/2H 2 O  (1),

wherein the heat provided by the ammonia is sufficient to heat the ammonia cracking catalyst in the ammonia cracking device to a temperature of 290° C. or greater.

2. The system of claim 1 , wherein:
the ammonia oxidizing device comprises a platinum-supported catalyst.

3. The system of claim 2 , wherein:
the platinum-supported catalyst has a monolithic shape.

4. The system of claim 1 , further comprising:
a heater, provided between an outlet of the ammonia engine and an inlet of the ammonia oxidizing device, wherein the heater heats ammonia only when an inlet temperature of the ammonia oxidizing device is 150° C. or below.

5. The system of claim 1 , wherein:
the ammonia cracking device has a structure of a plate heat exchanger.

6. The system of claim 5 , wherein:
the ammonia cracking catalyst is filled in the ammonia cracking device on an ammonia supply side or the catalyst is coated on a surface of a material on the ammonia supply side of the ammonia cracking device.

7. The system of claim 6 , wherein:
the ammonia cracking catalyst comprises a catalyst supporting at least one selected from the group consisting of ruthenium, rhodium, nickel, and iron.

8. The system of claim 1 , wherein:
an inlet temperature on an exhaust gas introduction side of the ammonia cracking device is maintained at 290° C. or above.

9. The system of claim 1 , wherein:
an inlet temperature of the ammonia oxidizing device is maintained at 150° C. or above.

10. The system of claim 1 , wherein:
an ammonia gas is further added to the exhaust gas from the ammonia engine in a case where an inlet temperature on an exhaust gas introduction side of the ammonia cracking device is 300° C. or below.

11. The system of claim 10 , wherein:
the ammonia gas is added also in a case where an ammonia concentration of the exhaust gas from the ammonia engine is 3% or less.

12. The system of claim 4 , wherein:
ammonia to be supplied to the ammonia oxidizing device is heated by a heater only in a case where the inlet temperature of the ammonia oxidizing device is 150° C. or below.

13. The system of claim 2 , further comprising:
a heater, provided between an outlet of the ammonia engine and the ammonia oxidizing device.

14. The system of claim 3 , further comprising:
a heater, provided between an outlet of the ammonia engine and the ammonia oxidizing device.

15. The system of claim 2 , wherein, the ammonia cracking device has a structure of a plate heat exchanger.

16. The system of claim 3 , wherein the ammonia cracking device has a structure of a plate heat exchanger.

17. The system of claim 4 , wherein, the ammonia cracking device has a structure of a plate heat exchanger.

18. The system of claim 15 , wherein the ammonia cracking catalyst is filled in the ammonia cracking device on an ammonia supply side or the catalyst is coated on a surface of a material on the ammonia supply side of the ammonia cracking device.

19. The system of claim 16 , wherein the ammonia cracking catalyst is filled in the ammonia cracking device on an ammonia supply side or the catalyst is coated on a surface of a material on the ammonia supply side of the ammonia cracking device.

20. The system of claim 17 , wherein the ammonia cracking catalyst is filled in the ammonia cracking device on an ammonia supply side or the catalyst is coated on a surface of a material on the ammonia supply side of the ammonia cracking device.

21. The system of claim 1 , wherein the ammonia oxidizing device is downstream of the ammonia engine.

Assignees

• Hikazudani Susumu
• Inazumi Chikashi
• Nakanishi Haruyuki
• Nakamura Norihiko
• Arikawa Hidekazu
• Hitachi Shipbuilding Eng Co
• Toyota Motor Co Ltd

Inventors

• Hikazudani Susumu
• Inazumi Chikashi
• Nakanishi Haruyuki
• Nakamura Norihiko
• Arikawa Hidekazu

Classifications

• B01J23/46

  Ruthenium, rhodium, osmium or iridium · CPC title

• B01J23/58

  with alkali- or alkaline earth metals · CPC title

• B01J23/42

  Platinum · CPC title

• F02B43/10 Primary

  Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen · CPC title

• F02M25/12

  the apparatus having means for generating such gases (using rays and simultaneously generating ozone F02M27/06) · CPC title