Fibrous IM-5 molecular sieve and preparation process thereof

Patent metadata

Field	Value
Publication number	US-9327277-B2
Application number	US-201214356725-A
Country	US
Kind code	B2
Filing date	Oct 30, 2012
Priority date	Nov 10, 2011
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

The present invention provides a fibrous IM-5 molecular sieve and the preparation process thereof. According to the process according to the present invention, by adding an appropriate amount of a quaternary ammonium salt with a long carbon chain to the preparation system so as to occur a synergistic action with the organic templet agent, an IM-5 molecular sieve which would be otherwise a rodlike form is converted into the fibrous form. The IM-5 molecular sieve according to the present invention has an aspect ratio greater than that of the rodlike IM-5 molecular sieve obtained according to the prior art, such that the proportion of the exposed periphery crystal face is higher, which benefit to increasing the selectivity of the catalytic reaction for the corresponding crystal face.

First claim

The invention claimed is:

1. An IM-5 molecular sieve, wherein the IM-5 molecular sieve is in a fibrous form, having an average diameter of about 5-about 30 nm and an average aspect ratio of about 15-about 100.

2. The IM-5 molecular sieve according to claim 1 , wherein an average length of the fibrous IM-5 molecular sieve is about 100-about 3000 nm.

3. The IM-5 molecular sieve according to claim 2 , wherein the average length of the fibrous IM-5 molecular sieve is about 200-about 1250 nm.

4. The IM-5 molecular sieve according to claim 1 , wherein the IM-5 molecular sieve has an average diameter of about 10-about 25 nm and an average aspect ratio of about 20-about 50.

5. A process of preparing the IM-5 molecular sieve according to claim 1 , comprising:
(1) mixing an alkali source, a templet agent, an aluminum source, water, a silicon source and a cationic surfactant to form a mixture, and stirring the mixture to generate a sol; and
(2) heating the sol of step (1) at about 140-about 200 degrees C. for about 2-about 15 days to produce a solid material in the sol, separating the solid material from the sol, drying and calcinating the solid material to obtain the IM-5 molecular sieve of claim 1 ,
wherein, in the mixture of step (1), a molar ratio of R/SUR + is about 5-about 20,
wherein SUR + represents the cationic surfactant and R represents the templet agent.

6. The process according to claim 5 , wherein in step (1), the mixture is stirred at a temperature about 20-about 70 degrees C. for about 1-about 24 hours.

7. The process according to claim 6 , wherein in step (1), the mixture is stirred at a temperature about 55-about 65 degrees C. for about 3about 12 hours.

8. The process according to claim 5 , wherein the templet agent R is 1,1′-(pentamethylene) bis(1-methylpyrrolidinium) bromide.

9. The process according to claim 5 , wherein, in step (1), the aluminum source is aluminum nitrate, aluminum chloride, aluminum sulfate, or a combination thereof; the alkali source is sodium hydroxide, potassium hydroxide, lithium hydroxide, or a combination thereof; and the silicon source is white carbon, silicic acid, silanolate, silica sol, silica gel, or a combination thereof.

10. The process according to claim 5 , wherein, in step (1), the cationic surfactant is a cationic quaternary ammonium salt having a carbon chain of 12-18 carbon atoms, and a corresponding negative ion thereof is a bromide ion or a chloride ion.

11. The process according to claim 5 , wherein, in step (1), the cationic surfactant is cetyl trimethylammonium bromide, myristyl trimethylammonium bromide, or dodecyl trimethylammonium bromide.

12. The process according to claim 5 , wherein in the mixture of step (1), a molar ratio of SiO 2 /Al 2 O 3 is about 40-about 70, a molar ratio of R/SiO 2 is about 0.15-about 0.4, wherein R represents the templet agent, and a molar ratio of H 2 O/SiO 2 is about 30-about 70, a molar ratio of OH − /SiO 2 is about 0.6-about 0.8.

13. The process according to claim 12 , wherein the moler raito of SiO 2 /Al 2 O 3 is about 50-about 70, the molar ratio of R/SiO 2 is about 0.15-about 0.3, the molar ratio of H 2 O/SiO 2 is about 40 to about 60, and the molar ratio of OH/SiO 2 is about 0.70-about 0.75.

14. The process according to claim 5 , wherein, in step (2), the sol is heated at a temperature of about 160-about 185 degrees C.

15. The process according to claim 14 , wherein, in step (2), the sol is heated at a temperature of about 165-about 175 degrees C.

16. The process according to claim 5 , wherein, in step (2), the sol is heated for about 7-about 12 days.

17. The process according to claim 5 , wherein the IM-5 molecular sieve of claim 1 has an average diameter of about 10-about 25 nm and an average aspect ratio of about 20-about 50.

18. The process according to claim 5 , wherein the IM-5 molecular sieve of claim 1 has an average length of about 200-about 1250 nm.

19. The process according to claim 5 , wherein, in the mixture of step (1), the molar ratio of R/SUR + is about 8-about 16.

Assignees

• China Petroleum & Chemical
• Fushun Res Inst Petroleum & Petrochemicals Sinopec

Inventors

• Yang Weiya
• Ling Fengxiang
• Wang Shaojun
• Shen Zhiqi

Classifications

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01B39/40

  using at least one organic template directing agent · CPC title

• B01J29/70 Primary

  of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 · CPC title

• C01P2004/10

  extending in one dimension, e.g. needle-like · CPC title

• C01B39/48

  using at least one organic template directing agent · CPC title