Radioactive organic waste treatment method

Patent metadata

Field	Value
Publication number	US-9336913-B2
Application number	US-201414309164-A
Country	US
Kind code	B2
Filing date	Jun 19, 2014
Priority date	Jun 21, 2013
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

Disclosed is a method for treating a radioactive organic waste, the radioactive organic waste including a cation exchange resin adsorbing radionuclide ions, the method including the step of bringing the radioactive organic waste into contact with an organic acid salt aqueous solution containing an organic acid salt and whereby desorbing the radionuclide ions from the cation exchange resin, in which the organic acid salt contained in the organic acid salt aqueous solution includes a cation that is more readily adsorbable by the cation exchange resin than hydrogen ion is. This enables reduction in concentration of a radioactive substance in the radioactive organic waste and reduction in amount of a high-dose radioactive waste.

First claim

What is claimed is:

1. A method for treating a radioactive organic waste, the radioactive organic waste including a cation exchange resin adsorbing radionuclide ions,
the method comprising the step of:
an organic acid salt treatment process bringing the radioactive organic waste into contact with an organic acid salt aqueous solution containing an organic acid salt and whereby desorbing the radionuclide ions from the cation exchange resin,
wherein the organic acid salt contained in the organic acid salt aqueous solution includes a cation that is more readily adsorbable by the cation exchange resin than hydrogen ion is.

2. The method according to claim 1 , further comprising the step of:
an organic acid salt oxidization treatment process subjecting the organic acid salt aqueous solution after the step of desorbing to an oxidization treatment and whereby decomposing the organic acid salt, the organic acid salt aqueous solution containing the radionuclide ions desorbed from the cation exchange resin.

3. The method according to claim 1 ,
when the radioactive organic waste includes an iron oxide,
the method further comprising the step of:
an organic acid treatment process bringing the radioactive organic waste into contact with an organic acid aqueous solution and whereby dissolving the iron oxide before the step of the organic acid salt treatment process.

4. The method according to claim 3 , further comprising the step of:
an organic acid oxidization treatment process subjecting the organic acid aqueous solution to an oxidization treatment and whereby decomposing the organic acid contained in the organic acid aqueous solution after the step of the organic acid treatment process.

5. The method according to claim 3 ,
wherein the radioactive organic waste is brought into contact with the organic acid aqueous solution in a cleaning tank;
the organic acid aqueous solution is discharged from the cleaning tank after the contact; and
the organic acid salt aqueous solution is supplied after the discharge into the cleaning tank storing the radioactive organic waste so as to bring the radioactive organic waste into contact with the organic acid salt aqueous solution.

6. The method according to claim 3 ,
wherein the organic acid salt aqueous solution includes a substance prepared by adding a basic aqueous solution to the organic acid aqueous solution after the dissolution of the iron oxide and whereby neutralizing the organic acid aqueous solution.

7. The method according to claim 1 ,
wherein the organic acid salt is a salt selected from the group consisting of ammonium salt, barium salt and cesium salt of an acid selected from the group consisting of oxalic acid, formic acid, carbonic acid, acetic acid and citric acid.

8. The method according to claim 3 ,
wherein the organic acid is selected from the group consisting of oxalic acid, formic acid, carbonic acid, acetic acid and citric acid.

9. The method according to claim 3 ,
comprising both the organic acid treatment process and the organic acid salt treatment process,
wherein the organic acid treatment process and the organic acid salt treatment process are performed with heating of the radioactive organic waste.

10. The method according to claim 3 ,
comprising both the organic acid treatment process and the organic acid salt treatment process,
wherein the organic acid treatment process and the organic acid salt treatment process are performed step by step in an identical cleaning tank.

11. The method according to claim 3 ,
wherein the organic acid aqueous solution for use in the organic acid treatment process includes an organic acid including at least one element selected from the group consisting of carbon, oxygen, hydrogen and nitrogen.

12. The method according to claim 1 ,
wherein the organic acid salt aqueous solution for use in the organic acid salt treatment process includes an organic acid salt with an anion, the anion including at least one element selected from the group consisting of carbon, oxygen, hydrogen and nitrogen.

13. The method according to claim 1 ,
wherein the organic acid salt for use in the organic acid salt treatment process is added with a non-volatile ion having a selectivity for the radioactive organic waste higher than that of hydrogen ion.

14. The method according to claim 13 ,
wherein the non-volatile ion is at least one selected from the group consisting of potassium ion, zinc ion, calcium ion and cobalt ion.

15. The method according to claim 3 ,
wherein the organic acid treatment process is not performed when the radioactive organic waste includes substantially no crud, or when the organic acid salt for use in the organic acid salt treatment process is capable of dissolving crud.

16. The method according to claim 3 ,
wherein the organic acid salt treatment process is not performed when the organic acid aqueous solution for use in the organic acid treatment process is capable of efficiently eluting radioactive metal ions adsorbed by the radioactive organic waste.

Assignees

• Hitachi Ge Nuclear Energy Ltd

Inventors

• Sumiya Takako
• Noshita Kenji
• Ishida Kazushige
• Nagayama Nozomu
• Kamoshida Mamoru
• Yukita Atsushi

Classifications

• G21F9/28

  Treating solids · CPC title

• G21F9/12 Primary

  by absorption; by adsorption; by ion-exchange · CPC title

• G21F9/125

  by solvent extraction · CPC title