Process for producing cumene

Patent metadata

Field	Value
Publication number	US-9321705-B2
Application number	US-201113886000-A
Country	US
Kind code	B2
Filing date	Nov 15, 2011
Priority date	Nov 17, 2010
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

A process of producing isopropyl benzene which solves the problem of high amount of n-propyl benzene according to the prior art. The process separates the polyisopropyl benzene through a suitable rectification into two streams of relatively lighter and heavier components, wherein the content of diisopropylbenzene in the stream of relatively lighter components is controlled to be at least greater than 95 wt %, and the content of tri-isopropyl benzene in the stream of relatively heavier components is controlled to be at least greater than 0.5 wt %. Such a technical solution subjecting the two streams respectively to the transalkylation solves the problem raised from the prior art, and is useful for the industrial production of isopropyl benzene.

First claim

The invention claimed is:

1. A process of producing isopropyl benzene, comprising steps of:
a) feeding a stream containing polyisopropyl benzene into a polyisopropyl benzene column, resulting in a stream of relatively lighter components at the top of the column, a stream of relatively heavier components at the middle of the column and a stream of heavy components containing tar at the bottom of the column through a separation by rectification, in which the stream of heavy components containing the tar is fed into subsequent procedures; wherein the stream of relatively lighter components contains at least greater than 95 wt % of diisopropylbenzene and the stream of relatively heavier components contains at least greater than 0.5 wt % of triisopropyl benzene; and
b1) feeding a first benzene stream and the stream of relatively lighter components into a first transalkylation zone, contacting with a catalyst for transalkylation, and providing a first isopropyl benzene-containing stream at the bottom of the first transalkylation zone;
feeding a second benzene stream and the stream of relatively heavier components into a second transalkylation zone, contacting with a catalyst for transalkylation, and providing a second isopropyl benzene-containing stream at the bottom of the second transalkylation zone; and
feeding the first isopropyl benzene-containing stream and the second isopropyl benzene-containing stream into subsequent refining procedures, to provide a product isopropyl benzene; or
b2) feeding a first benzene stream and the stream of relatively lighter components into a first transalkylation zone, contacting with a catalyst for transalkylation, and providing a first isopropyl benzene-containing stream at the bottom of the first transalkylation zone;
feeding the first isopropyl benzene-containing stream and the stream of relatively heavier components into a second transalkylation zone, contacting with a catalyst for transalkylation, and providing a second isopropyl benzene-containing stream at the bottom of the second transalkylation zone; and
feeding the second isopropyl benzene-containing stream into subsequent refining procedures, to provide a product isopropyl benzene.

2. The process of producing isopropyl benzene according to claim 1 , wherein in step b1), a weight ratio of the first benzene stream to the stream of relatively lighter components is in a range of 0.3-5 and a weight ratio of the second benzene stream to the stream of relatively heavier components is in a range of 0.3-5; and in step b2), a weight ratio of the first benzene stream to the stream of relatively lighter components is in a range of 0.3-5 and a weight ratio of the first isopropyl benzene-containing stream to the stream of relatively heavier components is in a range of 0.3-5.

3. The process of producing isopropyl benzene according to claim 2 , wherein in step b1), the weight ratio of the first benzene stream to the stream of relatively lighter components is in a range of 0.7-3 and the weight ratio of the second benzene stream to the stream of relatively heavier components is in a range of 0.7-3; and in step b2), the weight ratio of the first benzene stream to the stream of relatively lighter components is in a range of 0.7-3 and the weight ratio of the first isopropyl benzene-containing stream to the stream of relatively heavier components is in a range of 0.7-3.

4. The process of producing isopropyl benzene according to claim 1 , wherein in the stream of relatively lighter components a content of diisopropylbenzene is in a range of 96-100 wt %; and in the stream of relatively heavier components a content of tri-isopropyl benzene is in a range of 1-50 wt %.

5. The process of producing isopropyl benzene according to claim 1 , wherein the catalyst is selected from the group consisting of Y zeolite, Beta zeolite, mordenite, SHY-1, SHY-2 and MCM-22.

6. The process of producing isopropyl benzene according to claim 1 , wherein in-the first transalkylation zone, a reaction temperature is in a range of 130˜190 degrees C., a reaction pressure is in a range of 1.0˜3.0 MPa, and a liquid weight space velocity is in a range of 0.5-10 hour −1 .

7. The process of producing isopropyl benzene according to claim 1 , wherein in the second transalkylation zone, a reaction temperature is in a range of 150˜210 degrees C., a reaction pressure is in a range of 1.0˜3.0 MPa, and a liquid weight space velocity is in a range of 0.5-10 hour −1 .

8. The process of producing isopropyl benzene according to claim 1 , wherein, for the polyisopropyl benzene column, an operation pressure is in a range of −300 to 0 kPa, a column top temperature is in a range of 120-160 degrees C., and a column bottom temperature is in a range of 190-250 degrees C.

9. The process of producing isopropyl benzene according to claim 1 , wherein in step b2), a weight ratio of the first benzene stream to the stream containing the polyisopropyl benzene is in a range of 0.3-5.

10. The process of producing isopropyl benzene according to claim 1 , wherein in the stream of relatively lighter components, a content of diisopropylbenzene is in a range of 98-100 wt %.

11. The process of producing isopropyl benzene according to claim 1 , wherein in the stream of relatively heavier components, a content of tri-isopropyl benzene is in a range of 5-12 wt %.

Assignees

• Gao Huanxin
• Zhou Bin
• Wei Yilun
• Gu Ruifang
• Fang Hua
• Ji Shufang
• Yao Hui
• China Petroleum & Chemical
• Shanghai Res Inst Petrochemical Technology Sinopec

Inventors

• Gao Huanxin
• Zhou Bin
• Wei Yilun
• Gu Ruifang
• Fang Hua
• Ji Shufang
• Yao Hui

Classifications

• C07C6/06 Primary

  at a cyclic carbon-to-carbon double bond · CPC title

• C07C6/126 Primary

  of more than one hydrocarbon · CPC title

• C07C2529/08

  of the faujasite type, e.g. type X or Y · CPC title

• C07C2529/70

  of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 · CPC title

• C07C15/085

  Isopropylbenzene · CPC title