Carbon microparticle having lignin as raw material and preparation method therefor

Patent metadata

Field	Value
Publication number	US-9321649-B2
Application number	US-201213536053-A
Country	US
Kind code	B2
Filing date	Jun 28, 2012
Priority date	Dec 3, 2007
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

A method for preparing a carbon microparticle from an organic raw material having lignin as a main constituent, wherein an aqueous solution with 5% total concentration of lignin and sodium hydroxide (the proportion in mass is 1:0.5) is spray-dried to prepare a complex microparticle. This complex microparticle is heat-processed under nitrogen atmosphere at 600° C. for one hour and cooled. Thereafter, this is washed with water and further dried to prepare a hollow carbon microparticle such as those shown in FIG. 2 ( b ). The prepared carbon microparticle is light-weight and has an equivalent specific surface area to commercially available activated charcoal.

First claim

The invention claimed is:

1. A hollow carbon microparticle preparation method, comprising:
providing an aqueous solution of an organic raw material having lignin as a main constituent;
turning the aqueous solution into a micro-droplet;
drying the micro-droplet to prepare a microparticle; and
thermally decomposing the microparticle in a range of 300° C. to 1200° C. to prepare a hollow carbon microparticle.

2. A hollow carbon microparticle preparation method, comprising:
providing a mixed aqueous solution of an organic raw material having lignin as a main constituent and an inorganic substance;
turning the mixed aqueous solution into a micro-droplet;
drying the micro-droplet to prepare a microparticle; and
thermally decomposing the microparticle in a range of 300° C. to 1200° C. to prepare a hollow carbon microparticle.

3. The hollow carbon microparticle preparation method according to claim 2 ,
wherein the inorganic substance is a metal compound constituted by one or more species selected from the group consisting of an oxide, a hydroxide, a carbonate and a halide of a metal, and
wherein based on the property that a carbon wall thickness of the carbon microparticle becomes thinner as the proportion of the metal compound added increases, the proportion of the metal compound added is adjusted when preparing the mixed solution, so as to control the carbon wall thickness of the microparticle.

4. The hollow carbon microparticle preparation method according to claim 2 , further comprising bringing the carbon microparticle obtained by the thermal decomposition into contact with a gas having lower reactivity to the surface of the carbon microparticle than the air, thereby inactivating the surface of the carbon microparticle by reaction with the gas and inhibiting a rapid heat generation occurring when the carbon microparticle is taken out into the air.

5. A hollow carbon microparticle preparation method, comprising:
providing a mixed aqueous solution of an organic raw material having lignin as a main constituent and a basic compound selected from the group consisting of alkali hydroxide and alkali carboxylate;
turning the mixed aqueous solution into a micro-droplet;
drying the micro-droplet to prepare a microparticle; and
thermally decomposing the microparticle in a range of 300° C. to 1200° C. to prepare a hollow carbon microparticle,
wherein the specific surface area is increased to prepare a carbon microparticle.

6. A hollow carbon microparticle preparation method, comprising:
preprocessing a pulp waste solution to raise a concentration of lignin included in the pulp waste solution, the pulp waste solution being aqueous,
turning the pulp waste solution thus preprocessed into a micro-droplet;
drying the micro-droplet to prepare a microparticle; and
thermally decomposing the microparticle in a range of 300° C. to 1200° C. to prepare a hollow carbon microparticle.

7. A hollow carbon microparticle preparation method, comprising:
preprocessing a pulp waste solution to raise a concentration of lignin included in the pulp waste solution, the pulp waste solution being aqueous;
adding an inorganic substance to the pulp waste solution;
turning the pulp waste solution into a micro-droplet;
drying the micro-droplet to prepare a microparticle; and
thermally decomposing the microparticle in a range of 300° C. to 1200° C. to prepare a carbon microparticle.

8. The hollow carbon microparticle preparation method according to claim 6 ,
wherein the step of preprocessing includes carrying out separation-collection of lignin by ultrafiltration.

9. The hollow carbon microparticle preparation method according to claim 7 ,
wherein the step of preprocessing includes carrying out separation-collection of high molecular weight lignin by ultrafiltration.

10. The hollow carbon microparticle preparation method according to claim 6 ,
wherein the step of preprocessing includes absorbing carbon dioxide by the pulp waste solution to thereby decrease a hydrogen ion index and deposit a portion of an organic constituent, and removing the organic constituent from the pulp waste solution.

11. The hollow carbon microparticle preparation method according to claim 7 ,
wherein the step of preprocessing includes absorbing carbon dioxide by the pulp waste solution to thereby decrease a hydrogen ion index and deposit a portion of an organic constituent, and removing the organic constituent from the pulp waste solution.

Assignees

• Kamegawa Katsumi
• Sakaki Tsuyoshi
• Sakanishi Kinya
• Kodama Masaya
• Nishikubo Keiko
• Adachi Yoshio
• Nat Inst Of Advanced Ind Scien

Inventors

• Kamegawa Katsumi
• Sakaki Tsuyoshi
• Sakanishi Kinya
• Kodama Masaya
• Nishikubo Keiko
• Adachi Yoshio

Classifications

• C01B31/02 Primary

  Chemistry & Metallurgy · mapped topic

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C01P2004/32

  Spheres · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C01B32/348 Primary

  Metallic compounds · CPC title