Lubricating oil composition for transmissions

Patent metadata

Field	Value
Publication number	US-9340747-B2
Application number	US-201214384572-A
Country	US
Kind code	B2
Filing date	Nov 9, 2012
Priority date	Mar 13, 2012
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The present invention provides a lubricating oil composition for transmissions which is improved in fuel saving properties and has excellent metal fatigue prevention properties and heat resistance. The lubricating oil composition comprises (A) a mineral base oil having a 100° C. kinematic viscosity of 1.5 mm 2 /s or higher and 3.5 mm 2 /s or lower, a pour point of −25° C. or lower, a viscosity index of 110 or greater, a % C N of 2 or greater and 20 or less and a % C A of 3 or less, the lubricating oil composition having a 100° C. kinematic viscosity of 2.5 mm 2 /s or higher and 3.8 mm 2 /s or lower.

First claim

The invention claimed is:

1. A lubricating oil composition for transmissions comprising:
(A) a mineral base oil having a 100° C. kinematic viscosity of 1.5 mm 2 /s or higher and 3.5 mm 2 /s or lower, a pour point of −25° C. or lower, a viscosity index of 110 or greater, a % CN of 2 or greater and 20 or less and a % CA of 3 or less,
(B) a poly(meth)acrylate comprising at least a structural component derived from a monomer represented by formula (1) in an amount of 0.1 percent by mass or more and 20 percent by mass or less,
the lubricating oil composition having a 100° C. kinematic viscosity of 2.5 mm 2 /s or higher and 3.8 mm 2 /s or lower:

wherein R 1 is hydrogen or methyl, and R 2 is a hydrocarbon group having 1 to 30 carbon atoms,
wherein Component (B) comprises (B-1) a poly(meth)acrylate produced by polymerizing a monomer component comprising (Ba-1) to (Bd-1):
20 to 60 percent by mass of (Ba-1) a (meth)acrylate wherein R 2 is an alkyl group having 1 to 4 carbon atoms;
0 to 30 percent by mass of (Bb-1) a (meth)acrylate wherein R 2 is an alkyl group having 5 to 10 carbon atoms;
20 to 70 percent by mass of (Bc-1) a (meth)acrylate wherein R 2 is an alkyl group having 11 to 18 carbon atoms; and
5 to 50 percent by mass of (Bd-1) a (meth)acrylate wherein R 2 is an alkyl group having 19 to 30 carbon atoms.

2. A lubricating oil composition for transmissions comprising:
(A) a mineral base oil having a 100° C. kinematic viscosity of 1.5 mm 2 /s or higher and 3.5 mm 2 /s or lower, a pour point of −25° C. or lower, a viscosity index of 110 or greater, a % C N of 2 or greater and 20 or less and a % C A of 3 or less,
(B) a poly(meth)acrylate comprising at least a structural component derived from a monomer represented by formula (1) in an amount of 0.1 percent by mass or more and 20 percent by mass or less,
the lubricating oil composition having a 100° C. kinematic viscosity of 2.5 mm 2 /s or higher and 3.8 mm 2 /s or lower:

wherein R 1 is hydrogen or methyl, and R 2 is a hydrocarbon group having 1 to 30 carbon atoms, wherein Component (B) comprises (B-2) a poly(meth)acrylate produced by polymerizing a monomer component comprising (Ba-2) to (Bd-2):
0 to 60 percent by mass of (Ba-2) a (meth)acrylate wherein R 2 is an alkyl group having 1 to 4 carbon atoms;
0 to 30 percent by mass of (Bb-2) a (meth)acrylate wherein R 2 is an alkyl group having 5 to 10 carbon atoms;
30 to 100 percent by mass of (Bc-2) a (meth)acrylate wherein R 2 is an alkyl group having 11 to 18 carbon atoms; and
0 percent by mass of (Bd-2) a (meth)acrylate wherein R 2 is an alkyl group having 19 to 30 carbon atoms.

3. The lubricating oil composition for transmissions according to claim 1 , wherein the mineral base oil (A) has a naphthene content of 3 percent by mass or more and 15 percent by mass or less.

4. The lubricating oil composition for transmissions according to claim 2 , wherein the mineral base oil (A) has a naphthene content of 3 percent by mass or more and 15 percent by mass or less.

5. The lubricating oil composition for transmissions according to claim 2 , wherein Component (Bc-2) contains (Bc-2-1) and (Bc-2-2):
60 to 100 percent by mass (on the (Bc-2) basis) of (Bc-2-1) a (meth)acrylate wherein R 2 is an alkyl group having 11 to 15 carbon atoms; and
0 to 40 percent by mass (on the (Bc-2) basis) of (Bc-2-2) a (meth)acrylate wherein R 2 is an alkyl group having 16 to 18 carbon atoms.

6. The lubricating oil composition for transmissions according to claim 4 , wherein Component (Bc-2) contains (Bc-2-1) and (Bc-2-2):
60 to 100 percent by mass (on the (Bc-2) basis) of (Bc-2-1) a (meth)acrylate wherein R 2 is an alkyl group having 11 to 15 carbon atoms; and
0 to 40 percent by mass (on the (Bc-2) basis) of (Bc-2-2) a (meth)acrylate wherein R 2 is an alkyl group having 16 to 18 carbon atoms.

7. The lubricating oil composition for transmissions according to claim 2 , wherein the composition ratio of Component (Ba-2) is from 0 to 10 percent by mass on the basis of the total mass of the monomer.

8. The lubricating oil composition for transmissions according to claim 5 , wherein the composition ratio of Component (Ba-2) is from 0 to 10 percent by mass on the basis of the total mass of the monomer.

9. The lubricating oil composition for transmissions according to claim 1 , wherein (B-1) the poly(meth)acrylate has an weight average molecular weight of 10,000 to 60,000 and is contained in an amount of 0.5 to 10 percent by mass, on the basis of the total mass of the composition.

10. The lubricating oil composition for transmissions according to claim 2 , wherein (B-2) the poly(meth)acrylate has an weight average molecular weight of 20,000 to 100,000 and contained in an amount of 0.05 to 10 percent by mass on the basis of the total mass of the composition.

11. The lubricating oil composition for transmissions according to claim 1 , wherein the composition contains no pour point depressants or viscosity index improver having an weight average molecular weight of 10,000 or greater other than Component (B).

12. The lubricating oil composition for transmissions according to claim 2 , wherein the composition contains no pour point depressants or viscosity index improver having an weight average molecular weight of 10,000 or greater other than Component (B).

Assignees

• Jx Nippon Oil & Energy Corp

Inventors

• Nakao Hajime
• Komatsubara Hitoshi

Classifications

• C10M2215/28

  Amides; Imides · CPC title

• C10M2203/1025

  used as base material · CPC title

• C10N2020/011

  Cloud point · CPC title

• C10M2203/1006

  used as base material · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title