Additives for oil-based drilling fluids

Patent metadata

Field	Value
Publication number	US-9328280-B2
Application number	US-201313889940-A
Country	US
Kind code	B2
Filing date	May 8, 2013
Priority date	May 8, 2013
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

An additive for a wellbore treatment fluid comprising a sulfonated asphalt compound comprising particles having a D90 particle size of less than about 215 μm. A wellbore treatment fluid comprising (i) an oleaginous component and (ii) a sulfonated asphalt wherein the sulfonated asphalt comprises particles having a D90 of less than about 215 μm.

First claim

What is claimed is:

1. An additive for an oil-based wellbore treatment fluid, the additive comprising:
a ground sulfonated asphalt compound comprising particles having a D10, D50 and D90 particle size distribution as determined by standard particle size measurements wherein:
the D10 particle size is less than about 30 μm,
the D50 particle size is less than about 50 μm, and
the D90 particle size is less than about 215 μm;
wherein the ground sulfonated asphalt is included in the wellbore treatment fluid in an amount of from about 0.1 lbs/bbl to about 15 lbs/bbl,
such that the wellbore treatment fluid with the additive has a yield point (YP) of from about 1 lb/100 ft 2 to about 50 lb/100 ft 2 .

2. The additive of claim 1 wherein equal to or greater than about 95% of the particles pass through a 70 mesh sieve.

3. The additive of claim 1 wherein equal to or greater than about 95% of the particles pass through a 100 mesh sieve.

4. The additive of claim 1 wherein equal to or greater than about 95% of the particles pass through a 170 mesh sieve.

5. The additive of claim 1 wherein the sulfonated asphalt comprises one or more compounds selected from the group consisting of an ammonium salt, an alkali metal salt, and an alkaline earth metal salt.

6. The additive of claim 1 wherein the sulfonated asphalt comprises a sodium salt of a sulfonated asphalt.

7. The additive of claim 1 wherein the sulfonated asphalt comprises a potassium salt of a sulfonated asphalt.

8. A wellbore treatment fluid comprising:
(i) an oleaginous component, and
(ii) a ground sulfonated asphalt,
wherein the sulfonated asphalt comprises particles having a D10, D50 and D90 particle size distribution as determined by standard particle size measurements wherein:
the D10 particle size is less than about 30 μm,
the D50 particle size is less than about 50 μm, and
the D90 particle size is less than about 215 μm,
wherein the ground sulfonated asphalt is included in the wellbore treatment fluid in an amount of from about 0.1 lbs/bbl to about 15 lbs/bbl and the wellbore
treatment fluid has a yield point (YP) of from about 1 lb/100 ft 2 to about 50 lb/100 ft 2 .

9. The wellbore treatment fluid of claim 8 wherein equal to or greater than about 95% of the sulfonated asphalt particles pass through a 70 mesh sieve.

10. The wellbore treatment fluid of claim 8 wherein equal to or greater than about 95% of the sulfonated asphalt particles pass through a 100 mesh sieve.

11. The wellbore treatment fluid of claim 8 wherein equal to or greater than about 95% of the sulfonated asphalt particles pass through a 170 mesh sieve.

12. The wellbore treatment fluid of claim 8 wherein the sulfonated asphalt comprises one or more components selected from the group consisting of a free acid, an ammonium salt, an alkali metal salt, and an alkaline earth metal salt.

13. The wellbore treatment fluid of claim 8 wherein the sulfonated asphalt comprises a sodium salt of a sulfonated asphalt.

14. The wellbore treatment fluid of claim 8 wherein the sulfonated asphalt comprises a potassium salt of a sulfonated asphalt.

15. The wellbore treatment fluid of claim 8 comprising one or more oleaginous components selected from the group consisting of diesel oil, mineral oil, a synthetic oil, kerosene, fuel oil, crude oil, and derivatives thereof.

16. The wellbore treatment fluid of claim 8 wherein the oleaginous component comprises an olefin.

17. The wellbore treatment fluid of claim 8 wherein the oleaginous component comprises an organic ester.

18. The wellbore treatment fluid of claim 8 wherein the oleaginous component comprises one or more oleaginous components selected from the group consisting of a linear and a branched paraffin.

19. The wellbore treatment fluid of claim 8 wherein the oleaginous component comprises an acetal.

20. The wellbore treatment fluid of claim 8 wherein the sulfonated asphalt is present at a concentration less than or equal to about 15 ppb.

21. The wellbore treatment fluid of claim 8 wherein the oleaginous component is present in the wellbore servicing fluid in an amount greater than or equal to about 70% by volume.

22. The wellbore treatment fluid of claim 8 formulated as an invert emulsion drilling fluid.

23. The wellbore treatment fluid of claim 8 , wherein the wellbore treatment fluid with the additive has a high-temperature high-pressure (HTHP) fluid loss at 300° F. that is decreased by from about 10% to about 90% when compared to the HTHP fluid loss of the wellbore treatment fluid in the absence of an additive.

24. The wellbore treatment fluid of claim 8 , wherein the wellbore treatment fluid is characterized by a plastic viscosity ranging from about 1 cPs to about 75 cPs and a yield point ranging from about 2 lb/100 ft 2 to about 25 lb/100 ft 2 .

25. The additive of claim 1 wherein the ground sulfonated asphalt has a ring and ball softening point in the range of from about 115° F. to about 475° F.

26. The wellbore treatment fluid of claim 8 wherein the ground sulfonated asphalt has a ring and ball softening point in the range of from about 1.15° F. to about 475° F.

Assignees

• Chevron Phillips Chemical Co

Inventors

• Bishop Marshall D
• Reneau Willie P
• Evans Frank E
• Anderson John E

Classifications

• C09K8/36

  Water-in-oil emulsions · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C09K8/34 Primary

  Organic liquids · CPC title

• C09K8/035 Primary

  Organic additives · CPC title