System and method for making renewable fuels

Patent metadata

Field	Value
Publication number	US-9328290-B2
Application number	US-201314035752-A
Country	US
Kind code	B2
Filing date	Sep 24, 2013
Priority date	Mar 24, 2011
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

Multiple catalytic processing stations enable a method for producing volatile gas streams from biomass decomposition at discrete increasing temperatures. These catalytic processing stations can be programmed to maximize conversion of biomass to useful renewable fuel components based on input feedstock and desired outputs.

First claim

The invention claimed is:

1. A method for converting biomass to renewable fuels, comprising:
providing a system containing a number of processing stations (N) in communication with a series of catalysts;
heating a biomass within the stations at a starting temperature (Tstart) to produce a volatile and a non-volatile component, said biomass and said heating selected to provide volatile components suitable for producing at least one renewable fuel; and
subjecting the volatile components generated in at least one station through the series of catalysts to produce at least one renewable fuel.

2. The method of claim 1 , wherein said series of catalysts is selected based on said starting temperature.

3. The method of claim 1 , wherein said series of catalyst is based on the biomass composition.

4. The method of claim 3 , wherein the biomass is a lipid-rich biomass and the volatile components from the lipid-rich biomass is contacted with a dehydration catalyst to produce a product which on cooling to a temperature range of 1-20° C. produces a second volatile component, a first renewable fuel and water.

5. The method of claim 3 , wherein the biomass is a hemicellulose-rich biomass and a volatile components from the hemicellulose-rich biomass is contacted directly with an aromatization catalyst to produce a product which on cooling to a temperature of 0-5° C. produces a second volatile component, a first renewable fuel and water.

6. The method of claim 3 , wherein the biomass is a lignin-rich biomass and the volatile component from the lignin-rich biomass is contacted with a dehydration catalyst to produce a product which on cooling to 2-20° C. produces a second volatile component, a renewable fuel and water.

7. The method of claim 1 , further comprising incrementing an individual processing station temperature by increments (ΔT) to produce a volatile and a non-volatile component, said biomass and said incremental heating selected to provide incremental volatile components suitable for producing at least one renewable fuel.

8. The method of claim 7 , wherein the increment is in the range of 0° C. to 200° C.

9. A method for converting biomass, comprising:
providing a device containing a number of processing stations (N) and a series of catalysts;
subjecting biomass within the stations to at least one starting temperature (Tstart); and
incrementing an individual processing station temperature by increments (ΔT) to produce a volatile and a non-volatile component.

10. The method of claim 9 , further comprising subjecting the volatile components generated in each station through a sequence of catalysts to produce at least one-renewable fuel.

11. The method of claim 9 , further comprising:
identifying the temperature of an individual processing station after a temperature increment;
routing the volatile components generated at the individual processing station through a series of catalysts, said series of catalysts determined by the incremented temperature.

12. The method of claim 10 , wherein the sequence of catalyst contact is determined by renewable fuel yield or by temperature of devolatization of biomass components.

13. The method of claim 1 or 9 , wherein a co-solvent is added to volatile components or added to at least one of the processing stations, and the co-solvent comprises at least one co-solvent selected from the group consisting of alcohols, aldehydes, ketones, ethers, carboxylic acids, and hydrocarbons, and wherein the co-solvent is generated via a syngas conversion catalyst.

14. The method of claim 1 or 9 , wherein biomass is selected from the group consisting of lipids, hemicellulose, cellulose and lignins.

15. A system for the conversion of biomass to combustible fuels, comprising: a device containing a number of processing stations (N) and a series of catalysts;
a heater for subjecting biomass within the stations to at least one starting temperature (Tstart);
a controller for incrementing an individual processing station temperature by increments (ΔT) to produce a volatile and a non-volatile component;
series of catalysts for contacting the volatile components generated in each station to produce at least one renewable fuel; and
a processor for receiving data related to one or more of renewable fuel yield or temperature of devolatization of biomass components and determining a sequence of catalyst contacts.

16. A system for converting biomass to a renewable fuel, comprising:
a device containing a number of processing stations (N) and a series of catalysts selected from the group consisting of catalytic dehydration, catalytic aromatization and catalytic gas-upgrading;
means for subjecting biomass within the stations to at least one starting temperature (Tstart);
means for incrementing an individual processing station temperature by increments (ΔT) to produce a volatile and a non-volatile component; and
means for subjecting the volatile components generated in each station through the series of catalysts to produce at least one renewable fuel.

17. The system of claim 15 , wherein the series of catalysts are selected from the group consisting of catalytic dehydration, catalytic aromatization and catalytic gas-upgrading.

18. The system of claim 15 or 16 , wherein N ranges from 2 to 1000, and wherein Tstart ranges from 100° C. to 1000° C.

19. The system of claim 15 or 16 , wherein the temperature increment (ΔT) ranges from 0° C. to 200° C., and wherein biomass moisture content is less than 15%.

20. The system of claim 17 , wherein
the dehydration catalyst comprises any acid catalyst or combination of acid catalysts, or
the aromatization catalyst is selected from the group consisting of MFI type zeolites and metal modified MFI-type zeolites including one or more metals selected from the group consisting of: Group VIB metals, Group VIIB metals, Group VIII metals, Group IB metals, Group IIB metals, Ga, and In, or
the gas-upgrading catalyst comprises one or more metal modified MFI type zeolites including one or more metals selected from the group consisting of: Ga, Zn, In, Mo, W, Cr, Pt, Pd, Rh, Ru, Au, and Ir.

21. The system of claim 16 , wherein a sequence of catalysts is determined by renewable fuel yield or by temperature of devolatization of biomass components, and wherein one or more biomass source serve as feedstock for each processing station.

22. The method of claim 1 or 9 , wherein at least one processing station comprises an auger reactor.

23. The system of claim 15 or 16 , wherein at least one processing station comprises an auger reactor.

Assignees

• Cool Planet Energy Systems Inc

Inventors

• Cheiky Michael C
• Malyala Rajashekharam

Classifications

• C10G1/002 Primary

  in combination with oil conversion- or refining processes · CPC title

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title

• C10L3/08

  Production of synthetic natural gas · CPC title

• Y02E50/13

  Cross-Sectional Technologies · mapped topic

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title