Solid-state structures with volatile sintering aids, and methods for fabrication and use thereof
US-2024429439-A1 · Dec 26, 2024 · US
US9340867B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9340867-B2 |
| Application number | US-201213979682-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 19, 2012 |
| Priority date | Feb 4, 2011 |
| Publication date | May 17, 2016 |
| Grant date | May 17, 2016 |
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The present invention discloses a tablet for ion plating, which is capable of providing high speed film formation of a transparent conductive film suitable for a solar cell, and continuing film formation without generating crack, fracture or splash; and an oxide sintered body for obtaining the same. The oxide sintered body etc. comprising indium oxide as a main component, and tungsten as an additive element, content of tungsten being 0.001 to 0.15, as an atomic ratio of W/(In+W), characterized in that said oxide sintered body is mainly composed of a crystal grain (A) composed of the indium oxide phase with a bixbyite type structure, where tungsten does not make a solid solution, and a crystal grain (B) composed of the indium oxide phase with a bixbyite type structure, where tungsten does not make a solid solution, and has a density of 3.4 to 5.5 g/cm 3 .
Opening claim text (preview).
The invention claimed is: 1. An oxide sintered body comprising an indium oxide as a main component, and tungsten as an additive element, content of tungsten being 0.001 to 0.15 as an atomic ratio of W/(In+W), characterized in that said oxide sintered body is mainly composed of a crystal grain (A) composed of the indium oxide phase with a bixbyite type structure, where tungsten does not make a solid solution, and a crystal grain (B) composed of the indium oxide phase with a bixbyite type structure, where tungsten is present as a solid solution, and has a density of 3.4 to 5.5 g/cm 3 . 2. The oxide sintered body according to claim 1 , characterized by further comprising, as the additive element, one or more kinds of a metal element (M) selected from the group consisting of titanium, zirconium, hafnium, and molybdenum, wherein a total content of tungsten and the metal element is 0.001 to 0.15, as an atomic ratio of (W+M)/(In+W+M). 3. The oxide sintered body according to claim 1 , characterized in that the content of tungsten is 0.003 to 0.05, as an atomic ratio of W/(In+W). 4. The oxide sintered body according to claim 2 , characterized in that the total content of tungsten and the metal element is 0.003 to 0.05, as an atomic ratio of (W+M)/(In+W+M). 5. The oxide sintered body according to claim 1 , characterized by further comprising a crystal grain (C) composed of an indium tungstate compound phase. 6. The oxide sintered body according to claim 1 , characterized by not comprising a crystal grain (D) composed of a tungsten oxide phase. 7. A tablet obtained by processing the oxide sintered body according to claim 6 . 8. A tablet obtained by processing the oxide sintered body according to claim 1 .
made of transparent conductive layers, e.g. transparent conductive oxide [TCO] layers · CPC title
Active materials · CPC title
Heating rate · CPC title
micrometer sized, i.e. from 1 to 100 micron · CPC title
Gallium oxides, gallates, indium oxides, indates, thallium oxides, thallates or oxide forming salts thereof, e.g. zinc gallate · CPC title
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