Polyamide compositions with improved optical properties

Patent metadata

Field	Value
Publication number	US-9328219-B2
Application number	US-201313847752-A
Country	US
Kind code	B2
Filing date	Mar 20, 2013
Priority date	Mar 20, 2012
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

The present invention relates to a polymer composition comprising at least one polyamide and at least one urea compound of the formula I

where x is 1, 2 or 3; R 1 and R 2 are selected from hydrogen, linear C 1 -C 7 -alkyl, branched C 3 -C 10 -alkyl, unsubstituted or substituted C 3 -C 12 -cycloalkyl, unsubstituted or substituted C 3 -C 12 -cycloalkyl-C 1 -C 4 -alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C 1 -C 4 -alkyl; and Z is selected from C 3 -C 10 -alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted aryl unsubstituted or substituted ene-C 1 -C 4 -alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C 1 -C 4 -alkylene-heteroarylene, unsubstituted or substituted C 5 -C 8 -cycloalkylene, C 5 -C 8 -cycloalkylene-C 1 -C 4 -alkylene-C 5 -C 8 -cycloalkylene, unsubstituted or substituted heterocycloalkylene and heterocycloalkylene-C 1 -C 4 -alkylene-heterocycloalkylene.

This urea compound is used for improving the optical properties of the polyamide polymer composition. The present invention also relates to shaped articles obtained from said composition and to novel urea compounds.

First claim

The invention claimed is:

1. A polymer composition which comprises at least one polyamide polymer and at least one compound of the formula I

wherein
x is 1;
R 1 and R 2 are, independently of each other, hydrogen, linear C 1 -C 7 -alkyl, branched C 3 -C 10 -alkyl, unsubstituted C 3 -C 12 -cycloalkyl, unsubstituted C 3 -C 12 -cycloalkyl-C 1 -C 4 -alkyl, unsubstituted aryl or unsubstituted aryl-C 1 -C 4 -alkyl; and
Z is trans1,4-cyclohexanediyl, and
wherein the compound of the formula I is present in an amount of 0.025 to 2% by weight relative to the weight of the polyamide polymer.

2. The composition according to claim 1 , wherein R 1 and R 2 are, independently of each other, are linear C 1 -C 7 -alkyl, branched C 3 -C 10 -alkyl, unsubstituted C 3 -C 12 -cycloalkyl, unsubstituted C 3 -C 12 -cycloalkyl-C 1 -C 4 -alkyl, unsubstituted aryl or unsubstituted aryl-C 1 -C 4 -alkyl.

3. The composition according to claim 1 , wherein R 1 and R 2 are, independently of each other, hydrogen, branched C 3 -C 10 -alkyl, C 5 -C 12 -cycloalkyl, or phenyl.

4. The composition according to claim 1 , wherein R 1 and R 2 are, independently of each other, C 3 -C 10 -alkyl, which is attached to the skeleton via a secondary or tertiary carbon atom of the alkyl group, C 5 -C 10 -cycloalkyl which is unsubstituted, or phenyl.

5. The composition according to claim 1 , wherein R 1 and R 2 have the same meaning.

6. The composition according to claim 1 , wherein
R 1 and R 2 are identical and are tert-butyl, 1,1-dimethylpropyl, 1,5-dimethylhexyl, 1,1,3,3-tetramethylbutyl or 1-adamantyl; and
x is 1.

7. The composition according to claim 1 , wherein the polyamide polymer is an aliphatic polyamide homopolymer, aliphatic polyamide copolymer or a partially aromatic polyamide.

8. The composition according to claim 1 , wherein the polyamide polymer is PA 6, PA 7, PA 10, PA 11, PA 12, PA 66, PA 69, PA 610, PA 612, PA1010, PA 6/66, PA 66/6, PA 66/610 or mixtures thereof.

9. The composition according to claim 1 , wherein the polyamide polymer is PA 6, PA 11, PA 12, PA 66, PA 66/6 or PA 6/66 and R 1 and R 2 are identical and are hydrogen, tert-butyl, 1,1-dimethylpropyl, 1,5-dimethylhexyl, 1,1,3,3-tetramethylbutyl or 1-adamantyl.

10. The composition according to claim 1 , wherein the polymer composition additionally comprises at least one further additive selected from the group consisting of colorants, antioxidants, UV-absorber, light stabilizers, reinforcing materials, fillers, antifogging agents, mold release agents, biocides, antistatic agents and rheology modifier.

11. A method for improving at least one at least one optical property selected from increased clarity, increased laser transparency and reduced haze which comprises adding the compound of the formula I

wherein
x is 1,
R 1 and R 2 are, independently of each other, hydrogen, linear C 1 -C 7 -alkyl, branched C 3 -C 10 -alkyl, unsubstituted C 3 -C 12 -cycloalkyl, unsubstituted C 3 -C 12 -cycloalkyl-C 1 -C 4 -alkyl, unsubstituted aryl or unsubstituted aryl-C 1 -C 4 -alkyl; and
Z is trans1,4-cyclohexanediyl;
in a polymer composition comprising at least one semi-crystalline polyamide polymer and
wherein the compound of the formula I is present in an amount of 0.025 to 2% by weight relative to the weight of the polyamide polymer.

12. The method according to claim 11 , wherein R 1 and R 2 are, independently of each other, hydrogen, branched C 3 -C 10 -alkyl, C 5 -C 12 -cycloalkyl or phenyl.

13. The method according to claim 11 , wherein the polyamide polymer is an aliphatic polyamide homopolymer, aliphatic polyamide copolymer or a partially aromatic polyamide.

14. The method according to claim 13 , wherein the polyamide polymer is PA 6, PA 7, PA 10, PA 11, PA 12, PA 66, PA 69, PA 610, PA 612, PA 1010, PA 6/66, PA 66/6 or PA 66/610.

15. The method according to claim 11 , wherein the polyamide polymer is PA 6, PA 11, PA 12, PA 66, PA 66/6 or PA 6/66 and R 1 and R 2 are identical and are hydrogen, tert-butyl, 1,1-dimethylpropyl, 1,5-dimethylhexyl, 1,1,3,3-tetramethylbutyl or 1-adamantyl.

16. The method according to claim 11 , wherein the haze-value is reduced by at least 5%, compared to a reference polymer composition without an additive of the formula I, the haze being measured at a plate of 1.1 mm thickness.

17. The method according to claim 11 , wherein the clarity-value is increased by at least 5%, compared to a reference polymer composition without an additive of the formula I, the clarity being measured at a plate of 1.1 mm thickness.

18. The method according to claim 11 , wherein the laser transparency value is increased by at least 1%, compared to a reference polymer composition without an additive of the formula I, measured at 1064 nm and at a plate of 1.1 mm thickness.

19. The method according to claim 11 , wherein the haze-value is reduced by at least 5% and the clarity-value is increased by at least 5% compared to a reference polymer composition without an additive of the formula I, haze and clarity being measured at a plate of 1.1 mm thickness.

20. A shaped article comprising the polymer composition according to claim 1 .

21. The shaped article according to claim 20 wherein the article is a film, fiber, sheet, pipe, semi-finished product, granulate, container, blow-molded article or monofilament.

Assignees

• Basf Se

Inventors

• Gabriel Claus
• Richter Florian
• Park Hye Jin
• Xalter Rainer
• Schmidt Hans-Werner

Classifications

• Y10T428/1352

  Polymer or resin containing [i.e., natural or synthetic] · CPC title

• C08K5/21 Primary

  Urea; Derivatives thereof, e.g. biuret · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title