Yellow light emitting phosphor and light emitting device package using the same

Patent metadata

Field	Value
Publication number	US-9321958-B2
Application number	US-201514737175-A
Country	US
Kind code	B2
Filing date	Jun 11, 2015
Priority date	Jul 14, 2014
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

Disclosed are phosphors and, more particularly, yellow light emitting phosphors and light emitting device packages using the same. The yellow light emitting phosphor includes a first phosphor to emit light having a central wavelength located within a band of 510 nm to 550 nm, a second phosphor adapted to be mixed with the first phosphor to emit light having a central wavelength located within a band of 560 nm to 600 nm, and a third phosphor adapted to be mixed with the first and second phosphors to emit light having a central wavelength located within a band of 610 nm to 630 nm, the third phosphor having a light absorption rate of 50% or less at a wavelength of 550 nm.

First claim

What is claimed is:

1. A yellow light emitting phosphor comprising:
a first phosphor including at least one of BaYSi 4 N 7 :Eu, Ba 3 Si 6 O 12 N 2 :Eu, CaSi 2 O 2 N 2 :Eu, SrYSi 4 N 7 :Eu, α-type SiAlON(Ca-α-SiAlON:Yb) containing Ca as a metal component, Lu 3 Al 5 O 12 :Ce, and SrSi 2 O 2 N 2 :Eu, the first phosphor being adapted to emit light having a central wavelength located within a band of 510 nm to 550 nm;
a second phosphor including at least one of α-type SiAlON(Li-α-SiAlON:Eu) containing Li as a metal component and α-type SiAlON(Ca-α-SiAlON:Eu) containing Ca as a metal component, the second phosphor being mixed with the first phosphor to emit light having a central wavelength located within a band of 560 nm to 600 nm; and
a third phosphor including at least one of CaAlSiN 3 :Eu, (Sr, Ca)AlSiN 3 :Eu, Sr 2 Si 5 N 8 :Eu, K 2 SiF 6 :Mn, La 3 Si 6 N 11 :Ce, SrAlSiN 3 :Eu, SrCN 2 :Eu, Ca 2 Si 5 N 8 :Eu, Ba 2 Si 5 N 8 :Eu, SrAlSi 4 N 7 :Eu, and (Sr, Ba)SiN 2 :Eu, the third phosphor being mixed with the first and second phosphors to emit light having a central wavelength located within a band of 610 nm to 630 nm, the third phosphor having a light absorption rate of 50% or less at a wavelength of 550 nm.

2. The yellow light emitting phosphor according to claim 1 , wherein the second phosphor is α-type SiAlON(Li-α-SiAlON:Eu) containing Li as a metal component.

3. The yellow light emitting phosphor according to claim 1 , wherein the second phosphor is represented by the following chemical formula 1:
Li m−2x Eu x Si 12−(m+n) Al m+n O n N 16−n
where, “x”, “m” and “n” fulfill at least one condition of 0.01≦x≦0.1, 0≦m≦2 and 0≦n≦1.

4. The yellow light emitting phosphor according to claim 1 , wherein the first phosphor is a phosphor represented by a chemical formula of Lu 3 Al 5 O 12 :Ce.

5. The yellow light emitting phosphor according to claim 1 , wherein the first phosphor is present in an amount of 62 wt % to 75.8 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

6. The yellow light emitting phosphor according to claim 1 , wherein the second phosphor is present in an amount of 20 wt % to 35 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

7. The yellow light emitting phosphor according to claim 1 , wherein the third phosphor is present in an amount of 3 wt % to 4.2 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

8. The yellow light emitting phosphor according to claim 1 , wherein a ratio of the third phosphor to the second phosphor is within a range of 8.6% to 21.0%.

9. The yellow light emitting phosphor according to claim 1 , wherein the third phosphor is a phosphor represented by (Sr, Ca)AlSiN 3 :Eu.

10. The yellow light emitting phosphor according to claim 1 , wherein an emission spectrum of the yellow light emitting phosphor within a wavelength band of 480 nm to 780 nm has a full width at half maximum of 120 nm or more.

