Methods, apparatuses and kits for collecting chemical samples

Patent metadata

Field	Value
Publication number	US-9329106-B2
Application number	US-201414193300-A
Country	US
Kind code	B2
Filing date	Feb 28, 2014
Priority date	Feb 28, 2014
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

Methods, apparatuses, and kits for collecting chemical samples are provided. In one embodiment, a method for collecting a sample of a chemical from a vessel includes connecting a sampling chamber and a removal chamber in fluid communication with the vessel and flowing a liquid phase of the chemical from the vessel through the sampling chamber and the removal chamber. The method isolates a first volume of the liquid phase in the sampling chamber and removes a second volume of the liquid phase from the removal chamber. Further, the method includes establishing fluid communication between the sampling chamber and the removal chamber and filling the removal chamber with a portion of the first volume to form a vapor phase of the chemical in the sampling chamber. Also, the method includes isolating the sample including the vapor phase and a remaining portion of the liquid phase in the sampling chamber.

First claim

What is claimed is:

1. A method for collecting a sample of a chemical from a vessel, the method comprising the steps of:
connecting a sampling chamber and a removal chamber in fluid communication with the vessel;
flowing a liquid phase of the chemical from the vessel through the sampling chamber and the removal chamber;
isolating a first volume of the liquid phase of the chemical in the sampling chamber comprising isolating a first volume of the liquid phase of the chemical equal to a sampling chamber capacity;
removing a second volume of the liquid phase of the chemical from the removal chamber comprising removing a second volume of the liquid phase of the chemical equal to a removal chamber capacity, wherein the second volume is less than the first volume;
establishing fluid communication between the sampling chamber and the removal chamber and filling the removal chamber with a portion of the first volume of the liquid phase of the chemical to form a vapor phase of the chemical in the sampling chamber; and
isolating the sample including the vapor phase of the chemical and a remaining portion of the liquid phase of the chemical in the sampling chamber.

2. The method of claim 1 wherein flowing the liquid phase of the chemical from the vessel through the sampling chamber and the removal chamber comprises flowing the liquid phase of the chemical in a downstream direction from the vessel through the removal chamber, and from the removal chamber through the sampling chamber, and wherein filling the removal chamber with a portion of the first volume of the liquid phase of the chemical comprises flowing the portion of the first volume of the liquid phase of the chemical in an upstream direction from the sampling chamber to the removal chamber.

3. The method of claim 1 wherein:
connecting a sampling chamber and a removal chamber in fluid communication with the vessel comprises interconnecting valves with the vessel, the sampling chamber, and the removal chamber;
flowing a liquid phase of the chemical from the vessel through the sampling chamber and the removal chamber comprises manipulating the valves to sequentially open flow of the liquid phase of the chemical in a downstream direction through the removal chamber and through the sampling chamber;
isolating a first volume of the liquid phase of the chemical in the sampling chamber comprises manipulating the valves to close flow of the liquid phase of the chemical out of and into the sampling chamber;
removing a second volume of the liquid phase of the chemical from the removal chamber comprises manipulating the valves to open flow of the second volume of the liquid phase of the chemical out of the removal chamber in an upstream direction to an exit vent;
establishing fluid communication between the sampling chamber and the removal chamber and filling the removal chamber with a portion of the first volume of the liquid phase of the chemical to form a vapor phase of the chemical in the sampling chamber comprises manipulating the valves to sequentially close flow of the liquid phase of the chemical upstream of the removal chamber and to open flow the liquid phase of the chemical between the sampling chamber and the removal chamber; and
isolating the sample including the vapor phase of the chemical and a remaining portion of the liquid phase of the chemical in the sampling chamber comprises manipulating the valves to close flow of the liquid phase of the chemical out of and into the sampling chamber.

4. The method of claim 1 wherein connecting a sampling chamber and a removal chamber in fluid communication with the vessel comprises connecting a multiple direction valve between the vessel, the removal chamber, and an exit vent, and wherein removing a second volume of the liquid phase of the chemical from the removal chamber comprises flowing the second volume of the liquid phase of the chemical through the multiple direction valve to the exit vent.

5. The method of claim 1 wherein connecting a sampling chamber and a removal chamber in fluid communication with the vessel comprises interconnecting a multiple direction valve between the vessel and the removal chamber to selectively control flow of the chemical from the vessel in a downstream direction, an upstream valve upstream of the sampling chamber to selectively control flow of the liquid phase of the chemical into the sampling chamber in the downstream direction and out of the sampling chamber in an upstream direction, and a downstream valve downstream of the sampling chamber to selectively control flow of the liquid phase of the chemical out of the sampling chamber in the downstream direction.

6. The method of claim 5 wherein flowing a liquid phase of the chemical from the vessel through the sampling chamber and the removal chamber comprises opening the multiple direction valve to flow from the vessel, opening the upstream valve and opening the downstream valve.

7. The method of claim 6 wherein isolating a first volume of the liquid phase of the chemical in the sampling chamber comprises sequentially closing the downstream valve and closing the upstream valve.

8. The method of claim 7 wherein removing a second volume of the liquid phase of the chemical from the removal chamber comprises opening the multiple direction valve to flow from the removal chamber to an exit vent.

9. The method of claim 8 wherein establishing fluid communication between the sampling chamber and the removal chamber and filling the removal chamber with a portion of the first volume of the liquid phase of the chemical to form a vapor phase of the chemical in the sampling chamber comprises sequentially closing the multiple direction valve to flow from the removal chamber and opening the upstream valve to permit flow from the sampling chamber to the removal chamber.

10. The method of claim 9 wherein isolating the sample including the vapor phase of the chemical and a remaining portion of the liquid phase of the chemical in the sampling chamber comprises closing the upstream valve.

11. The method of claim 1 wherein removing a second volume of the liquid phase of the chemical from the removal chamber comprises reducing a pressure in the removal chamber, and wherein establishing fluid communication between the sampling chamber and the removal chamber comprises equalizing pressure between the sampling chamber and the removal chamber.

Assignees

• Uop Llc

Inventors

• Leeton Eric

Classifications

• G01N2001/2071

  Removable sample bottle · CPC title

• G01N33/2823

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• G01N2001/205

  using a valve · CPC title

• Y10T436/25875

  Gaseous sample or with change of physical state · CPC title

• G01N1/2035 Primary

  by deviating part of a fluid stream, e.g. by drawing-off or tapping · CPC title