Styrene removal in paraxylene recovery process

Patent metadata

Field	Value
Publication number	US-9321029-B2
Application number	US-201514849918-A
Country	US
Kind code	B2
Filing date	Sep 10, 2015
Priority date	May 31, 2012
Publication date	Apr 26, 2016
Grant date	Apr 26, 2016

Abstract

The invention relates to removal of styrene from hydrocarbon mixtures, and more particularly, removal of styrene from hydrocarbon mixtures containing higher than equilibrium paraxylene concentrations.

First claim

What is claimed is:

1. An apparatus comprising an alkylation reactor fluidly connected with a purification system comprising at least one apparatus adapted for the selective removal of styrene by contact of a process stream with at least one material selected from MWW molecular sieves, clays, and mixtures thereof, to provide a product stream without significant production of benzene and without significant loss of paraxylene by isomerization, said at least one apparatus adapted for the removal of styrene fluidly connect to and upstream of an apparatus for the selective removal of paraxylene from a process stream,
wherein the selective removal of styrene causes less than 5 wt % of paraxylene to be lost to isomerization by said contact, and
wherein said contact comprises initially contacting said process stream with said at least one material at a temperature of about 100° C. to about 180° C. to effectively remove styrene until paraxylene lost by isomerization is less than 5 wt % and subsequently raising said temperature to about 275° C. in a step-wise manner while maintaining paraxylene lost by isomerization to less than 5 wt %.

2. The apparatus according to claim 1 , wherein said purification system comprises a vessel containing a material selected from MCM-22, MCM-49, and MCM-56 molecular sieves, acid-treated clays, and mixtures thereof.

3. The apparatus according to claim 2 , further comprising a liquid isomerization unit, a vapor phase isomerization unit, or a combination thereof.

4. The apparatus according to claim 3 , further characterized by being integrated by fluid connection and/or heat exchange to a system adapted for at least one of the processes selected from: (i) transalkylation of an aromatic species; (ii) disproportionation of an aromatic species; and (iii) disproportionation and transalkylation of an aromatic species; wherein said disproportionation may be selective disproportionation or non-selective disproportionation.

Assignees

• Exxonmobil Chem Patents Inc

Inventors

• Heeter Glenn A
• Ou John D
• Gawlik Allen S
• Osby Terrance C
• Abichandani Jeevan S
• Tinger Robert G
• Eilands Indulis J
• Luo Shifang L

Classifications

• B01J19/245

  placed in series · CPC title

• B01J19/24 Primary

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07C7/13 Primary

  by molecular-sieve technique · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title