Stable percarboxylic acid compositions and uses thereof

Patent metadata

Field	Value
Publication number	US-9321664-B2
Application number	US-201313844515-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Dec 20, 2011
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

The present invention relates generally to stable percarboxylic acid compositions comprising, inter alia, at least two stabilizing agents, and various uses for water treatments, including water treatments in connection with oil- and gas-field operations. The present invention also relates to slick water compositions and gel based compositions that comprise stable percarboxylic acid compositions and the use thereof in oil- and gas-field operations.

First claim

The claimed invention is:

1. A composition, which composition comprises:
1) a C 1 -C 22 carboxylic acid;
2) a C 1 -C 22 percarboxylic acid;
3) hydrogen peroxide;
4) a first stabilizing agent, which is a picolinic acid or a compound having the following Formula (IA):

wherein
R 1 is OH;
R 2 is OH;
each R 3 is independently (C 1 -C 6 )alkyl, (C 2 -C 6 )alkenyl or (C 2 -C 6 )alkynyl; and
n is a number from zero to 3;
or a salt thereof, and

wherein said first stabilizing agent has a concentration of at least about 0.005 wt-%;
or a compound having the following Formula (IB):

wherein
R 1 is OH;
R 2 is OH;
each R 3 is independently (C 1 -C 6 )alkyl, (C 2 -C 6 )alkenyl or (C 2 -C 6 )alkynyl; and
n is a number from zero to 3;
or a salt thereof;

5) a second stabilizing agent, which is a compound having the following Formula (IIA):

wherein
R 1 , R 2 , R 3 , and R 4 are independently hydrogen;
R 5 is (C 1 -C 6 )alkyl, (C 2 -C 6 )alkenyl or (C 2 -C 6 )alkynyl; and
R 6 is hydrogen, (C 1 -C 6 )alkyl, (C 2 -C 6 )alkenyl or (C 2 -C 6 )alkynyl;
or a salt thereof, and

wherein said second stabilizing agent has a concentration of at least about 0.1 wt-%; and
wherein said C 1 -C 22 percarboxylic acid has a concentration of about 10 wt-% to about 30 wt-%, said hydrogen peroxide has a concentration of at least about 0.1 wt-%, said C 1 -C 22 percarboxylic acid has a concentration of at least about 3 times of the concentration of said hydrogen peroxide, and said composition has a pH at about 4 or less, and said composition retains at least about 80% of the C 1 -C 22 percarboxylic acid activity after storage of about 30 days at about 50° C.

2. The composition of claim 1 , wherein the C 1 -C 22 percarboxylic acid has a concentration of at least about 5 times of the concentration of the hydrogen peroxide.

3. The composition of claim 1 , wherein the C 1 -C 22 carboxylic acid comprises acetic acid, octanoic acid and/or sulfonated oleic acid.

4. The composition of claim 1 , wherein the C 1 -C 22 carboxylic acid has a concentration of about 50 wt-%, the C 1 -C 22 percarboxylic acid has a concentration of about 20 wt-%, and the hydrogen peroxide has a concentration of at least about 3 wt-%.

5. The composition of claim 1 , wherein the first stabilizing agent is a 2,6-pyridinedicarboxylic acid, or a salt thereof, and the second stabilizing agent is HEDP, or a salt thereof.

6. The composition of claim 1 , wherein the first and second stabilizing agents delay or prevent the composition from exceeding its self-accelerating decomposition temperature (SADT).

7. The composition of claim 1 , which retains at least about 90% of the C 1 -C 22 percarboxylic acid activity after storage of about 30 days at about 50° C.

8. A method for treating water, which method comprises providing a composition of claim 1 to a water source in need of treatment to form a treated water source, wherein said treated water source comprises from about 1 ppm to about 1,000 ppm of said C 1 -C 22 percarboxylic acid.

9. The method of claim 8 , wherein the water source in need of treatment is selected from the group consisting of fresh water, pond water, sea water, produced water and a combination thereof.

10. The method of claim 8 , wherein the C 1 -C 22 percarboxylic acid comprises peroxyacetic acid, peroxyoctanoic acid and/or peroxysulfonated oleic acid.

11. The method of claim 8 , wherein the treated water source retains at least about 60% of the initial C 1 -C 22 percarboxylic acid activity in the treated water source for 15 minutes after the treated water source is formed.

12. The method of claim 8 , which further comprises directing the treated water source into a subterranean environment or disposing of the treated water source.

13. The method of claim 8 , wherein the water source does not comprise reuse water, the treated water source comprises from about 10 ppm to about 20 ppm of the C 1 -C 22 percarboxylic acid and from about 1 ppm to about 2 ppm of hydrogen peroxide and the treated water source does not comprise a friction reducer and/or a rheology modifier.

14. The method of claim 8 , wherein the water source is a blended water source that comprises about 80 wt-% fresh water or pond water and about 20 wt-% of reuse water, the treated water source comprises from about 25 ppm to about 35 ppm of the C 1 -C 22 percarboxylic acid and from about 2 ppm to about 3 ppm of hydrogen peroxide and catalase, the treated water source does not comprise a friction reducer and/or a rheology modifier, and the treated water source is formed before reaching a blending tub.

15. The method of claim 8 , wherein the water source is a blended water source that comprises about 80 wt-% fresh water or pond water and about 20 wt-% of reuse water, the treated water source comprises from about 25 ppm to about 35 ppm of the C 1 -C 22 percarboxylic acid and from about 2 ppm to about 3 ppm of hydrogen peroxide and catalase, the treated water source comprises a friction reducer and/or a rheology modifier, and the treated water source is formed in a blending tub.

16. The method of claim 8 , wherein the treated water source comprises from about 30 ppm or less of the C 1 -C 22 percarboxylic acid and about 0.5 ppm or less of the hydrogen peroxide, the treated water source comprises a friction reducer and/or a rheology modifier, and the treated water source is directed into or is at a subterranean environment.

17. The composition of claim 1 , which does not comprise a mineral acid.

18. The composition of claim 6 , which does not comprise a mineral acid.

19. The composition of claim 7 , which does not comprise a mineral acid.

20. The composition of claim 1 , wherein the first stabilizing agent has a concentration from about 0.005 wt-% to about 5 wt-%.

21. The composition of claim 1 , wherein the second stabilizing agent has a concentration from about 0.1 wt-% to about 10 wt-%.

Assignees

• Ecolab Usa Inc

Inventors

• Li Junzhong
• Mcsherry David
• Brewster Allison
• Staub Richard
• De Paula Renato
• Bolduc John Wilhelm
• Ryther Robert J
• Keasler Victor V

Classifications

• C11D7/04

  Water-soluble compounds · CPC title

• A01N25/22

  containing ingredients stabilising the active ingredients · CPC title

• C11D3/394 Primary

  Organic compounds · CPC title

• C02F2303/04

  Disinfection · CPC title

• C02F2103/42

  from bathing facilities, e.g. swimming pools · CPC title