Process for the preparation of 2,3,3,3 tetrafluoropropene

Patent metadata

Field	Value
Publication number	US-9334208-B2
Application number	US-201114363918-A
Country	US
Kind code	B2
Filing date	Dec 14, 2011
Priority date	Dec 14, 2011
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene from 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane, comprising the following steps: (a) catalytic reaction of 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF into a reaction mixture comprising HCl, 2-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, unreacted HF, and optionally 1,1,1,2,2-pentafluoropropane; (b) separating the reaction mixture into a first stream comprising HCl and 2,3,3,3-tetrafluoropropene and a second stream comprising HF, 2-chloro-3,3,3-trifluoropropene and optionally 1,1,1,2,2-pentafluoropropane; (c) catalytic reaction of the second stream into a reaction mixture comprising 2,3,3,3-tetrafluoropropene, HCl, unreacted 2-chloro-3,3,3-trifluoropropene, unreacted HF and optionally 1,1,1,2,2-pentafluoropropane and (d) feeding the reaction mixture of step (c) directly without separation to step (a).

First claim

The invention claimed is:

1. A process for preparing 2,3,3,3-tetrafluoropropene, comprising:
(a) catalytically reacting 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF in a gas phase to produce a first reaction mixture comprising HCl, 2-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, unreacted HF and optionally 1,1,1,2,2-pentafluoropropane;
(b) separating the first reaction mixture into a first stream comprising HCl and 2,3,3,3-tetrafluoropropene and a second stream comprising HF, 2-chloro-3,3,3-trifluoropropene and optionally 1,1,1,2,2-pentafluoropropane;
(c) catalytically reacting the second stream in a gas phase to produce a second reaction mixture comprising 2,3,3,3-tetrafluoropropene, HCl, unreacted 2-chloro-3,3,3-trifluoropropene and HF and optionally 1,1,1,2,2-pentafluoropropane; and
(d) feeding the second reaction mixture of step (c) directly to step (a).

2. The process according to claim 1 , wherein the catalyst in step (a) and/or step (c) is a chromium based catalyst.

3. The process according to claim 1 , wherein the catalyst in step (a) and/or step (c) is a mixed catalyst.

4. The process according to claim 1 , wherein the catalyst in step (a) and/or step a supported catalyst.

5. The process according to claim 1 , wherein step (a) and/or step (c) is carried out in the presence of oxygen or chlorine.

6. The process according to claim 1 , wherein step (a) and/or step (c) is carried out at a temperature of 100 to 500° C.

7. The process according to claim 1 , wherein step (a) and/or step (c) is carried out at a molar ratio of HF:Organics from 4:1 to 100:1.

8. The process according to claim 5 , wherein the molar ratio of oxygen: Organics in step (a) and/ or step (c) is 0.005 to 2.

9. The process according to claim 1 , wherein step (b) can be performed at a temperature of −90 to 150° C. and a pressure of 0.1 to 50 bar abs.

Assignees

• Deur-Bert Dominique
• Collier Bertrand
• Wendlinger Laurent
• Arkema France

Inventors

• Deur-Bert Dominique
• Collier Bertrand
• Wendlinger Laurent

Classifications

• B01J37/12

  Oxidising · CPC title

• C07C17/383

  by distillation · CPC title

• B01J23/26

  Chromium · CPC title

• B01J27/132

  with chromium, molybdenum, tungsten or polonium · CPC title

• B01J37/26

  Fluorinating · CPC title