Process for reclaiming inorganic powders from polymer-based coating compositions

Patent metadata

Field	Value
Publication number	US-9327309-B2
Application number	US-201313949255-A
Country	US
Kind code	B2
Filing date	Jul 24, 2013
Priority date	Jul 24, 2013
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

Processes for recovering inorganic powder materials from polymer-based coating compositions used to deposit a polymer-based coating. The process includes combining a polymer precursor, first solvent, and inorganic powder material to form a suspension, and applying the suspension to a substrate to form a layer. At least a portion of the suspension that did not adhere to the substrate is then collected. Residual portions of the first solvent and polymer precursor are at least partially removed from this portion of the suspension to yield a crude inorganic powder material comprising a residual portion of the inorganic powder and optionally a partially-cured polymer precursor, the latter of which can be removed by treating the crude inorganic powder material with a second solvent.

First claim

The invention claimed is:

1. A process of recovering an inorganic powder material from a polymer-based coating composition, the process comprising:
combining at least a polymer precursor, a first solvent, and the inorganic powder material to form a suspension of the polymer-based coating composition;
applying the suspension to a substrate so that a first portion of the suspension adheres to the substrate and forms a layer on the substrate;
collecting a second portion of the suspension that did not adhere to the substrate, the second portion of the suspension comprising residual portions of each the first solvent, the inorganic powder material, and the polymer precursor and optionally further comprising a partially-cured polymer precursor formed from the polymer precursor;
removing at least some of the residual portions of each the first solvent and the polymer precursor to yield a crude inorganic powder material comprising the residual portion of each the inorganic powder material and any partially-cured polymer precursor; and
treating the crude inorganic powder material with a second solvent in which the partially-cured polymer precursor is soluble to dissolve at least a portion of any partially-cured polymer precursor;
wherein the process further comprises at least partially removing the second solvent and any partially-cured polymer precursor dissolved therein from the crude inorganic powder material; and
wherein the process yields the residual portion of the inorganic powder material substantially free of the polymer precursor and the first and second solvents.

2. The process according to claim 1 , wherein the steps of treating with the second solvent and at least partially removing the second solvent are repeated.

3. The process according to claim 1 , wherein the inorganic powder material comprises a phosphor material.

4. The process according to claim 3 , wherein the phosphor material comprises a rare earth element or a rare earth-containing compound.

5. The process according to claim 1 , wherein the inorganic powder material comprises Nd 2 O 3 .

6. The process according to claim 1 , wherein the inorganic powder material comprises K 2 MF 6 :Mn 4+ , where M represents Si, Ge, Sn, and/or Ti.

7. A process of recovering an inorganic powder material from a polymer-based coating composition, the process comprising:
combining at least a polymer precursor, a first solvent, and the inorganic powder material to form a suspension of the polymer-based coating composition;
applying the suspension to a substrate so that a first portion of the suspension adheres to the substrate and forms a layer on the substrate;
treating the layer to remove the first solvent, cure the polymer precursor, and form therefrom a coating comprising particles of the inorganic powder material dispersed in a polymer binder formed by curing the polymer precursor, the polymer binder and the substrate being substantially insoluble in the first solvent;
collecting a second portion of the suspension that did not adhere to the substrate, the second portion of the suspension comprising residual portions of each the first solvent, the inorganic powder material, and the polymer precursor and further comprising a partially-cured polymer precursor formed from the polymer precursor undergoing polymerization during the applying step;
removing at least some of the residual portions of each the first solvent and the polymer precursor dissolved therein to yield a crude inorganic powder material comprising the residual portion of each the inorganic powder material and the partially-cured polymer precursor; and
treating the crude inorganic powder material with a second solvent in which the partially-cured polymer precursor is soluble to dissolve at least a portion of the partially-cured polymer precursor material.

8. The process according to claim 7 , wherein the polymer binder comprises a thermoplastic selected from one or more of polyethylene, poly(methyl methacrylate), polyurethane, polycarbonate, and fluoropolymers.

9. The process according to claim 7 , wherein the first solvent comprises one of more of water, isopropyl alcohol, and acetone.

10. The process according to claim 7 , wherein the second solvent comprises one of more of toluene, benzene, xylene, and dichlorobenzene.

11. The process according to claim 7 , wherein the inorganic powder material comprises a rare earth element or a rare earth-containing compound.

12. The process according to claim 7 , wherein the inorganic powder material comprises Nd 2 O 3 .

13. The process according to claim 7 , wherein the inorganic powder material comprises K 2 MF 6 :Mn 4+ , where M represents Si, Ge, Sn, and/or Ti.

14. A process of fabricating a component of a light-emitting device, the process comprising:
combining at least a polymer precursor, a first solvent, and an inorganic powder material to form a suspension of a polymer-based coating composition;
applying the suspension to a substrate of the component so that a first portion of the suspension adheres to the substrate and forms a layer on the substrate;
treating the layer to remove the first solvent, cure the polymer precursor, and form therefrom a coating on a surface of the substrate, the coating comprising particles of the inorganic powder material dispersed in a polymer binder formed by curing the polymer precursor, the polymer binder and the substrate being substantially insoluble in the first solvent;
collecting a second portion of the suspension that did not adhere to the substrate, the second portion of the suspension comprising residual portions of each the first solvent, the inorganic powder material, and the polymer precursor and further comprising a partially-cured polymer precursor formed from the polymer precursor undergoing polymerization during the applying step;
removing the residual portions of each the first solvent and the polymer precursor dissolved therein to yield a crude inorganic powder material comprising the residual portion of each the inorganic powder material and the partially-cured polymer precursor;
treating the crude inorganic powder material with a second solvent in which the partially-cured polymer precursor is soluble to dissolve at least a portion of the partially-cured polymer precursor;
removing the second solvent and the partially-cured polymer precursor dissolved therein from the crude inorganic powder material; and
optionally repeating the step of treating with the second solvent and removing the second solvent to yield essentially the residual portion of the inorganic powder material.

15. The process according to claim 14 , wherein the polymer binder comprises a thermoplastic selected from one or more of polyethylene, poly(methyl methacrylate), polyurethane, polycarbonate, and fluoropolymers.

16. The process according to claim 14 , wherein the inorganic powder material comprises a rare earth element or a rare earth-containing compound.

17. The process according to claim 14 , wherein the inorganic powder material comprises Nd 2 O 3 .

18. The process according to claim 14 , wherein the inorganic powder material comprises K 2 MF 6 :Mn 4+ , where M represents Si, Ge, Sn, and/or Ti.

Assignees

• Ge Lighting Solutions Llc

Inventors

• Cai Dengke
• Allen Gary Robert
• Clynne Thomas

Classifications

• C09K11/01 Primary

  Recovery of luminescent materials · CPC title

• Y02W30/72

  Cross-Sectional Technologies · mapped topic

• B05C11/1039 Primary

  Recovery of excess liquid or other fluent material; Controlling means therefor · CPC title

• Y02W30/50

  Reuse, recycling or recovery technologies · CPC title