Organic electroluminescent element, organic electroluminescent display device, and electronic equipment
US-2024423010-A1 · Dec 19, 2024 · US
US9337447B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9337447-B2 |
| Application number | US-201013378919-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 16, 2010 |
| Priority date | Jun 16, 2009 |
| Publication date | May 10, 2016 |
| Grant date | May 10, 2016 |
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A radiation-emitting device having an organic radiation-emitting functional layer and a radiation decoupling layer. The organic radiation-emitting functional layer emits a primary radiation; the radiation decoupling layer is disposed in the beam path of the primary radiation. On the side remote from the radiation-emitting functional layer the radiation decoupling layer comprises a microstructure having regularly disposed geometric structural elements; at least partial regions of the radiation decoupling layer contain regions which effect scattering of the primary radiation.
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The invention claimed is: 1. A radiation-emitting device, comprising an organic radiation-emitting functional layer, which emits a primary radiation, and a radiation decoupling layer, which is disposed in a beam path of the primary radiation, wherein the radiation decoupling layer comprises, on a side remote from the radiation-emitting functional layer, a microstructure having regularly disposed geometric structural elements, and at least partial regions of the radiation decoupling layer contain regions which effect scattering of the primary radiation, the radiation decoupling layer further comprising a matrix which comprises a polymer which is transparent to the primary radiation, wherein each one of the geometric structural elements has exactly one light decoupling surface facing away from the radiation-emitting functional layer, said light decoupling surfaces being continuously differentiable, and wherein each planar curve, extending from a maximum of a respective one of the geometric structural elements to a base thereof, comprises in its lower third nearest to the radiation-emitting functional layer only curvatures which are smaller than any curvature in a corresponding upper third of the planar curve, the upper third being the third that is most remote from the radiation-emitting functional layer. 2. The radiation-emitting device as claimed in claim 1 , wherein the light-scattering regions comprise at least one selected from the group consisting of particles, hollow particles and gas inclusions. 3. The radiation-emitting device as claimed in claim 1 , wherein the light-scattering regions comprise an average diameter of 0.5 to 100 μm. 4. The radiation-emitting device as claimed in claim 1 , wherein the geometric structural elements each comprise a base surface which is a polygon. 5. The radiation-emitting device as claimed in claim 1 , wherein the microstructure can be embossed into a surface of the radiation decoupling layer using a metal roller. 6. The radiation-emitting device as claimed in claim 1 , wherein the maxima of mutually adjacent geometric structural elements comprise a spacing of 30 to 500 μm. 7. The radiation-emitting device as claimed in claim 1 , wherein the partial regions are not present in the region of the geometric structural elements. 8. The radiation-emitting device as claimed in claim 1 , wherein the radiation decoupling layer is disposed directly on a side of a substrate, of a barrier layer or of a transparent electrode, which in each case is remote from the radiation-emitting functional layer. 9. The radiation-emitting device as claimed in claim 1 , wherein the radiation decoupling layer comprises at least two mutually spaced-apart partial layers, wherein a gas is present between the partial layers and wherein mutually facing boundary surfaces of the partial layers extend substantially in parallel with one another and extend substantially in parallel with a surface of the radiation decoupling layer facing the radiation-emitting functional layer. 10. The radiation-emitting device as claimed in claim 9 , wherein a support structure is disposed between the mutually spaced-apart partial layers. 11. The radiation-emitting device as claimed in claim 1 , which is formed as an OLED. 12. The radiation-emitting device as claimed in claim 1 , which is provided for lighting purposes, in particular for lighting over a large area. 13. The radiation-emitting device as claimed in claim 1 , wherein the light-scattering regions comprise an average diameter of 2 to 20 μm. 14. The radiation-emitting device as claimed in claim 1 , wherein the maxima of mutually adjacent geometric structural elements comprise a spacing of 100 to 250 μm. 15. The radiation-emitting device as claimed in claim 10 , wherein said support structure consists of a transparent material. 16. The radiation-emitting device as claimed in claim 1 , wherein the light-scattering regions comprise scattering particles which are of a core-shell construction. 17. The radiation-emitting device as claimed in claim 1 , wherein said polymer which is transparent to the primary radiation is a polycarbonate. 18. A radiation-emitting device, comprising an organic radiation-emitting functional layer, which emits a primary radiation, and a radiation decoupling layer, which is disposed in a beam path of the primary radiation, wherein the radiation decoupling layer comprises first and second geometric structural elements, wherein the radiation decoupling layer comprises, on a side remote from the radiation-emitting functional layer, a microstructure having the first geometric structural elements regularly disposed therein, and at least one partial layer of the radiation decoupling layer contains regions which comprise the second geometric structural elements that effect scattering of the primary radiation, wherein each one of the first geometric structural elements has exactly one light decoupling surface facing away from the radiation-emitting functional layer, said light decoupling surfaces being continuously differentiable, and wherein each planar curve, extending from a maximum of a respective one of the first geometric structural elements to a base thereof, comprises in its lower third nearest to the radiation-emitting functional layer only curvatures which are smaller than any curvature in a corresponding upper third of the planar curve, the upper third being the third that is most remote from the radiation-emitting functional layer, wherein the at least one partial layer is arranged between the microstructure and the organic radiation-emitting functional layer, and the at least one partial layer comprises a matrix which is mixed with scattering particles in a statistical distribution, the scattering particles constituting the second geometric structural elements, wherein the matrix and the scattering particles are formed from radiation-permeable polymers, wherein the scattering particles are polymer particles having a core-shell morphology or the scattering particles are polymer hollow particles, wherein said first and second geometric structural elements have volumes that differ by at least 50 percent, wherein the first and second geometric structural elements alternate in a regular manner, and wherein the partial layer with the scattering particles is in direct contact with the radiation-emitting functional layer and with the radiation decoupling layer comprising the microstructure.
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