Solid solution lithium-containing transition metal oxide and lithium ion secondary battery

Patent metadata

Field	Value
Publication number	US-9331334-B2
Application number	US-201314375248-A
Country	US
Kind code	B2
Filing date	Jan 31, 2013
Priority date	Feb 3, 2012
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

A solid solution lithium-containing transition metal oxide includes a compound represented by chemical formula (1): Li 1.5 [Ni a Co b Mn c [Li] d ]O 3 , where a, b, c and d satisfy relationships: 0.39≦a<0.75, 0≦b≦0.18, 0<c<1.00, 0.05≦d≦0.25, and a+b+c+d=1.5. The use of the solid solution lithium-containing transition metal oxide in a lithium ion secondary battery can contribute to decreasing the amount of hysteresis of the battery, achieving high energy efficiency, and ensuring a high discharge capacity.

First claim

The invention claimed is:

1. A solid solution lithium-containing transition metal oxide comprising a compound represented by chemical formula (1):
Li 1.5 [Ni a Co b Mn c [Li] d ]O 3   (1)

wherein a, b, c and d satisfy relationships: 0.39≦a<0.75, 0≦b≦0.18, 0<c<1.00, 0.05≦d≦0.25, and a+b+c+d=1.5, the oxide having a structure obtained by pretreatment done by repeating a charge and discharge cycle with respect to a counter electrode to gradually increase the upper limit potential, each cycle charging at a rate of 0.1 C until an upper voltage of between 4.3 or greater and less than 4.8 and discharging at the rate of 0.1 C until a minimum voltage is reached, the upper voltage increasing with each cycle.

2. The solid solution lithium-containing transition metal oxide according to claim 1 , wherein, in the chemical formula (1), a and d satisfy 0.42≦a<0.75 and 0.05≦d≦0.23 respectively.

3. The solid solution lithium-containing transition metal oxide according to claim 2 , wherein, in the chemical formula (1), b satisfies 0≦b≦0.11.

4. The solid solution lithium-containing transition metal oxide according to claim 3 , wherein, in the chemical formula (1), a and d satisfy 0.48≦a<0.75 and 0.10≦d≦0.23 respectively.

5. The solid solution lithium-containing transition metal oxide according to claim 4 , wherein, in the chemical formula (1), b satisfies 0.02≦b≦0.07.

6. A lithium ion secondary battery comprising the solid solution lithium-containing transition metal oxide according to claim 1 .

7. The solid solution lithium-containing transition metal oxide according to claim 1 , wherein an amount of hysteresis of a lithium ion secondary battery to which the compound is applied as a positive electrode active material is in a range from 0.1 V to 0.25 V.

8. The solid solution lithium-containing transition metal oxide according to claim 1 , wherein the pretreatment includes the following charge and discharge cycles:
a first cycle charged at a rate of 0.1 C until a voltage of 4.45 V is reached and then discharged at the rate of 0.1 C until a voltage of 2.0 V is reached;
a second cycle charged at the rate of 0.1 C until a voltage of 4.55 V is reached and then discharged at the rate of 0.1 C until the voltage of 2.0 V is reached;
a third cycle charged at the rate of 0.1 C until a voltage of 4.65 V is reached and then discharged at the rate of 0.1 C until the voltage of 2.0 V is reached; and
a fourth cycle charged at the rate of 0.1 C until a voltage of 4.75 V is reached and then discharged at the rate of 0.1 C until the voltage of 2.0 V is reached.

Assignees

• Nissan Motor

Inventors

• Kaburagi Tomohiro
• Osawa Yasuhiko
• Ito Atsushi

Classifications

• C01G53/82 Primary

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M4/485 Primary

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title