Marking paper products

Patent metadata

Field	Value
Publication number	US-9317722-B2
Application number	US-201414308156-A
Country	US
Kind code	B2
Filing date	Jun 18, 2014
Priority date	Oct 14, 2009
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

Methods of marking paper products and marked paper products are provided. Some methods include irradiating the paper product to alter the functionalization of the paper.

First claim

What is claimed is:

1. A method of determining whether a sample paper product has been marked in a discrete portion by a functionality-altering dose of irradiation, the method comprising:
(a) irradiating a discrete portion of a paper product with accelerated particles at a dose of irradiation sufficient to alter the functionality of the discrete portion of the paper, thereby providing a marked paper product; and
(b) utilizing a technique selected from the group consisting of infrared spectroscopy (IR), atomic force microscopy (AFM), chemical force microscopy (CFM), or electron spin resonance (ESR), and combinations thereof, comprising:
(i) determining the functionality of a corresponding discrete portion of a sample paper product and
(ii) comparing the discrete portions of the sample paper product and the marked paper product thereby determining whether the sample paper product has been marked in the same manner as the marked paper product, using the marked paper product as a control.

2. The method of claim 1 wherein the marked or sample paper product comprises a note.

3. The method of claim 2 wherein the note comprises currency.

4. The method of claim 3 wherein the note comprises paper money.

5. The method of claim 4 wherein the paper money is marked with a watermark.

6. The method of claim 2 wherein the note is marked with a symbol.

7. The method of claim 1 wherein the irradiating with accelerated particles comprises irradiating with accelerated electrons.

8. The method of claim 7 wherein the electrons have an energy of at least 0.25 MeV.

9. The method of claim 1 wherein the irradiating with accelerated particles comprises irradiating with particles heavier than an electron.

10. The method of claim 9 wherein the particles are positively charged particles.

11. The method of claim 9 wherein the particles are negatively charged particles.

12. The method of claim 9 wherein the particles are selected from the group consisting of protons, carbon ions, and combinations thereof.

13. The method of claim 9 wherein the irradiating with the particles occurs in a fluid.

14. The method of claim 13 wherein at least some of the particles generate additional chemical species by interacting with the fluid.

15. The method of claim 14 wherein the additional chemical species comprises ozone.

16. The method of claim 1 wherein the paper product is marked by said irradiating at a dose sufficient to also crosslink material of the paper product.

17. The method of claim 1 wherein the irradiating comprises irradiating with a total dosage of at least 0.1 Mrad.

18. The method of claim 17 wherein the dosage is from about 0.25 Mrad to 5 Mrad.

Assignees

• Xyleco Inc

Inventors

• Medoff Marshall

Classifications

• H01J3/04

  Ion guns · CPC title

• B32B2554/00

  Paper of special types, e.g. banknotes · CPC title

• G01N2223/102

  beta or electrons · CPC title

• D21H21/48 Primary

  Elements suited for physical verification, e.g. by irradiation · CPC title

• B32B29/002

  as the main or only constituent of a layer, which is next to another layer of the same or of a different material (next to a layer of a particular substance B32B9/06; next to a bituminous or tarry layer B32B11/06; next to a water-setting substance layer B32B13/08; next to a metal layer B32B15/12; next to a glass layer B32B17/065; next to a layer formed of natural mineral fibres or particles B32B19/046; next to a wood layer B32B21/06; next to a cellulosic plastic layer B32B23/06; next to a natural or synthetic rubber layer B32B25/06; next to a synthetic resin layer B32B27/10) · CPC title