Toner for electrostatic image development

Patent metadata

Field	Value
Publication number	US-9316937-B2
Application number	US-201414311933-A
Country	US
Kind code	B2
Filing date	Jun 23, 2014
Priority date	Jun 26, 2013
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

Provided is a toner for electrostatic image development that has good low-temperature fixability, also has long-term heat-resistant storage stability and can form an image with unevenness in gloss suppressed. The toner for electrostatic image development includes toner particles. The toner particles have a domain-matrix structure in which a first domain phase including a crystalline polyester resin A and a second domain phase including a crystalline polyester resin B are dispersed in a matrix phase including a vinyl resin. The average diameter of the first domain phase is 400 to 900 nm, and the average diameter of the second domain phase is 10 to 200 nm. The melting point of the crystalline polyester resin A and the melting point of the crystalline polyester resin B are each 95° C. or lower.

First claim

The invention claimed is:

1. A toner for electrostatic image development, comprising toner particles, wherein
the toner particles have a domain-matrix structure in which a first domain phase comprising a crystalline polyester resin A and a second domain phase comprising a crystalline polyester resin B are dispersed in a matrix phase comprising a vinyl resin,
an average diameter of the first domain phase is 400 to 900 nm,
an average diameter of the second domain phase is 10 to 200 nm, and
a melting point of the crystalline polyester resin A and a melting point of the crystalline polyester resin B are each 95° C. or lower.

2. The toner for electrostatic image development according to claim 1 , wherein
the vinyl resin has a carboxy group concentration of 0.4 to 0.8 mmol/g,
the crystalline polyester resin A has an ester group concentration of 4.6 to 5.5 mmol/g, and
the crystalline polyester resin B has an ester group concentration of 6.4 to 7.7 mmol/g.

3. The toner for electrostatic image development according to claim 2 , wherein a difference between the ester group concentration in the crystalline polyester resin B and the ester group concentration in the crystalline polyester resin A is 1.0 to 3.0 mol/g.

4. The toner for electrostatic image development according to claim 2 , wherein the vinyl resin has the carboxy group concentration of 0.5 to 0.7 mmol/g.

5. The toner for electrostatic image development according to claim 2 , wherein the crystalline polyester resin A has the ester group concentration of 4.8 to 5.2 mmol/g.

6. The toner for electrostatic image development according to claim 2 , wherein the crystalline polyester resin B has the ester group concentration of 6.5 to 7.2 mmol/g.

7. The toner for electrostatic image development according to claim 1 , wherein a ratio of an amount of the crystalline polyester resin B with respect to a total amount of the resins constituting the toner particles is 2 to 5% by mass, and
a ratio of the amount of the crystalline polyester resin B with respect to an amount of the crystalline polyester resin A is 10 to 25% by mass.

8. The toner for electrostatic image development according to claim 1 , wherein a melting point of the crystalline polyester resin B is 65° C. or higher.

9. The toner for electrostatic image development according to claim 8 , wherein the melting point of the crystalline polyester resin B is 65 to 80° C.

10. The toner for electrostatic image development according to claim 1 , wherein the toner particles further include a third domain phase comprising a parting agent, the third domain phase being dispersed in the matrix phase.

11. The toner for electrostatic image development according to claim 1 , wherein the average diameter of the first domain phase is 550 to 700 nm.

12. The toner for electrostatic image development according to claim 1 , wherein the average diameter of the second domain phase is 20 to 120 nm.

13. The toner for electrostatic image development according to claim 1 , wherein the toner for electrostatic image development is manufactured by an emulsion aggregation process.

14. The toner for electrostatic image development according to claim 1 , wherein a ratio of an amount of the crystalline polyester resin A with respect to a total amount of the resins constituting the toner particles is 10 to 25% by mass.

15. The toner for electrostatic image development according to claim 1 , wherein the melting point of the crystalline polyester resin A is 65 to 90° C.

16. The toner for electrostatic image development according to claim 1 , wherein a glass transition point of the vinyl resin is 35 to 65° C.

Assignees

• Konica Minolta Inc

Inventors

• Amemiya Taiki
• Matsushima Kaori
• Onishi Junya
• Shirai Aya
• Kawamura Takaki

Classifications

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08711

  with esters of acrylic or methacrylic acid · CPC title

• G03G9/08755 Primary

  Polyesters · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/0825

  characterised by their structure; characterised by non-homogenuous distribution of components (microcapsular toners G03G9/093) · CPC title