Actinic ray curable inkjet ink and image recording method using same

Patent metadata

Field	Value
Publication number	US-9340693-B2
Application number	US-201214004729-A
Country	US
Kind code	B2
Filing date	Mar 27, 2012
Priority date	Mar 28, 2011
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The purpose of the present invention is to provide an actinic ray curable inkjet ink which, in an inkjet printing method, is capable of having both high pinning characteristics and high ejection characteristics. In order to achieve the above purpose, this actinic ray curable inkjet ink includes an actinic ray curable compound, ketone wax, and ester wax, and reversibly goes through a sol-gel phase transition depending on the temperature.

First claim

The invention claimed is:

1. An actinic ray curable inkjet ink comprising an actinic ray curable compound, a ketone wax, and an ester wax,
wherein the ink undergoes reversible sol-gel phase transition depending on temperature, and
wherein the total amount of the ketone wax and the ester wax is less than 10% by mass with respect to the mass of the actinic ray curable inkjet ink.

2. The actinic ray curable inkjet ink according to claim 1 , wherein a melting point of the ketone wax is higher than a melting point of the ester wax.

3. The actinic ray curable inkjet ink according to claim 1 , wherein a difference between the melting point of the ketone wax and the melting point of the ester wax is 10° C. or more.

4. The actinic ray curable inkjet ink according to claim 1 , wherein the number of carbon atoms in a molecule that constitute the ketone wax and the number of carbon atoms in a molecule that constitute the ester wax are each 19 to less than 100.

5. The actinic ray curable inkjet ink according to claim 1 , wherein the melting points of the ketone wax and the ester wax are each 30° C. to lower than 150° C.

6. The actinic ray curable inkjet ink according to claim 1 , wherein the ketone wax is a compound A represented by the following General Formula 1:
R1-(C═O)—R2  (1)

where R1 and R2 each independently represent an aliphatic hydrocarbon group containing a straight chain moiety having 9 to 25 carbon atoms; and
the ester wax is a compound B represented by General Formula 2:
R3-(C═O)—O—R4  (2)

where R3 and R4 each independently represent an aliphatic hydrocarbon group containing a straight chain moiety having 9 to 26 carbon atoms.

7. The actinic ray curable inkjet ink according to claim 1 , wherein a total amount of the ketone wax and the ester wax is 0.5% by mass to less than 10% by mass with respect to the actinic ray curable inkjet ink.

8. The actinic ray curable inkjet ink according to claim 1 , wherein a total amount of the ketone wax and the ester wax is 1% by mass to less than 7% by mass with respect to the actinic ray curable inkjet ink.

9. The actinic ray curable inkjet ink according to claim 1 , wherein the actinic ray curable compound is a (meth)acrylate compound.

10. The actinic ray curable inkjet ink according to claim 9 , wherein the (meth)acrylate compound is an ethylene oxide-modified (meth)acrylate compound.

11. The actinic ray curable inkjet ink according to claim 6 , wherein in General Formula 1,
R1 and R2 each represent an aliphatic hydrocarbon group containing a straight chain moiety having 11 to less than 23 carbon atoms.

12. The actinic ray curable inkjet ink according to claim 6 , wherein in General Formula 1,
R1 and R2 each represent a linear alkylene group 11 to less than 23 carbon atoms.

13. The actinic ray curable inkjet ink according to claim 6 , wherein in General Formula 2,
R3 represents an aliphatic hydrocarbon group containing a straight chain moiety having 11 to less than 23 carbon atoms, and
R4 represents an aliphatic hydrocarbon group containing a straight chain moiety having 12 to less than 24 carbon atoms.

14. The actinic ray curable inkjet ink according to claim 6 , wherein in General Formula 2,
R3 represents a linear alkylene group having 11 to less than 23 carbon atoms, and
R4 represents a linear alkylene group having 12 to less than 24 carbon atoms.

15. The actinic ray curable inkjet ink according to claim 1 , wherein the ketone wax comprises 18-pentatriacontanone.

16. The actinic ray curable inkjet ink according to claim 1 , wherein the ink comprises two or more kinds of the ketone wax.

17. The actinic ray curable inkjet ink according to claim 1 , wherein a viscosity of the ink as measured using a cone-plate type rheometer having a diameter of 75 mm and a cone angle of 1.0° at 80° C. and a shear rate of 11.7/s is 3 mPa·s to 20 mPa·s.

18. The actinic ray curable inkjet ink according to claim 1 , wherein a viscosity of the ink as measured using a cone-plate type rheometer having a diameter of 75 mm and a cone angle of 1.0° at 25° C. and a shear rate of 11.7/s is 1,000 mPa·s or greater.

19. The actinic ray curable inkjet ink according to claim 1 ,
wherein a gelling temperature of the ink is 40° C. to 70° C., the gelling temperature being a temperature at which a viscosity of the ink reaches 200 mPa·s when a temperature of the ink is lowered from 100° C. to 20° C. at a temperature decline rate of 0.1° C./s, the viscosity being measured at a shear rate of 11.7/s using a cone-plate type rheometer having a diameter of 75 mm and a cone angle of 1.0°.

20. An image recording method comprising:
discharging droplets of the actinic ray curable inkjet ink according to claim 1 from a inkjet head, allowing the droplets to adhere onto a recording medium; and
irradiating the droplets adhered onto the recording medium with an actinic ray to cure the ink.

21. The image recording method according to claim 20 , wherein a temperature of the ink inside the inkjet head is 10° C. to 30° C. higher than a gelling temperature of the ink, the gelling temperature being a temperature at which a viscosity of the ink reaches 200 mPa·s when a temperature of the ink is lowered from 100° C. to 20° C. at a temperature decline rate of 0.1° C./s, the viscosity being measured at a shear rate of 11.7/s using a cone-plate type rheometer having a diameter of 75 mm and a cone angle of 1.0°.

22. The image recording method according to claim 20 , wherein an image is recorded by means of single-pass printing.

23. The actinic ray curable inkjet ink according to claim 1 , wherein the ketone wax and the ester wax crystallize in the ink when temperature of the ink is lower than or equal to the gelling temperature of the ink.

24. The actinic ray curable inkjet ink according to claim 1 , wherein the ketone wax and the ester wax form a card-house structure.

25. The actinic ray curable inkjet ink according to claim 1 , wherein the ketone wax and the ester wax are dissolved in the actinic ray curable compound when temperature of the ink is higher than the gelling temperature of the ink.

Assignees

• Maeda Akio
• Mori Satoshi
• Ikeda Masashi
• Takabayashi Toshiyuki
• Iwata Takashi
• Iijima Hirotaka
• Konica Minolta Inc

Inventors

• Maeda Akio
• Mori Satoshi
• Ikeda Masashi
• Takabayashi Toshiyuki
• Iwata Takashi
• Iijima Hirotaka

Classifications

• C09D11/101

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• B41M7/0081

  using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams · CPC title

• B41J11/0015

  for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing (selective coating B41J2/2114) · CPC title

• C09D11/12

  based on waxes or bitumen · CPC title