Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends

Patent metadata

Field	Value
Publication number	US-9334203-B2
Application number	US-201313955515-A
Country	US
Kind code	B2
Filing date	Jul 31, 2013
Priority date	Jun 16, 2009
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

This disclosure provides for alpha olefin oligomers and polyalphaolefins (or PAOs) and methods of making the alpha olefin oligomers and PAOs. This disclosure encompasses metallocene-based alpha olefin oligomerization catalyst systems, including those that include at least one metallocene and an activator comprising a solid oxide chemically-treated with an electron withdrawing anion. The alpha olefin oligomers and PAOs prepared with these catalyst systems can have a high viscosity index combined with a low pour point, making them particularly useful in lubricant compositions and as viscosity modifiers.

First claim

What is claimed:

1. A composition comprising a polyalphaolefin, the polyalphaolefin being produced from a C 6 to C 16 normal alpha olefin comprising at least 82.5 weight percent of a C 8 normal alpha olefin, the polyalphaolefin comprising:
a) less than 1 weight % saturated alpha olefin monomer;
b) less than 3 weight % saturated dimers; and
c) greater than 80 weight % saturated higher oligomers
and having
i) a 100° C. kinematic viscosity of at least 25 cSt;
ii) a viscosity index greater than 160;
iii) a pour point less than −35° C.; and
iv) no discernable crystallization as determined by differential scanning calorimetry using ASTM D 3418.

2. The composition of claim 1 , wherein the polyalphaolefin comprises:
a) less than 0.5 weight % saturated alpha olefin monomer;
b) less than 1 weight % saturated dimers; and
c) at least 88 weight % saturated higher oligomers.

3. The composition of claim 1 , wherein the polyalphaolefin has a kinematic viscosity from 25 cSt to 225 cSt.

4. The composition of claim 1 , wherein the polyalphaolefin has RPVOT as measured by ASTM D2272 in the presence of 0.5 weight % of an antioxidant of at least 2,000, wherein the antioxidant contains at least 90 weight % N-(dodecylphenyl)naphthalen-1-amine and from greater than 5 weight % to less than 10 weight % N-1-naphthylaniline.

5. The composition of claim 1 , wherein the C 6 to C 16 normal alpha olefin comprises at least 90 weight percent of the C 8 normal alpha olefin.

6. The composition of claim 5 , wherein the polyalphaolefin comprises:
a) less than 0.5 weight % saturated alpha olefin monomer;
b) less than 1 weight % saturated dimers; and
c) at least 88 weight % saturated higher oligomers;
and wherein
i) the 100° C. kinematic viscosity ranges from 30 cSt to 50 cSt;
ii) the viscosity index is greater than 160; and
iii) the pour point is less than −40° C.

7. The composition of claim 5 , wherein the polyalphaolefin comprises:
a) less than 0.5 weight % saturated alpha olefin monomer;
b) less than 1 weight % saturated dimers; and
c) at least 88 weight % saturated higher oligomers; and
and wherein
i) the 100° C. kinematic viscosity ranges from 80 cSt to 140 cSt;
ii) the viscosity index is greater than 160; and
iii) the pour point is less than −35° C.

8. The composition of claim 5 , wherein the polyalphaolefin has a Bernoulli index less than 1.65.

9. A composition comprising a polyalphaolefin, the polyalphaolefin being produced from a C 6 to C 16 normal alpha olefin comprising at least 80 weight percent of a C 8 normal alpha olefin, the polyalphaolefin comprising:
a) less than 1 weight % saturated alpha olefin monomer;
b) less than 3 weight % saturated dimers; and
c) greater than 80 weight % saturated higher oligomers
and having
i) a 100° C. kinematic viscosity of at least 25 cSt;
ii) a viscosity index greater than 150; and
iii) a pour point less than 0° C.; and
iv. a Bernoulli index less than 1.65.

10. A composition comprising an alpha olefin oligomer product, the alpha olefin oligomer product being produced from a C 6 to C 16 normal alpha olefin comprising at least 90 weight percent of a C 8 normal alpha olefin, the alpha olefin oligomer product comprising:
a) less than 1 weight % residual alpha olefin monomer;
b) less than 3 weight % dimers; and
c) greater than 80 weight % higher oligomers;
and having
i) a 100° C. kinematic viscosity of at least 25 cSt; and
ii) a viscosity index greater than 170.

11. The composition of claim 10 , wherein the alpha olefin oligomer product comprises:
a) less than 0.5 weight % residual alpha olefin monomer;
b) less than 1 weight % dimers; and
c) greater than 88 weight % higher oligomers; and
wherein the alpha olefin oligomer product has
i) a 100° C. kinematic viscosity from 30 cSt to 50 cSt; and
ii) a viscosity index greater than 170.

12. The composition of claim 10 , wherein the alpha olefin oligomer product comprises:
a) less than 0.5 weight % residual alpha olefin monomer;
b) less than 1 weight % dimers; and
c) greater than 80 weight % higher oligomers;
and having
i) a 100° C. kinematic viscosity from 80 cSt to 140 cSt; and
ii) a viscosity index greater than 175.

13. The composition of claim 9 , wherein the polyalphaolefin has no discernible crystallization as determined by differential scanning calorimetry using ASTM D 3418.

14. The composition of claim 9 , wherein:
i) the 100° C. kinematic viscosity ranges from 40 cSt to 80 cSt;
ii) the viscosity index ranges from 170 to 220; and
iii) the pour point ranges from −30° C. to −90° C.

15. The composition of claim 9 , wherein:
i) the 100° C. kinematic viscosity ranges from 80 cSt to 120 cSt;
ii) the viscosity index ranges from 170 to 220; and
iii) the pour point ranges from −30° C. to −90° C.

16. The composition of claim 9 , wherein:
i) the 100° C. kinematic viscosity ranges from 130 cSt to 170 cSt;
ii) the viscosity index ranges from 170 to 220; and
iii) the pour point ranges from −30° C. to −90° C.

17. The composition of claim 10 , wherein:
i) the 100° C. kinematic viscosity ranges from 40 cSt to 80 cSt; and
ii) the viscosity index ranges from 175 to 220.

18. The composition of claim 10 , wherein:
i) the 100° C. kinematic viscosity ranges from 80 cSt to 120 cSt; and
ii) the viscosity index ranges from 175 to 220.

19. The composition of claim 10 , wherein:
i) the 100° C. kinematic viscosity ranges from 130 cSt to 170 cSt; and
ii) the viscosity index ranges from 175 to 220.

Assignees

• Chevron Phillips Chemical Co

Inventors

• Small Brooke L
• Hope Kenneth D
• Yang Qing
• Masino Albert P
• Mcdaniel Max P
• Buck Richard M
• Beaulieu William B
• Baralt Eduardo J
• Netemeyer Eric J
• Kreischer Bruce

Classifications

• C10N2030/74

  Noack Volatility · CPC title

• C10N2020/017

  Specific gravity or density · CPC title

• C10N2020/071

  Branched chain compounds · CPC title

• C10N2070/00

  Specific manufacturing methods for lubricant compositions · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title