Emulsion aggregation process

Patent metadata

Field	Value
Publication number	US-9329508-B2
Application number	US-201313850654-A
Country	US
Kind code	B2
Filing date	Mar 26, 2013
Priority date	Mar 26, 2013
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

The method of manufacturing toners disclosed herein includes a continuous temperature ramp and coalescence process that involves continuously passing toner slurry, such as an aggregated toner slurry, through at least one heat exchanger before being subjected to a cooling step. The heat exchanger is pressurized, so the temperature of the slurry may be increased above the atmospheric boiling point of water without boiling the water component of the slurry. Because of these higher temperatures, the coalescence step can be completed more quickly than in conventional batch processes. More than two heat exchangers may be connected in the coalescence step, yielding multiple ramping/cooling temperature steps, ability to inject components, or recycling heat from the process to reduce energy consumption.

First claim

What is claimed is:

1. A method of making toner particles, the method comprising:
forming a slurry comprising particles by mixing together an emulsion comprising:
a latex of at least one polymer resin,
optionally a wax dispersion,
optionally a colorant dispersion, and
optional additives dispersions;

aggregating the particles from the slurry;
optionally adding a second polymer latex and further aggregating the particles to form a shell on the particles;
freezing aggregation of the particles;
coalescing the aggregated particles to form toner particles by continuously passing the particles through a system comprises at least two heat exchangers and comprises a first heat exchanger and a second heat exchanger; wherein the first heat exchanger is heated to a temperature greater than the glass transition temperature of the resin but less than the temperature of the second heat exchanger, and the second heat exchanger is heated to a temperature of from about 100° C. to about 150° C.; and
recovering toner particles from the system comprising at least two heat exchangers;
the circularity of the particles before entering the system comprising at least one heat exchanger is between about 0.900 and about 0.940, and the circularity of the toner particles recovered from the system is between about 0.940 and about 0.999 and wherein the circularity is reached with a residence time of from 1 second to 15 minutes, and
after the aggregated particles are coalesced to form toner particles, the toner particles are cooled;

wherein the coalescing is completed within the residence time;
wherein the aggregated particles are continuously added to the system and the toner particles are recovered continuously from the system.

2. The method according to claim 1 , wherein the process further comprising preheating the particles, and further wherein aggregating the particles, freezing the particles, and preheating the particles to a temperature greater than the glass transition of the resin but less than the coalescence temperature all takes place within the same vessel.

3. The method according to claim 1 , wherein the temperature of the first heat exchanger preheats the toner slurry to a temperature of from about 5° C. greater than the glass transition temperature of the resin to about 30° C. greater than the glass transition temperature of the resin.

4. The method according to claim 1 , wherein at least one of the at least two heat exchangers is at a temperature of from about 100° C. to about 115° C.,
and at least one of the at least two heat exchangers is at a temperature of from about 115° C. to about 150° C.

5. The method according to claim 1 , wherein the system comprises at least three heat exchangers and comprises a first heat exchanger, a second heat exchanger and a third heat exchanger; and further wherein
the first heat exchanger of the at least three heat exchangers is at a temperature of from about 100° C. to about 115° C.;
the second heat exchanger of the at least three heat exchangers is at a temperature of from about 115° C. to about 150° C.; and
the third heat exchanger of the at least three heat exchangers is at a temperature that quenches the temperature of the toner slurry after it exits the second heat exchanger.

6. The method according to claim 1 , wherein the temperature of one of the at least two heat exchangers is between about 120° C. and about 145° C.

7. The method according to claim 1 , wherein the temperature of one of the at least two heat exchangers is between about 130° C. and about 140° C.

8. The method according to claim 1 , wherein one of the at least two heat exchangers is pressurized to a pressure from 1% to 20% greater than the vapor pressure of water at the temperature of the heat exchanger.

9. A method of making toner particles, the method comprising:
forming a slurry comprising particles by mixing together at least one emulsion comprising:
a latex of at least one polymer resin,
optionally a wax dispersion,
optionally a colorant dispersion, and
optional additives dispersions;

aggregating the particles from the slurry;
optionally adding a second polymer latex and further aggregating the particles to form a shell on the particles;
freezing aggregation of the particles;
coalescing the aggregated particles to form toner particles by continuously passing the particles through a system comprising at least three heat exchangers; and
recovering toner particles from the system comprising at least three heat exchangers; wherein
the at least three heat exchangers comprises a first, a second and a third heat exchangers; wherein the first heat exchanger and the third heat exchanger are connected in a closed loop, and the second heat exchanger is located between the first heat exchanger and the third heat exchanger;
wherein the second heat exchanger of the at least three heat exchangers is at a temperature of from about 100° C. to about 150° C.;
the circularity of the particles before entering the heat exchanger system is between about 0.900 and about 0.940, and the circularity of the toner particles recovered from the system is between about 0.940 and about 0.999 and wherein the circularity is reached with a residence time of from 1 second to 15 minutes; and
after the aggregated particles are coalesced to form toner particles, the toner particles are cooled;
wherein the coalescing is completed within the residence time;

wherein the aggregated particles are continuously added to the system and the toner particles are recovered continuously from the system.

10. The method according to claim 9 , wherein the system is pressurized.

11. The method according to claim 9 , wherein the first heat exchanger increases the temperature of the incoming slurry before it enters the second heat exchanger, and the third heat exchanger decreases the temperature of the slurry after it exits the second heat exchanger.

Assignees

• Xerox Corp

Inventors

• Lawton David John William
• Kurceba David R
• Lee Frank Ping-Hay
• Mcneil Daniel Mcdougall
• Faucher Santiago

Classifications

• G03G9/08711

  with esters of acrylic or methacrylic acid · CPC title

• G03G9/0827

  characterised by their shape, e.g. degree of sphericity · CPC title

• G03G9/0825 Primary

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title