Method for increasing density of aligned carbon nanotubes

Patent metadata

Field	Value
Publication number	US-9340428-B2
Application number	US-201414453831-A
Country	US
Kind code	B2
Filing date	Aug 7, 2014
Priority date	Apr 17, 2014
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The present application relates to a method of increasing density of aligned carbon nanotubes. Firstly, aligned carbon nanotubes grown on a substrate is transferred to a stretched retractable film. The retractable film is then shrunk along a direction which is perpendicular to the alignment direction of the carbon nanotubes to obtain high density carbon nanotubes. The array of aligned carbon nanotubes is finally transferred from the retractable film to a target substrate. The disclosed method can efficiently obtain high-density high-quality aligned carbon nanotubes at low cost.

First claim

What is claimed is:

1. A method for increasing density of aligned carbon nanotubes, comprising the following steps:
(a) transferring aligned carbon nanotubes from an initial substrate to a stretched retractable film to obtain a composite structure comprising the aligned carbon nanotubes and the stretched retractable film, wherein the carbon nanotubes are aligned perpendicular to a retracting direction of the retractable film,
wherein step (a) further comprises:
coating a polymer transfer material on the aligned carbon nanotubes on the initial substrate;
removing the initial substrate to form a composite of the aligned carbon nanotubes and a transfer film made of the polymer transfer material; and
attaching the aligned carbon nanotubes in the composite of the aligned carbon nanotubes and the transfer film to the stretched retractable film;

(b) shrinking the retractable film in the composite structure along the retracting direction to increase density of the aligned carbon nanotubes; and
(c) transferring the aligned carbon nanotubes in the composite structure to a target substrate.

2. The method of claim 1 , wherein the carbon nanotubes are distributed in an array of aligned carbon nanotubes, single carbon nanotubes at low density, or a thin film of carbon nanotubes.

3. The method of claim 1 , wherein the initial substrate includes a quartz substrate or a sapphire substrate, wherein the aligned carbon nanotubes are grown on the initial substrate using chemical vapor deposition.

4. The method of claim 1 , wherein the retractable film is composed of a polymeric material or a shape memory alloy.

5. The method of claim 4 , wherein the polymeric material includes rubber or polyester.

6. The method of claim 1 , wherein the polymer transfer material comprises PMMA.

7. The method of claim 6 , wherein the retractable film is shrunk at a temperature above a glass transition temperature of PMMA.

8. The method of claim 1 , wherein the step (c) further comprises:
attaching the aligned carbon nanotubes in the composite structure to the target substrate;
dissolving the retractable film; and
dissolving the polymer transfer material to leave the aligned carbon nanotubes on the target substrate.

9. The method of claim 1 , wherein the step (a) further comprises:
forming a metal layer on a surface of the stretched retractable film; and
attaching the aligned carbon nanotubes in the composite of the aligned carbon nanotubes and the transfer film to the metal layer on the stretched retractable film.

10. The method of claim 9 , wherein the step (c) further comprises:
attaching the aligned carbon nanotubes in the composite structure to the target substrate;
dissolving the metal layer using a metal etchant to lift off the retractable film; and
dissolving the polymer transfer material to leave the aligned carbon nanotubes on the target substrate.

11. The method of claim 1 , further comprising:
treating the target substrate by UV irradiation and/or oxygen plasma bombardment before the step (c).

12. The method of claim 1 , further comprising:
coating the target substrate by a layer of organic molecules, wherein the aligned carbon nanotubes in the composite structure are transferred onto to the layer of organic molecules on the target substrate.

13. The method of claim 1 , wherein the step (c) further comprises:
lifting the retractable film off the composite structure to leave the aligned carbon nanotubes on the target substrate.

14. The method of claim 1 , wherein the retractable film comprises a shape memory alloy, wherein the step (b) further comprises heating the shape memory alloy above a transformation temperature of the shape memory alloy to shrink the retractable film.

15. The method of claim 14 , wherein the step (c) further comprises:
attaching the aligned carbon nanotubes in the composite structure to the target substrate; and
dissolving the shape memory alloy by a metal etchant.

16. The method of claim 14 , wherein in the step (c), the retractable film is lifted off mechanically or is directly tore off.

Assignees

• Univ Beijing

Inventors

• Si Jia
• Zhang Zhiyong
• Peng Lianmao

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01B31/0253 Primary

  Chemistry & Metallurgy · mapped topic

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C01B31/0226

  Chemistry & Metallurgy · mapped topic

• C01B32/168 Primary

  After-treatment · CPC title