11. A yellow light emitting phosphor comprising:
a first phosphor including at least one of BaYSi 4 N 7 :Eu, Ba 3 Si 6 O 12 N 2 :Eu, CaSi 2 O 2 N 2 :Eu, SrYSi 4 N 7 :Eu, α-type SiAlON(Ca-α-SiAlON:Yb) containing Ca as a metal component, Lu 3 Al 5 O 12 :Ce, and SrSi 2 O 2 N 2 :Eu, the first phosphor being adapted to emit light having a central wavelength located within a band of 510 nm to 550 nm;
a second phosphor including at least one of α-type SiAlON(Li-α-SiAlON:Eu) containing Li as a metal component and α-type SiAlON(Ca-α-SiAlON:Eu) containing Ca as a metal component, the second phosphor being adapted to emit light having a central wavelength located within a band of 560 nm to 600 nm; and
a third phosphor including at least one of CaAlSiN 3 :Eu, (Sr, Ca)AlSiN 3 :Eu, Sr 2 Si 5 N 8 :Eu, K 2 SiF 6 :Mn, La 3 Si 6 N 11 :Ce, SrAlSiN 3 :Eu, SrCN 2 :Eu, Ca 2 Si 5 N 8 :Eu, Ba 2 Si 5 N 8 :Eu, SrAlSi 4 N 7 :Eu, and (Sr, Ba)SiN 2 :Eu, the third phosphor being adapted to emit light having a central wavelength located within a band of 610 nm to 630 nm,
wherein a mixture of the first phosphor to the third phosphor is excited by near ultraviolet (UV) or blue excitation light to emit light of a spectrum having a central wavelength located within a band of 480 nm to 780 nm, and a full width at half maximum of the spectrum is 120 nm or more.

12. The yellow light emitting phosphor according to claim 11 , wherein the third phosphor is designed to minimize absorption of light caused by the excitation light.

13. The yellow light emitting phosphor according to claim 11 , wherein the third phosphor has a light absorption rate of 50% or less at a wavelength of 550 nm.

14. The yellow light emitting phosphor according to claim 11 , wherein the first phosphor is present in an amount of 62 wt % to 75.8 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

15. The yellow light emitting phosphor according to claim 11 , wherein the second phosphor is present in an amount of 20 wt % to 35 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

16. The yellow light emitting phosphor according to claim 11 , wherein the third phosphor is present in an amount of 3 wt % to 4.2 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

17. A yellow light emitting phosphor comprising:
a first phosphor including a phosphor represented by a chemical formula of Lu 3 Al 5 O 12 :Ce, the first phosphor being adapted to emit light having a central wavelength located within a band of 510 nm to 550 nm;
a second phosphor including α-type SiAlON(Li-α-SiAlON:Eu) containing Li as a metal component, the second phosphor being adapted to emit light having a central wavelength located within a band of 560 nm to 600 nm; and
a third phosphor including a phosphor represented by (Sr, Ca)AlSiN 3 :Eu, the third phosphor being adapted to emit light having a central wavelength located within a band of 610 nm to 630 nm,
wherein weight proportions of the first phosphor, the second phosphor, and the third phosphor are respectively within a range of 62 wt % to 75.8 wt %, within a range of 20 wt % to 35 wt %, and within a range of 3 wt % to 4.2 wt % when the sum of the first phosphor to the third phosphor is 100 wt %.

18. The yellow light emitting phosphor according to claim 17 , wherein the third phosphor has a light absorption rate of 50% or less at a wavelength of 550 nm.

19. The yellow light emitting phosphor according to claim 17 , wherein the second phosphor is represented by the following chemical formula;
Li m−2x Eu x Si 12−(m+n) Al m+n O n N 16−n
where, “x”, “m” and “n” fulfill at least one condition of 0.01≦x≦0.1, 0≦m≦2 and 0≦n≦1.

20. A light emitting device package comprising:
the yellow light emitting phosphor according to claim 17 ; and
a light emitting device configured to emit near ultraviolet (UV) or blue light to excite the yellow light emitting phosphor.

Assignees

• Lg Electronics Inc

Inventors

• Yoo Younggil
• Kim Minsung
• Lee Jeongsoo

Classifications

• H10W90/756

  between a chip and a stacked lead frame, conducting package substrate or heat sink · CPC title

• H10W74/00

  Encapsulations, e.g. protective coatings · CPC title

• H10W72/07554

  changes in dispositions · CPC title

• H10W72/5363

  the connected ends being wedge-shaped · CPC title

• H10W72/547

  Dispositions of multiple bond wires · CPC title