Transparent electrode and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-9330811-B2
Application number	US-201314232070-A
Country	US
Kind code	B2
Filing date	May 17, 2013
Priority date	Jun 6, 2012
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

There is provided a transparent electrode comprising a supporting substrate, a first transparent electrically-conductive film provided on the supporting substrate, a transparent insulating film provided on the first transparent electrically-conductive film, and a second transparent electrically-conductive film provided on the transparent insulating film. In the transparent electrode of the present invention, all of the first transparent electrically-conductive film, the second transparent electrically-conductive film and the transparent insulating film provided therebetween comprise a metal compound, and the first transparent electrically-conductive film and the second transparent electrically-conductive film have a crystalline structure, whereas the transparent insulating film has an amorphous structure.

First claim

The invention claimed is:

1. A transparent electrode comprising:
a supporting substrate;
a first transparent electrically-conductive film provided on the supporting substrate;
a transparent insulating film provided on the first transparent electrically-conductive film; and
a second transparent electrically-conductive film provided on the transparent insulating film,
wherein all of the first transparent electrically-conductive film, the second transparent electrically-conductive film and the transparent insulating film provided therebetween comprise a metal compound, and
wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film have a crystalline structure, whereas the transparent insulating film has an amorphous structure.

2. The transparent electrode according to claim 1 , wherein a metal element, which constitutes the metal compound, is the same among the first transparent electrically-conductive film, the second transparent electrically-conductive film, and the transparent insulating film.

3. The transparent electrode according to claim 1 , wherein the metal compound is a zinc compound.

4. The transparent electrode according to claim 2 , wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film at least comprise a zinc oxide, whereas the transparent insulating film at least comprises a zinc hydroxide.

5. The transparent electrode according to claim 1 , wherein the crystalline structure of the first transparent electrically-conductive film and the second transparent electrically-conductive film is in a form of needle.

6. The transparent electrode according to claim 5 , wherein the crystalline structure in the form of needle is oriented in the direction perpendicular to the supporting substrate.

7. The transparent electrode according to claim 5 , wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film at least comprise a zinc oxide, whereas the transparent insulating film at least comprises a zinc hydroxide, and
wherein the zinc hydroxide of the transparent insulating film is in a form of sphere.

8. The transparent electrode according to claim 1 , wherein each thickness of the first transparent electrically-conductive film and the second transparent electrically-conductive film is 2 μm or less.

9. The transparent electrode according to claim 1 , wherein at least one of the first transparent electrically-conductive film, the second transparent electrically-conductive film, and the transparent insulating film includes a Group IIIB element.

10. The transparent electrode according to claim 9 , wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film include the Group IIIB element.

11. The transparent electrode according to claim 10 , wherein the Group IIIB element of the first transparent electrically-conductive film and the Group IIIB element of the second transparent electrically-conductive film are different in their kinds from each other.

12. The transparent electrode according to claim 1 , wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film have a patterned form.

13. The transparent electrode according to claim 1 , further comprising a gas barrier film between the supporting substrate and the first transparent electrically-conductive film.

14. The transparent electrode according to claim 1 , wherein at least one additional transparent insulating film and at least one additional transparent electrically-conductive film are alternately provided on the second transparent electrically-conductive film, and thereby there is provided a laminate structure in which a plurality of transparent electrically-conductive films and a plurality of transparent insulating films are alternately disposed on the supporting substrate.

15. The transparent electrode according to claim 1 , wherein the transparent electrode is used for a touch panel.

16. A method for manufacturing a transparent electrode, comprising sequentially applying a first transparent electrically-conductive film raw material, a transparent insulating film raw material, and a second transparent electrically-conductive film raw material with respect to a supporting substrate heated at a predetermined temperature to form a lamination of a first transparent electrically-conductive film, a transparent insulating film, and a second transparent electrically-conductive film on the supporting substrate, the method comprising the steps of:
(i) applying the first transparent electrically-conductive film raw material onto the supporting substrate, and thereby forming the first transparent electrically-conductive film on the supporting substrate;
(ii) applying the transparent insulating film raw material onto the first transparent electrically-conductive film, and thereby forming the transparent insulating film on the first transparent electrically-conductive film; and
(iii) applying the second transparent electrically-conductive film raw material onto the transparent insulating film, and thereby forming the second transparent electrically-conductive film on the transparent insulating film,
wherein all of the first transparent electrically-conductive film raw material, the transparent insulating film raw material and the second transparent electrically-conductive film raw material comprise an organic metal compound and an organic solvent, and
wherein the first transparent electrically-conductive film and the second transparent electrically-conductive film, which are to be formed in the steps (i) and (iii), have a crystalline structure, whereas the transparent insulating film, which is to be formed in the step (ii), has an amorphous structure.

17. The method according to claim 16 , a metal element, which constitutes the organic metal compound, is the same among the first transparent electrically-conductive film raw material, the second transparent electrically-conductive film raw material, and the transparent insulating film raw material.

18. The method according to claim 16 , wherein an organic zinc compound is used as the organic metal compound.

19. The method according to claim 16 , wherein a heating temperature of the supporting substrate is changed between in the step (i) and in the step (ii), and between in the step (iii) and in the step (ii).

20. The method according to claim 19 , wherein the heating temperature of the supporting substrate in the steps (i) and (iii) is adjusted to 100° C. or higher, whereas the heating temperature of the supporting substrate in the step (ii) is adjusted to lower than 100° C.

21. The method according to claim 20 , wherein the heating temperature of the supporting substrate in the steps (i) to (iii) is 200° C. or lower.

22. The method according to claim 16 , wherein the applications of the first transparent electrically-conductive film raw material, the transparent insulating film raw material and the second transparent electrically-conductive film raw material are performed by a spray atomization.

23. The method according to claim 22 , wherein a spray nozzle is used in the spray atomization such that the spray nozzle is inclined with respect to the supporting substrate.

24. The method according to claim 16 , further comprising the step of irradiating the first transparent

Assignees

• Panasonic Ip Man Co Ltd
• Panasonic Ip Man Co Ltd

Inventors

• Ichiryu Takashi
• Yamashita Yoshihisa
• Nakatani Seiichi

Classifications

• H01B5/14 Primary

  comprising conductive layers or films on insulating-supports · CPC title

• G06F3/041 Primary

  Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means · CPC title

• H10F77/251

  comprising zinc oxide [ZnO] · CPC title

• H10F77/244

  made of transparent conductive layers, e.g. transparent conductive oxide [TCO] layers · CPC title

• H10F71/1385

  Etching transparent electrodes · CPC title