Pipeline hydrate inhibitor and method of reducing hydrates using the hydrate inhibitor

Patent metadata

Field	Value
Publication number	US-9328302-B2
Application number	US-201113271070-A
Country	US
Kind code	B2
Filing date	Oct 11, 2011
Priority date	Oct 27, 2010
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

Compositions and methods for reducing the formation of hydrates within subsea or over-land pipeline systems. The compositions and methods include the use of organic salt solutions, such as an acetate salt solution, to precondition, treat, and/or dewater the pipeline systems, or employ the use of the organic salt solutions during other pre-commissioning operations. An effective concentration of an organic salt solution acts to reduce hydrates and/or inhibit hydrate formation within the pipeline systems.

First claim

What is claimed is:

1. A method for reducing hydrate formation in a hydrocarbon production pipeline system, the method comprising:
introducing an aqueous composition comprising an acetate salt into the hydrocarbon production pipeline system;
hydrotesting the hydrocarbon production pipeline system, comprising the steps of:
filling the hydrocarbon production pipeline system with the aqueous composition comprising an acetate salt;
pressurizing the aqueous composition within the hydrocarbon production pipeline system; and
determining the integrity of the pipeline system; and

flowing a hydrocarbon through the hydrocarbon production pipeline system,
wherein the concentration of the acetate salt in the aqueous composition is adequate to reduce the formation of hydrates during hydrocarbon flow compared to hydrate formation that would occur if the acetate salt had not been introduced.

2. The method of claim 1 , further comprising:
passing a pipeline pig through the hydrocarbon production pipeline system, thereby removing bulk water from the hydrocarbon production pipeline system.

3. The method of claim 1 , wherein the aqueous composition comprises at least one ion selected from the group consisting of Li + , Na + , K + , Rd + , Cs + , Mg 2+ , Ca 2+ , Ba 2+ , Ti 4+ , Zr 4+ , Hf 4+ , Zn 2+ , La 3+ , Ce 4+ , Nd 3+ , Pr 2+ , Pr 3+ , Pr 4+ , Sm 2+ , Sm 3+ , Gd 3+ , Dy 2+ , Dy 3+ , NH 4 + , and mixtures or combinations thereof.

4. The method of claim 1 , wherein the acetate salt is sodium acetate.

5. The method of claim 4 , wherein the aqueous composition introduced into the hydrocarbon production pipeline system has a concentration of sodium acetate in water ranging from about 0.1% to about 50% of saturation of sodium acetate in water at ambient conditions before introducing the aqueous composition into the hydrocarbon production pipeline system.

6. The method of claim 4 , wherein the aqueous composition introduced into the hydrocarbon production pipeline system has a concentration of sodium acetate in water ranging from about 50% of saturation of sodium acetate in water at ambient conditions to about 0.25% less than saturation of sodium acetate in water at ambient conditions before introducing the aqueous composition into the hydrocarbon production pipeline system.

7. The method of claim 1 , wherein the acetate salt is potassium acetate.

8. The method of claim 7 , wherein the aqueous composition introduced into the hydrocarbon production pipeline system has a concentration of potassium acetate in water ranging from about 50% of saturation of potassium acetate in water at ambient conditions to about 0.25% less than saturation of potassium acetate in water at ambient conditions before introducing the aqueous composition into the hydrocarbon production pipeline system.

9. The method of claim 1 , wherein the hydrocarbon production pipeline system is a subsea hydrocarbon production pipeline system.

10. The method of claim 1 , wherein the hydrocarbon production pipeline system is an over-land hydrocarbon production pipeline system.

11. The method of claim 1 , wherein introducing an aqueous composition comprising an acetate salt into the hydrocarbon production pipeline system further comprises pumping at least first and second separated slugs of the aqueous composition into the hydrocarbon production pipeline system.

12. The method of claim 11 , wherein:
the first separated slug of the aqueous composition has a first concentration of the acetate salt;
the second separated slug of the aqueous composition has a second concentration of the acetate salt; and
the second concentration is greater than the first concentration.

13. The method of claim 11 , further comprising passing at least one pipeline pig through the hydrocarbon production pipeline system between the first and second separated slugs of the aqueous composition.

14. The method of claim 7 , wherein introducing an aqueous composition comprising potassium acetate into the hydrocarbon production pipeline system further comprises pumping at least first and second separated slugs of the aqueous composition into the hydrocarbon production pipeline system.

15. The method of claim 14 , wherein:
the first separated slug of the aqueous composition has a first concentration of potassium acetate salt;
the second separated slug of the aqueous composition has a second concentration of potassium acetate salt; and
the second concentration is greater than the first concentration.

16. The method of claim 14 , further comprising passing at least one pipeline pig through the hydrocarbon production pipeline system between the first and second separated slugs of the aqueous composition.

17. A method for reducing hydrate formation in a hydrocarbon production pipeline system, the method comprising:
introducing an aqueous composition comprising potassium acetate into the hydrocarbon production pipeline system, wherein the aqueous composition introduced into the hydrocarbon production pipeline system has a concentration of potassium acetate in water ranging from about 0.1% to about 50% of saturation of potassium acetate in water at ambient conditions before introducing the aqueous composition into the hydrocarbon production pipeline system; and
flowing a hydrocarbon through the hydrocarbon production pipeline system,
wherein the concentration of the acetate salt in the aqueous composition is adequate to reduce the formation of hydrates during hydrocarbon flow compared to hydrate formation that would occur if the acetate salt had not been introduced.

18. A method for reducing hydrate formation in a hydrocarbon production pipeline system, the method comprising:
introducing an aqueous composition comprising an acetate salt into the hydrocarbon production pipeline system by pumping at least first and second separated slugs of the aqueous composition into the hydrocarbon production pipeline system:
the first separated slug of the aqueous composition having a first concentration of acetate salt;
the second separated slug of the aqueous composition having a second concentration of acetate salt; and
the second concentration being greater than the first concentration, the first concentration of acetate salt in water ranging from about 0.1% to about 50% of saturation of acetate salt in water at ambient conditions before introducing the aqueous composition into the hydrocarbon production pipeline system; and

flowing a hydrocarbon through the hydrocarbon production pipeline system,
the first and second concentrations of acetate salt in the aqueous composition being adequate to reduce the formation of hydrates during hydrocarbon flow compared to hydrate formation that would occur if the acetate salt had not been introduced.

Assignees

• Casey Gregory E
• Hoover Angel
• Barden Andrew J
• Baker Hughes Inc

Inventors

• Casey Gregory E
• Hoover Angel
• Barden Andrew J

Classifications

• C09K8/52 Primary

  Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning · CPC title

• C10L3/107 Primary

  Limiting or prohibiting hydrate formation · CPC title

• F16L58/00

  Protection of pipes or pipe fittings against corrosion or incrustation (compound tubes F16L9/14) · CPC title

• E21B43/00

  Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells (applicable only to water E03B) · CPC title

• E21B37/06

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title