Photoelectric conversion material
US-9224896-B2 · Dec 29, 2015 · US
US9318327B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9318327-B2 |
| Application number | US-56371206-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 28, 2006 |
| Priority date | Nov 28, 2006 |
| Publication date | Apr 19, 2016 |
| Grant date | Apr 19, 2016 |
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Semiconductor device structures are provided that are suitable for use in the fabrication of electronic devices such as light emitting diodes. The semiconductor device structures include a substrate having a roughened growth surface suitable for supporting the growth of an epitaxial region thereon. The device structure can include an epitaxial region having reduced defects and/or improved radiation extraction efficiency on the roughened growth surface of the substrate. The roughened growth surface of the substrate can have an average roughness R a of at least about 1 nanometer (nm) and an average peak to valley height R z of at least about 10 nanometers (nm).
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That which is claimed is: 1. A semiconductor device structure suitable for use in the fabrication of electronic devices such as light emitting diodes, comprising: a substrate comprising a substantially randomly or irregularly roughened growth surface suitable for supporting the growth of an epitaxial region thereon, wherein the roughened growth surface of said substrate has an average roughness R a of at least about 1 nanometer (nm); an epitaxial region on said substrate; and first and second ohmic contacts on opposite sides of said semiconductor device, such that said semiconductor device is a vertical semiconductor device. 2. The semiconductor device structure of claim 1 , wherein the roughened growth surface of said substrate has an average peak to valley height R z of at least about 10 nanometers (nm). 3. The semiconductor device structure of claim 1 , wherein the epitaxial region includes fewer defects as compared to the same epitaxial region on a substantially smooth growth surface of said substrate. 4. The semiconductor device structure of claim 1 , wherein the epitaxial region has a threading dislocation of less than or about 6×10 8 cm −2 . 5. The semiconductor device structure of claim 4 , wherein the epitaxial region has a threading dislocation of less than or about 10 8 cm −2 . 6. The semiconductor device structure of claim 1 , wherein the substrate further comprises a second roughened surface opposite the roughened growth surface. 7. The semiconductor device structure of claim 6 , wherein the second roughened surface of the substrate has an average roughness R a of at least about 1 nanometer (nm). 8. The semiconductor device structure of claim 7 , wherein the second roughened surface of the substrate has an average peak to valley height R z of at least about 10 nanometers (nm). 9. The semiconductor device structure of claim 1 , wherein said substrate comprises a material selected from silicon carbide, aluminum nitride, gallium nitride, silicon, gallium arsenide, gallium phosphide, zinc oxide, and sapphire. 10. The semiconductor device structure of claim 1 , wherein said substrate comprises a conductive substrate. 11. The semiconductor device structure of claim 1 , wherein the substrate comprises silicon carbide (SiC). 12. The semiconductor device structure of claim 1 , wherein the epitaxial region comprises an active region capable of emitting radiation. 13. The semiconductor device structure of claim 12 , wherein the roughened growth surface of the substrate has a roughness sufficient to increase the radiation extraction efficiency of the active region as compared to the radiation extraction efficiency of the same active region on a substantially smooth growth surface. 14. The semiconductor device structure of claim 13 , wherein the active region comprises a Group III nitride. 15. The semiconductor device structure of claim 14 , wherein the Group III nitride is selected from the group consisting of A 1 N, GaN, InN, A 1 GaN, AlInN, InGaN, and AlInGaN. 16. The semiconductor device structure of claim 15 , wherein Group III nitride comprises InGaN. 17. The semiconductor device structure of claim 12 , further comprising an n-type layer along a first surface of the active region and a p-type layer on a second opposing surface of the active region to form a diode region. 18. The semiconductor device structure of claim 17 , wherein each of the n-type layer and the p-type layer comprises a Group III nitride layer. 19. The semiconductor device structure of claim 1 , wherein the epitaxial region includes a buffer layer. 20. A light emitting diode, comprising: a conductive substrate comprising a substantially randomly or irregularly roughened growth surface suitable for supporting the growth of an epitaxial region thereon, wherein the roughened growth surface of the conductive substrate has an average roughness R a of at least about 1 nanometer (nm); a diode region comprising an epitaxial region on the growth surface of the conductive substrate; and a first ohmic layer on a surface of the conductive substrate opposite the diode region and a second ohmic contact on a surface of the diode region opposite the conductive substrate. 21. The light emitting diode of claim 20 , wherein the roughened growth surface of the substrate has an average peak to valley height R z of at least about 10 nanometers (nm). 22. The light emitting diode of claim 20 , wherein the epitaxial region includes fewer defects as compared to the same epitaxial region on a substantially smooth growth surface of said substrate. 23. The light emitting diode of claim 20 , wherein the epitaxial region has a threading dislocation of less than or about 6×10 8 cm −2 . 24. The light emitting diode of claim 23 , wherein the epitaxial region has a threading dislocation of less than or about 10 8 cm −2 . 25. The light emitting diode of claim 20 , wherein the substrate further comprises a second roughened surface opposite the roughened growth surface. 26. The light emitting diode of claim 25 , wherein the second roughened surface of the substrate has an average roughness R a of at least about 1 nanometer (nm). 27. The light emitting diode of claim 26 , wherein the second roughened surface of the substrate has an average peak to valley height R z of at least about 10 nanometers (nm). 28. The light emitting diode of claim 20 , wherein said substrate comprises a material selected from silicon carbide, aluminum nitride, gallium nitride, silicon, gallium arsenide, gallium phosphide, zinc oxide, and sapphire. 29. The light emitting diode of claim 20 , wherein said substrate comprises a conductive substrate. 30. The light emitting diode of claim 20 , wherein the substrate comprises silicon carbide (SiC). 31. The light emitting diode of claim 20 , wherein the diode region comprises a n-type layer, an active region, and a p-type layer. 32. The light emitting diode of claim 31 , wherein each of the n-type layer, the active layer and the p-type layer independently comprises a Group III nitride layer. 33. The light emitting diode of claim 20 , further comprising a reflective layer on a surface of the diode region opposite the substrate. 34. The light emitting diode of claim 33 , further comprising a submount on a surface of the reflective layer opposite the diode region. 35. A method of fabricating a semiconductor device structure suitable for use in the fabrication of electronic devices such as light emitting diodes, comprising: treating a substrate growth surface suitable for supporting the growth of an epitaxial region thereon to substantially randomly or irregularly roughen the growth surface sufficient to provide a growth surface having an average roughness R a of at least about 1 nanometer (nm); forming an epitaxial region on the roughened growth surface of the substrate; and providing first and second ohmic contacts on opposite sides of said semiconductor device, such that said semiconductor device is a vertical semiconductor device. 36. The method of claim 35 , wherein the treating step comprises treating the growth surface of the substrate under conditions sufficient to provide a growth surface having an average peak to valley hei
Nitrides · CPC title
being conductive materials, e.g. metallic silicides · CPC title
being crystalline insulating materials · CPC title
Oxides · CPC title
Arsenides · CPC title
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