Nitrogen rejection unit

Patent metadata

Field	Value
Publication number	US-9335091-B2
Application number	US-201313951021-A
Country	US
Kind code	B2
Filing date	Jul 25, 2013
Priority date	Feb 28, 2013
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

Methods and systems for removing nitrogen during liquefaction of natural are provided. Methods of removing nitrogen include warming a predominantly methane stream in a methane cold box to provide a warmed predominantly methane stream; conducting at least a portion of the warmed predominantly methane stream from the methane cold box to a nitrogen removal unit comprising at least a first nitrogen removal column and a last nitrogen removal column, wherein the first nitrogen removal column is located upstream of the last nitrogen removal column; passing the warmed predominantly methane stream through the last nitrogen removal column to provide a refluxed warmed predominantly methane stream; and routing at least a portion of the refluxed warmed predominantly methane stream to the last nitrogen removal column.

First claim

The invention claimed is:

1. A method of removing nitrogen from a natural gas stream comprising:
(a) routing the natural gas stream from a methane cold box of a main liquefaction process to a nitrogen rejection unit comprising: a first distillation column, a second distillation column, a third distillation column, and a condenser, wherein the main liquefaction process comprises: one or more refrigeration cycles external to the nitrogen rejection unit;
(b) at least partially condensing the natural gas stream via the condenser, wherein the condenser utilizes a refrigerant used to transfer heat in the one or more refrigeration cycles to form a condensed natural gas stream, wherein the refrigerant is taken from the refrigeration cycle routed into a core-in-shell exchanger forming the condenser and returned to the refrigeration cycle without passing through the first distillation column; and
(c) routing at least a portion of the condensed natural gas stream to the third distillation column to separate the at least a portion of the condensed natural gas stream into a third top fraction and a third bottom fraction, wherein the third top fraction comprises a predominantly nitrogen gas stream.

2. The method of claim 1 , wherein the natural gas stream from the methane cold box in step (a) is a predominantly methane gas stream.

3. The method of claim 1 , further comprising: routing the third bottom fraction to the main liquefaction process.

4. The method of claim 1 , wherein the nitrogen rejection unit further comprises one or more reboilers, each reboiler providing heating duty to the first distillation column, the second distillation column, the third distillation column, or any combination thereof.

5. The method of claim 1 , wherein heating duty to the first distillation column, the second distillation column, or the third distillation column is provided by stripping gas or heating gas.

6. The method of claim 1 , wherein the refrigerant is selected from the group consisting of: methane, ethylene, propane, any mixture thereof, and any combination thereof.

7. The method of claim 1 further comprising: cooling the natural gas stream to produce a liquefied natural gas stream.

8. The method of claim 1 further comprising expanding the refrigerant prior to being routed into the core-in-shell exchanger.

Assignees

• Conocophillips Co

Inventors

• Qualls Wesley Roy
• Ma Qi
• Evans Megan Victoria
• Herzog Karl Lee
• Yao Jame
• Chahal Mohan
• Gentry Matt Calvin
• Praderio Attilio Jose
• Bellomy Marc Thomas
• Gandhi Satish
• Wilkes Mike
• James Will

Classifications

• F25J2200/40

  Features relating to the provision of boil-up in the bottom of a column · CPC title

• F25J3/0233

  separation of CnHm with 1 carbon atom or more · CPC title

• F25J2215/60

  Methane · CPC title

• F25J1/0238

  Purification or treatment step is integrated within one refrigeration cycle only, i.e. the same or single refrigeration cycle provides feed gas cooling (if present) and overhead gas cooling · CPC title

• F25J2200/08

  in a triple pressure main column system · CPC title