Process for preparing polyolefin blends in a device for continuously physically melting and blending the blends

Patent metadata

Field	Value
Publication number	US-9334396-B2
Application number	US-201214003128-A
Country	US
Kind code	B2
Filing date	Mar 2, 2012
Priority date	Mar 4, 2011
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

A process for preparing a polyolefin product can include providing a first high molecular weight (HMW) polyolefin resin having an HLMI of between 0.01 and 5 g/10 min, and separately providing a second low molecular weight (LMW) polyolefin resin having an MI 2 of between 1 and 150 g/10 min. A device can be used to continuously physically melt and blend the first HMW polyolefin resin and the second LMW polyolefin resin to produce the polyolefin product. The device can include at least two feeding zones spatially separated and operably connected to each other. At least a art of the first HMW polyolefin resin is introduced in a first feeding zone, and at least a part of the second LMW polyolefin is introduced in a second feeding zone different from the first zone.

First claim

The invention claimed is:

1. A process for preparing a polyolefin product, said process comprising:
(a) providing a first high molecular weight (HMW) polyolefin resin having a High Load Melt Index (HLMI), measured at 190° C. under a 21.6 kg load according ASTM D-1238, of between 0.01 and 5 g/10 min;
(b) separately providing a second low molecular weight (LMW) polyolefin resin having a Melt Index (MI 2 ), measured at 190° C. under a 2.16 kg load according ASTM D-1238, of between 1 and 150 g/10 min; and
(c) using a device for physically melting and blending said first HMW polyolefin resin and said second LMW polyolefin resin to produce a polyolefin product;
characterized in that said device comprises at least two feeding zones spatially separated and operably connected to each other, wherein at least part of the first HMW polyolefin resin is introduced in a first feeding zone, and at least part and up to 90% by weight of the second LMW polyolefin resin is introduced in a second feeding zone different from the first feeding zone, wherein a remainder of the second LMW polyolefin resin in introduced in the first feeding zone;
wherein the second feeding zone is located downstream of the first feeding zone, and wherein polyolefin resin is moved from the first feeding zone, through a first melting and blending zone, to the second feeding zone, and through a second melting and blending zone; and
wherein a ratio the first HMW polyolefin resin/the second LMW polyolefin resin of the polyolefin product decreases as a function of residence time in the device.

2. The process according to claim 1 , wherein the first HMW polyolefin resin is a polyethylene polymerized in the presence of a Ziegler-Natta catalyst, and wherein the second LMW polyolefin resin is a polyethylene polymerized in the presence of a Ziegler-Natta catalyst, and wherein the polyolefin product is a multimodal polyethylene product.

3. The process according to claim 1 , wherein said polyolefin product is polyethylene.

4. The process according to claim 1 , wherein said polyolefin product has a multimodal weight distribution.

5. The process according to claim 1 , wherein said polyolefin product has a bimodal weight distribution.

6. The process according to claim 1 , wherein said device comprises at least one extruder or at least one mixer.

7. The process according to claim 1 , wherein said device comprises at least two extruders connected in series, or at least two mixers connected in series, or a combination thereof.

8. The process according to claim 1 , wherein a weight ratio of said first HMW polyolefin resin to said second LMW polyolefin resin in said polyolefin product is between 0.67 and 1.5.

9. The process according to claim 1 , wherein at least 10% by weight of the first HMW polyolefin resin is introduced in the first feeding zone.

10. The process according to claim 1 , wherein at least 10% and up to 90% by weight of the second LMW polyolefin resin is introduced in the second feeding zone.

11. The process according to claim 1 , wherein the physically melting and blending of said first HMW polyolefin resin and said second LMW polyolefin resin to produce the polyolefin product is performed continuously.

12. The process according to claim 1 , wherein polyolefin resin is continuously moved from the first feeding zone, through a first melting and blending zone, to the second feeding zone, and through a second melting and blending zone.

13. The process according to claim 1 , wherein said device comprises at least one extruder connected in series with at least one screw mixer.

14. The process according to claim 1 , wherein the polyolefin product comprises at least 40% by weight of the first HMW polyolefin resin.

15. The process according to claim 1 , wherein the polyolefin product comprises at most 60% by weight of the second LMW polyolefin resin.

16. The process according to claim 1 , wherein the first HMW polyolefin resin is a homopolymer.

17. The process according to claim 1 , wherein the first HMW polyolefin resin is polymerized in the presence of a chromium catalyst or metallocene catalyst.

18. The process according to claim 1 , wherein the second LMW polyolefin resin is polymerized in the presence of a Ziegler-Natta catalyst or a metallocene catalyst.

19. The process according to claim 1 , wherein the first HMW polyolefin resin is polymerized in the presence of a Ziegler-Natta catalyst or metallocene catalyst, and wherein the second LMW polyolefin resin is polymerized in the presence of a Ziegler-Natta catalyst or metallocene catalyst.

20. The process according to claim 1 , wherein the polyolefin product has an HLMI, measured at 190° C. under a 21.6 kg load according ASTM D-1238, of between 2 and 75 g/10 min.

21. The process according to claim 1 , wherein the polyolefin product is a homogenous polyolefin product.

Assignees

• Dewachter Daan
• Damme Eric
• Total Res & Technology Feluy

Inventors

• Dewachter Daan
• Damme Eric

Classifications

• C08L2666/06

  Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title

• B29C47/1081

  Operations & Transport · mapped topic

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title