Optical apparatus and method of forming a gradient index device

Patent metadata

Field	Value
Publication number	US-9340446-B1
Application number	US-201414172175-A
Country	US
Kind code	B1
Filing date	Feb 4, 2014
Priority date	Feb 4, 2013
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

A refractive index device and method of making it include obtaining a glass structure comprising a plurality of nucleation sites. The glass structure is formed from a glass composition that comprises a first chemical component and a second chemical component. A crystal of the second chemical component has a different second refractive index from a first refractive index of the first chemical component. Each nucleation site defines where a crystal of the second chemical component can be grown. The method includes causing crystals of the second chemical component to grow in situ at a set of the plurality of nucleation sites in order to produce a spatial gradient of a refractive index in the glass structure.

First claim

What is claimed is:

1. A method comprising:
obtaining a glass structure comprising a plurality of nucleation sites, wherein
the glass structure is formed from a glass composition that comprises a first chalcogenide chemical component and a second chalcogenide chemical component,
a crystal of the second chalcogenide chemical component has a different second refractive index from a first refractive index of the first chalcogenide chemical component, and
each nucleation site defines where the crystal of the second chalcogenide chemical component can be grown; and

causing a plurality of crystals of the second chalcogenide chemical component to grow in situ at a corresponding set of the plurality of nucleation sites in order to produce a spatial gradient of a refractive index in the glass structure.

2. A method as recited in claim 1 , wherein an optical device comprises the glass structure with the spatial gradient of the refractive index.

3. A method as recited in claim 2 , further comprising fabricating an optical apparatus comprising the optical device.

4. A method as recited in claim 1 , wherein obtaining the glass structure further comprises obtaining the glass structure without the plurality of nucleation sites and causing the plurality of nucleation sites to be formed in the glass structure.

5. A method as recited in claim 4 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises causing the plurality of nucleation sites to be distributed spatially non-uniformly through the glass structure.

6. A method as recited in claim 4 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises introducing ions to the glass structure by ion implantation.

7. A method as recited in claim 6 , wherein introducing the ions to the glass structure by ion implantation further comprises introducing the ions to the glass structure by ion implantation through a mask of variable thickness.

8. A method as recited in claim 4 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises applying an energy beam through a mask.

9. A method as recited in claim 4 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises adding energy to cause molecules of the second chalcogenide chemical component to precipitate out of the glass composition.

10. A method as recited in claim 4 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises heating the glass structure using at least one of a furnace or a laser to produce at least one of a uniform temperature profile or a temperature gradient profile for a predetermined amount of time.

11. A method as recited in claim 1 , wherein obtaining the glass structure further comprises forming the glass structure from the glass composition and causing the plurality of nucleation sites to be formed in situ in the glass structure.

12. A method as recited in claim 11 , wherein forming the glass structure further comprises depositing the glass structure as a layer on a substrate.

13. A method as recited in claim 1 , wherein the glass composition does not include an organic polymer.

14. A method as recited in claim 1 , wherein the glass structure and the plurality of crystals of the second chalcogenide chemical component are transparent to infrared radiation.

15. A method as recited in claim 1 , wherein causing the plurality of crystals of the second chalcogenide chemical component to grow at the corresponding set of the plurality of nucleation sites further comprises causing the plurality of crystals to grow at a subset distributed spatially non-uniformly through the structure of the plurality of nucleation sites.

16. A method as recited in claim 1 , wherein the second chalcogenide chemical component has a higher refractive index than the first chalcogenide chemical component.

17. A method as recited in claim 1 , wherein the second chalcogenide chemical component has a higher refractive index than the first chemical component by about 0.5 or more.

18. A method as recited in claim 1 , wherein the first chalcogenide chemical component comprises As 2 Se 3 and GeSe 2 .

19. A method as recited in claim 18 , wherein the second chalcogenide chemical component comprises PbSe.

20. A method as recited in claim 1 , wherein the first chalcogenide chemical component comprises Sb 2 S 3 and GeS 2 .

21. A method as recited in claim 20 , wherein the second chalcogenide chemical component comprises PbS.

22. A method as recited in claim 1 , wherein causing the plurality of crystals of the second chalcogenide chemical component to grow further comprises adding energy to cause the plurality of crystals of the second chemical component to precipitate out of the glass composition.

23. A method as recited in claim 1 , wherein the spatial gradient of the refractive index in the glass structure is a two dimensional spatial gradient of the refractive index.

24. A method as recited in claim 1 , wherein the spatial gradient of the refractive index in the glass structure is a three dimensional spatial gradient of the refractive index.

25. A method as recited in claim 1 , wherein causing the plurality of crystals of the second chemical component to grow further comprises heating the glass structure using at least one of a furnace or a laser to produce at least one of a uniform temperature profile or a temperature gradient profile for a predetermined amount of time.

26. A method as recited in claim 1 , wherein the plurality of crystals has different sizes in a size range from about 10 nanometers to about 250 nanometers.

27. A method as recited in claim 1 , wherein the plurality of crystals has uniform sizes in a size range from about 10 nanometers to about 250 nanometers and non-uniform spatial distribution through the glass structure.

28. A method comprising:
obtaining a glass structure formed from a glass composition that comprises a first chalcogenide chemical component and a second chalcogenide chemical component, wherein a crystal of the second chalcogenide chemical component has a different second refractive index from a first refractive index of the first chalcogenide chemical component; and
causing a plurality of nucleation sites to be formed in situ wherein each nucleation site defines where the crystal of the second chalcogenide chemical component can be grown to produce a spatial gradient of a refractive index in the glass structure.

29. A method as recited in claim 28 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises causing the plurality of nucleation sites to be distributed spatially non-uniformly through the glass structure.

30. A method as recited in claim 29 , further comprising causing a plurality of crystals of the second chemical component to grow in situ at a corresponding set of the plurality of nucleation sites in order to produce the spatial gradient of a refractive index in the glass structure.

31. A method as recited in claim 28 , wherein causing the plurality of nucleation sites to be formed in the glass structure further comprises introducing ions to the glass structure by ion implantation.

32. A

Assignees

• Lockheed Corp
• Penn State Res Found
• Univ Clemson Res Foundation

Inventors

• Baleine Clara Rivero
• Mayer Theresa S
• Musgraves Jonathan David
• Richardson Kathleen
• Wachtel Peter

Classifications

• C03C4/0028 Primary

  for crystal glass, e.g. lead-free crystal glass · CPC title

• C03B32/02

  Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles {(C03B27/012 takes precedence)} · CPC title

• G02B2006/12038

  Glass (SiO2 based materials) · CPC title

• C03B25/00

  Annealing glass products · CPC title

• C03C23/0025

  by a laser beam · CPC title