Colored radiation-sensitive composition, colored cured film, color filter, pattern forming method, color filter production method, solid-state image sensor, and image display device

Patent metadata

Field	Value
Publication number	US-9323145-B2
Application number	US-201414454832-A
Country	US
Kind code	B2
Filing date	Aug 8, 2014
Priority date	Mar 21, 2012
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

A colored radiation-sensitive composition contains (A) a dye multimer, (B) a pigment, (C) a polymerizable compound, (D) a photopolymerization initiator, and (E) a dispersion resin obtained by reacting a polymer, which has a hydroxyl group on one terminal, with an acid anhydride.

First claim

What is claimed is:

1. A colored radiation-sensitive composition comprising:
(A) a dye multimer which is a trimer or higher;
(B) a pigment;
(C) a polymerizable compound;
(D) a photopolymerization initiator; and
(E) a dispersion resin obtained by reacting a polyester, which has a hydroxyl group on one terminal, with an acid anhydride,
wherein the (A) dye multimer has a partial structure derived from a dye selected from an azo dye, an anthraquinone dye, a triphenylmethane dye, a xanthene dye, a cyanine dye, a squarylium dye, a quinophthalone dye, a phthalocyanine dye, and a subphthalocyanine dye.

2. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer has a partial structure derived from a dye selected from a triphenylmethane dye and a xanthene dye.

3. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer further contains an alkali-soluble group.

4. The colored radiation-sensitive composition according to claim 1 ,
wherein the acid value of the (A) dye multimer is 0.3 mmol/g to 2.0 mmol/g.

5. The colored radiation-sensitive composition according to claim 1 ,
wherein the weight average molecular weight of the (A) dye multimer is 2,000 to 20,000.

6. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer is a radical polymer containing a dye monomer having an ethylenically unsaturated bond.

7. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer has a polymerizable group.

8. The colored radiation-sensitive composition according to claim 7 ,
wherein the content of the polymerizable group with respect to 1 g of the (A) dye multimer is 0.1 mmol to 2.0 mmol.

9. The colored radiation-sensitive composition according to claim 1 ,
wherein the (B) pigment is at least one kind of pigment selected from the group consisting of an anthraquinone pigment, a diketopyrrolopyrrole pigment, a phthalocyanine pigment, a quinophthalone pigment, an isoindoline pigment, an azomethine pigment, and a dioxazine pigment.

10. The colored radiation-sensitive composition according to claim 1 ,
wherein the (D) photopolymerization initiator is an oxime compound.

11. The colored radiation-sensitive composition according to claim 1 , that is used for forming a colored layer of a color filter.

12. A colored cured film obtained by curing the colored radiation-sensitive composition according to claim 1 .

13. A color filter comprising the colored cured film according to claim 12 .

14. The color filter according to claim 13 ,
wherein the film thickness of the colored cured film is 0.7 μm or less.

15. A solid-state image sensor comprising:
the color filter according to claim 13 .

16. An image display device comprising:
the color filter according to claim 13 .

17. A pattern forming method comprising:
forming a colored radiation-sensitive composition layer by applying the colored radiation-sensitive composition according to claim 1 onto a support;
exposing the colored radiation-sensitive composition layer in the form of a pattern; and
forming a colored pattern by developing and removing an unexposed portion.

18. A color filter production method comprising:
forming a colored radiation-sensitive composition layer by applying the colored radiation-sensitive composition according to claim 1 onto a support;
exposing the colored radiation-sensitive composition layer in the form of a pattern; and
forming a colored pattern by developing and removing an unexposed portion.

19. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer has a partial structure derived from a dye selected from a triphenylmethane dye, a xanthene dye, a cyanine dye, a squarylium dye, a quinophthalone dye, a phthalocyanine dye, and a subphthalocyanine dye.

20. The colored radiation-sensitive composition according to claim 1 ,
wherein the polyester, which has a hydroxyl group on one terminal, is obtained by reacting an alcohol with lactone.

21. The colored radiation-sensitive composition according to claim 20 , wherein the lactone is ε-caprolactone.

22. The colored radiation-sensitive composition according to claim 21 , wherein the alcohol has a boiling point of 100° C. or higher, or the alcohol is an aliphatic alcohol having 4 to 25 carbon atoms.

23. The colored radiation-sensitive composition according to claim 1 ,
wherein the acid anhydride is a tetracarboxylic acid dianhydride.

24. The colored radiation-sensitive composition according to claim 1 ,
wherein the (A) dye multimer contains at least one of the structural units represented by Formula (A) and Formula (C), or the (A) dye multimer is represented by Formula (D),

wherein in Formula (A),
X 1 represents a linking group formed by polymerization,
L 1 represents a single bond or a divalent linking group, and
DyeI represents a dye structure,

wherein in Formula (C),
L 3 represents a single bond or a divalent linking group,
DyeIII represents a partial structure of a dye, and
m represents 0 or 1,

Formula (D)
wherein in Formula (D),
L 4 represents a linking group having a valency of n,
n represents an integer from 2 to 20, when n is 2 or greater, structures of DyeIV may be the same as or different from each other, and
DyeIV represents a dye structure.

25. The colored radiation-sensitive composition according to claim 24 ,
wherein the (A) dye multimer contains the structural units represented by the Formula (A).

26. The colored radiation-sensitive composition according to claim 1 , wherein the polyester has one hydroxyl group on one terminal.

27. The colored radiation-sensitive composition according to claim 1 , wherein the (E) dispersion resin is selected from the group consisting of compounds (a-7) to (a-11):

Assignees

• Fujifilm Corp

Inventors

• Kaneko Yushi
• Idei Hiroaki
• Hitomi Seiichi
• Oota Kazuya
• Murakami Yousuke

Classifications

• G03F7/105

  having substances, e.g. indicators, for forming visible images · CPC title

• G02B1/04

  made of organic materials, e.g. plastics (G02B1/08 takes precedence) · CPC title

• G03F7/0388

  with ethylenic or acetylenic bands in the side chains of the photopolymer · CPC title

• G03F7/038

  Macromolecular compounds which are rendered insoluble or differentially wettable (G03F7/075 takes precedence; macromolecular azides G03F7/012; macromolecular diazonium compounds G03F7/021) · CPC title

• G03F7/031

  Organic compounds not covered by group G03F7/029 · CPC title