High-fluidity non-caking dianhydrohexitol pellets

Patent metadata

Field	Value
Publication number	US-9334287-B2
Application number	US-201514834603-A
Country	US
Kind code	B2
Filing date	Aug 25, 2015
Priority date	Sep 30, 2010
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

Dianhydrohexitol pellets, whose fluidity is preserved even after lengthy storage, include between 90% and 100%, preferably between 95% and 100%, and more preferentially between 97% and 100% of dianhydrohexitols by weight, on a dry weight basis, and have the particularity of not being subject to caking. A process for preparing the dianhydrohexitol pellets is also described.

First claim

The invention claimed is:

1. A composition of high-fluidity and non-caking dianhydrohexitol pellets comprising between 90% and 100% by weight of dianhydrohexitols on a dry basis, wherein at least 90% by weight of said pellets exhibit a particle size on sieves of greater than or equal to 2000 μm and wherein said pellets are selected from the group consisting of tablets, pebbles, granules, bars, beads, other shapes obtained by pelleting, and mixtures thereof.

2. The composition of dianhydrohexitol pellets as claimed in claim 1 , wherein said pellets are of round, oval, square, rectangular, octagonal or polygonal shape.

3. The composition of dianhydrohexitol pellets as claimed in claim 1 , wherein said pellets are dome-shaped.

4. The composition of dianhydrohexitol pellets as claimed in claim 1 , comprising less than 2% by weight of anticaking agent on a dry basis.

5. The composition of dianhydrohexitol pellets as claimed in claim 1 , wherein said dianhydrohexitols are selected from the group consisting of isosorbide, isomannide, isoidide and the mixtures thereof.

6. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting:
a bulk density of between 0.80 and 1.00 g/ml,
a tapped density, evaluated according to a test A, of between 0.81 and 1.00 g/ml.

7. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a tapping, evaluated according to the test A, at most equal to 2%.

8. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a compressibility, evaluated according to a test B carried out at 20° C., of less than 5%.

9. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a score of 1 in a caking test C carried out at 20° C. for 2 or 4 weeks and a score of 1 or 2 in the caking test C carried out at 40° C. for 2 or 4 weeks.

10. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a pH of greater than or equal to 7 after 6 months of storage in a ventilated oven thermostatically controlled at a temperature of 50° C.

11. The composition of dianhydrohexitol pellets as claimed in claim 1 , wherein at least 95% by weight of the pellets exhibit a particle size on sieves of greater than or equal to 2000 μm.

12. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a moisture content of less than 1% by weight.

13. The composition of dianhydrohexitol pellets as claimed in claim 1 , said dianhydrohexitol pellets exhibiting a flat face and a convex face.

Assignees

• Roquette Freres

Inventors

• Ibert Mathias
• Saint Pol Jerome
• Wyart Herve

Classifications

• C07D493/04 Primary

  Ortho-condensed systems · CPC title

• B01J2/30

  using agents to prevent the granules sticking together; Rendering particulate materials free flowing in general, e.g. making them hydrophobic · CPC title

• B01J2/26

  on endless conveyor belts · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• B01J2/02

  by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops · CPC title