Catalytic ink preparation method

Patent metadata

Field	Value
Publication number	US-9331340-B2
Application number	US-201214346792-A
Country	US
Kind code	B2
Filing date	Aug 14, 2012
Priority date	Sep 26, 2011
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

A catalytic ink preparation method comprises mixing a first ion conducting body and a catalyst, preparing a first ink, and concentrating the first ink. The method is characterized by further comprising a step of adding a second ion conducting body to the concentrated first ink. With such a catalytic ink preparation method, the quantity of solvent in the first ion conducting body is reduced by concentration. In other words, the first ion conducting body adheres to the catalyst, and re-dissolution is not prone to occurring with the first ion conducting body when the second ion conducting body is added. Thus, it is possible to efficiently manufacture an electrode catalyst in which a significant part of the surface of the catalyst is covered with two ionomer layers, and there is almost no portion which is covered with only one ionomer layer.

First claim

The invention claimed is:

1. A catalytic ink preparation method comprising:
mixing a first ion conductor and a catalyst to prepare a first ink;
concentrating the first ink; and
adding a second ion conductor to the concentrated first ink.

2. The catalytic ink preparation method according to claim 1 , wherein the concentrating the first ink is performed so that a solid content concentration of the first ink becomes 25 to 90% by mass.

3. The catalytic ink preparation method according to claim 1 , further comprising: stirring the concentrated first ink before adding the second ion conductor,
wherein the stirring is performed so that at least one of values of a mean volume diameter and a mean area diameter based on a particle size distribution of the catalyst covered with the first ion conductor after the stirring is equal to or smaller than the value before the concentrating the first ink is performed.

4. A method for manufacturing the electrode catalyst, using the catalytic ink obtained by the preparation method according to claim 1 .

5. The catalytic ink preparation method according to claim 1 , wherein the concentrating the first ink reduces a quantity of solvent in the first ion conductor.

6. The catalytic ink preparation method according to claim 2 , wherein the concentrating the first ink increases the solid content concentration of the first ink.

7. The catalytic ink preparation method according to claim 6 , wherein the concentrating the first ink increases the solid content concentration of the first ink from between 3% and 25% by mass to greater than 25% by mass.

8. The catalytic ink preparation method according to claim 7 , wherein the concentrating the first ink increases the solid content concentration of the first ink from between 5% and 20% by mass.

9. The catalytic ink preparation method according to claim 7 , wherein the concentrating the first ink increases the solid content concentration of the first ink to between 30% and 50% by mass.

10. The catalytic ink preparation method according to claim 9 , wherein the concentrating the first ink increases the solid content concentration of the first ink to between 31% and 38% by mass.

Assignees

• Toyoshima Kenichi
• Horibe Norifumi
• Terasaki Takayuki
• Nissan Motor

Inventors

• Toyoshima Kenichi
• Horibe Norifumi
• Terasaki Takayuki

Classifications

• H01M4/88

  Processes of manufacture · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/8657

  layered · CPC title

• H01M4/8663

  Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers · CPC title

• C09D11/52 Primary

  Electrically conductive inks · CPC title