Rubber composition for tire tread and tire manufactured by using the same

Patent metadata

Field	Value
Publication number	US-9321909-B2
Application number	US-201414522571-A
Country	US
Kind code	B2
Filing date	Oct 23, 2014
Priority date	Oct 31, 2013
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

Provided are a rubber composition for tire containing raw material rubber and cellulose whiskers, and a tire produced from the same composition and having excellent general properties. Since the rubber composition for tire contains cellulose whiskers having superior reinforcing properties than rubber reinforcing materials, the rubber composition for tire can provide a tire having markedly enhanced properties compared to tires using the conventional rubber reinforcing materials. Also, when cellulose whiskers are applied to the rubber composition for tire, the content of the conventional rubber reinforcing materials can be reduced. As a result, the elongation ratio and low-fuel consumption performance that have been considered poor due to the use of conventional rubber reinforcing materials can be improved to a superior level, and a lightweight tire can be provided.

First claim

What is claimed is:

1. A method for preparing a rubber composition for tire, the method comprising:
dispersing cellulose whiskers in an organic solvent, and preparing a solution having cellulose whiskers dispersed therein; and
adding the solution having cellulose whiskers dispersed therein, to raw material rubber,
wherein the process of producing cellulose whiskers includes hydrolyzing cellulose with an acid or a base at a temperature range greater than 60° C. and equal to or less than 100° C. for 5 hours to 10 hours.

2. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing the solution having cellulose whiskers dispersed therein uses any one organic solvent selected from treated distillate aromatic extract (TDAE) oil, a liquid aging inhibitor, a liquid rubber, and mixtures thereof.

3. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing a solution having cellulose whiskers dispersed therein, includes dispersing cellulose whiskers in an amount of 1 part to 30 parts by weight relative to 100 parts by weight of the organic solvent.

4. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing a solution having cellulose whiskers dispersed therein, includes further adding a surfactant to the organic solvent.

5. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing a solution having cellulose whiskers dispersed therein, includes dispersing cellulose whiskers in the organic solvent, and ultrasonicating the dispersed solution.

6. The method for preparing a rubber composition for tire according to claim 1 , further comprising a process of producing cellulose whiskers before the process of preparing a solution having cellulose whiskers dispersed therein.

7. The method for preparing a rubber composition for tire according to claim 6 , wherein the process of producing cellulose whiskers includes hydrolyzing cellulose with an acid or a base.

8. The method for preparing a rubber composition for tire according to claim 6 , wherein the process of producing cellulose whiskers includes adding 10 parts to 30 parts by weight of cellulose to 100 parts by weight of a 40% to 70% acidic or basic aqueous solution.

9. The method for preparing a rubber composition for tire according to claim 6 , wherein the process of producing cellulose whiskers further includes neutralizing the hydrolyzed reaction mixture.

10. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing the solution having cellulose whiskers dispersed therein uses a liquid rubber as the organic solvent.

11. The method for preparing a rubber composition for tire according to claim 1 , wherein the process of preparing the solution having cellulose whiskers dispersed therein uses the organic solvent chosen from a liquid aging inhibitor, a liquid rubber, and mixtures thereof.

12. The method for preparing a rubber composition for tire according to claim 11 , wherein the liquid aging inhibitor comprises at least one compound chosen from a group consisting of amine-based agents, phenolic agents, quinoline-based agents, imidazole-based agents, carbamic acid metal salts, and waxes.

Assignees

• Hankook Tire Co Ltd

Inventors

• Park Won Il
• Kim Jung Tae

Classifications

• C08K5/42

  Sulfonic acids; Derivatives thereof · CPC title

• C08K7/02 Primary

  Fibres or whiskers · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08J2401/02

  Cellulose; Modified cellulose · CPC title

• C08J2307/00

  Characterised by the use of natural rubber · CPC title