Process for selective hydrogenation in the presence of a catalyst based on a metal from group VIII prepared using at least one cyclic oligosaccharide

Patent metadata

Field	Value
Publication number	US-9328039-B2
Application number	US-201113812707-A
Country	US
Kind code	B2
Filing date	Jun 24, 2011
Priority date	Jul 29, 2010
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

Selective hydrogenation of a polyunsaturated hydrocarbon feed containing at least 2 carbon atoms per molecule and having an end point of 250° C. or less, by contacting said feed with a catalyst having an active phase of at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process involving at least:
i) contacting said support with at least one solution containing at least one precursor of metal from group VIII; ii) contacting said support with at least one organic compound formed from at least one cyclic oligosaccharide composed of at least 6 α-(1,4)-bonded glucopyranose subunits; iii) calcining to obtain metal from group VIII in oxide form; i) and ii) possibly being carried out separately, in any order, or simultaneously.

First claim

The invention claimed is:

1. A process for the selective hydrogenation of a hydrocarbon feed comprising at least 2 carbon atoms per molecule and having an end boiling point of 250° C. or less, said hydrocarbon feed comprising acetylenes, diolefins or a mixture thereof, said process comprising bringing said feed into contact with at least one catalyst the active phase of which comprises at least one metal from group VIII deposited on a support formed by at least one oxide, said catalyst being prepared using a process comprising at least:
i) at least once contacting said support with at least one solution containing at least one precursor of at least said metal from group VIII;
ii) at least once contacting at least said support with at least one organic compound formed from at least one cyclic oligosaccharide having at least 6 α-(1,4)-bonded glucopyranose subunits;
iii) calcining at least once to obtain at least said metal from said group VIII in the oxide form;
i) and ii) being carried out separately, in any order, or simultaneously.

2. The selective hydrogenation process according to claim 1 , in which said hydrocarbon feed is a C2 steam cracked cut, a C3 steam cracked cut, a C4 steam cracked cut, a C5 steam cracked cut or a steam cracked gasoline.

3. The selective hydrogenation process according to claim 2 , in which said hydrocarbon feed is a steam cracked gasoline.

4. The selective hydrogenation process according to claim 3 , carried out at a temperature of 20° C. to 200° C., at a pressure of 0.4 to 5 MPa and at an hourly space velocity (defined as the ratio of the volume flow rate of feed to the volume of catalyst) of 0.2 to 30 h −1 .

5. The selective hydrogenation process according to claim 1 , in which said metal from group VIII present in the active phase is nickel.

6. The selective hydrogenation process according to claim 1 , in which said active phase comprises at least one additional metal from group VIII or group IB.

7. The selective hydrogenation process according to claim 1 , in which said support comprises an alumina, silicas or silica alumina.

8. The selective hydrogenation process according to claim 1 , in which said organic compound is a cyclodextrin, substituted cyclodextrin, polymerized cyclodextrin or a mixture of cyclodextrins.

9. The selective hydrogenation process according to claim 8 , in which the cyclodextrin is α-cyclodextrin, β-cyclodextrin and γ-cyclodextrin respectively composed of 6, 7 and 8 α-(1,4)-bonded glucopyranose subunits.

10. The selective hydrogenation process according to claim 8 , in which the substituted cyclodextrins is hydroxypropyl beta-cyclodextrin or methylated beta-cyclodextrins.

11. The selective hydrogenation process according to claim 1 , in which said organic compound for carrying out said step ii) is introduced such that the molar ratio {(metal(s) from group VIII in the oxide form present in the active phase of the catalyst obtained from said step iii)/organic compound} is 10 to 300.

12. The selective hydrogenation process according to claim 1 , in which i) and ii) are carried out simultaneously a plurality of times.

13. The selective hydrogenation process according to claim 1 , in which ii) is carried out prior to i).

14. The selective hydrogenation process according to claim 1 in which, when the active phase of the catalyst comprises nickel as the metal from group VIII, said catalyst is prepared in accordance with a process comprising at least v) passivating said catalyst using at least one sulphur-containing compound.

Assignees

• Diehl Fabrice
• Dubreuil Anne Claire
• Janvier Josselin
• Thomazeau Cecile
• IFP Energies Nouvelles

Inventors

• Diehl Fabrice
• Dubreuil Anne Claire
• Janvier Josselin
• Thomazeau Cecile

Classifications

• B01J23/40

  of the platinum group metals · CPC title

• C10G2400/22

  Higher olefins · CPC title

• C10G2300/1011

  Biomass · CPC title

• B01J21/04

  Alumina · CPC title

• B01J37/20

  Sulfiding · CPC title