Power storage device

Patent metadata

Field	Value
Publication number	US-9337475-B2
Application number	US-201213586050-A
Country	US
Kind code	B2
Filing date	Aug 15, 2012
Priority date	Aug 30, 2011
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

A power storage device in which silicon is used as a negative electrode active material layer and which can have an improved performance such as higher discharge capacity, and a method for manufacturing the power storage device are provided. A power storage device includes a current collector and a silicon layer having a function as an active material layer over the current collector. The silicon layer includes a thin film portion in contact with the current collector, a plurality of bases, and a plurality of whisker-like protrusions extending from the plurality of bases. A protrusion extending from one of the plurality of bases is partly combined with a protrusion extending from another one of the plurality of bases.

First claim

What is claimed is:

1. A power storage device comprising:
a current collector; and
a silicon layer having a function as an active material layer over the current collector,
wherein the silicon layer comprises:
a thin silicon film portion in contact with the current collector,
a first base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a second base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a first whisker-like protrusion extending from the first base, the first whisker-like protrusion comprising a first core and a first shell;
a second whisker-like protrusion extending from the first base, the second whisker-like protrusion comprising a second core and a second shell;
a third whisker-like protrusion extending from the second base, the third whisker-like protrusion comprising third core and third shell; and
a fourth whisker-like protrusion extending from the second base, the fourth whisker-like protrusion comprising a fourth core and a fourth shell,

wherein each of the first core and the third core comprises crystalline silicon,
wherein each of the first shell and the third shell comprises amorphous silicon, and
wherein the first shell is directly combined with the third shell.

2. The power storage device according to claim 1 ,
wherein the first whisker-like protrusion is combined with the second whisker-like protrusion.

3. The power storage device according to claim 1 ,
wherein the first whisker-like protrusion has a columnar shape such as a cylindrical shape or a prismatic shape, or a needle-like shape such as a conical shape or a pyramidal shape.

4. The power storage device according to claim 1 ,
wherein the thin silicon film portion comprises amorphous silicon.

5. An electrode comprising:
a current collector; and
a silicon layer having a function as an active material layer over the current collector,
wherein the silicon layer comprises:
a thin silicon film portion in contact with the current collector,
a first base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a second base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a first whisker-like protrusion extending from the first base, the first whisker-like protrusion comprising a first core and a first shell;
a second whisker-like protrusion extending from the first base, the second whisker-like protrusion comprising a second core and a second shell;
a third whisker-like protrusion extending from the second base, the third whisker-like protrusion comprising a third core and a third shell; and
a fourth whisker-like protrusion extending from the second base, the fourth whisker-like protrusion comprising a fourth core and a fourth shell,

wherein each of the first core and the third core comprises crystalline silicon,
wherein each of the first shell and the third shell comprises amorphous silicon, and
wherein the first shell is directly combined with the third shell.

6. The electrode according to claim 5 ,
wherein the electrode is a negative electrode.

7. The electrode according to claim 5 ,
wherein the first whisker-like protrusion is combined with the second whisker-like protrusion.

8. The electrode according to claim 5 ,
wherein the first whisker-like protrusion has a columnar shape such as a cylindrical shape or a prismatic shape, or a needle-like shape such as a conical shape or a pyramidal shape.

9. The electrode according to claim 5 ,
wherein the thin silicon film portion comprises amorphous silicon.

10. A silicon layer comprising:
a thin silicon film portion;
a first base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a second base comprising crystalline silicon formed in the thin silicon film portion and having a stump-like shape;
a first whisker-like protrusion extending from the first base, the first whisker-like protrusion comprising a first core and a first shell;
a second whisker-like protrusion extending from the first base, the second whisker-like protrusion comprising a second core and a second shell; and
a third whisker-like protrusion extending from the second base, the third whisker-like protrusion comprising a third core and a third shell,

wherein each of the first core and the third core comprises crystalline silicon,
wherein each of the first shell and the third shell comprises amorphous silicon, and
wherein the first shell is directly combined with the third shell.

11. The silicon layer according to claim 10 ,
wherein the first whisker-like protrusion is combined with the second whisker-like protrusion.

12. The silicon layer according to claim 10 ,
wherein the first whisker-like protrusion has a columnar shape such as a cylindrical shape or a prismatic shape, or a needle-like shape such as a conical shape or a pyramidal shape.

13. The silicon layer according to claim 10 ,
wherein the thin silicon film portion comprises amorphous silicon.

14. The power storage device according to claim 1 ,
wherein the current collector comprises a metal element which forms silicide by reacting with silicon.

15. The electrode according to claim 5 ,
wherein the current collector comprises a metal element which forms silicide by reacting with silicon.

16. The power storage device according to claim 1 ,
wherein a width of the first core is greater than or equal to 0.5 μm and less than or equal to 2 μm, and
wherein a length of the first core is greater than or equal to 0.5 μM and less than or equal to 1000 μm.

17. The electrode according to claim 5 ,
wherein a width of the first core is greater than or equal to 0.5 μm and less than or equal to 2 μm, and
wherein a length of the first core is greater than or equal to 0.5 μM and less than or equal to 1000 μm.

18. The silicon layer according to claim 10 ,
wherein a width of the first core is greater than or equal to 0.5 μm and less than or equal to 2 μm, and
wherein a length of the first core is greater than or equal to 0.5 μM and less than or equal to 1000 μm.

Assignees

• Takeuchi Toshihiko
• Takahashi Minoru
• Osada Takeshi
• Oguni Teppei
• Tanemura Kazuki
• Semiconductor Energy Lab

Inventors

• Takeuchi Toshihiko
• Takahashi Minoru
• Osada Takeshi
• Oguni Teppei
• Tanemura Kazuki

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02T10/7022

  Cross-Sectional Technologies · mapped topic

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01G11/30

  characterised by their material · CPC title