Retroreflectors for remote detection

Patent metadata

Field	Value
Publication number	US-9316593-B2
Application number	US-201113297657-A
Country	US
Kind code	B2
Filing date	Nov 16, 2011
Priority date	Nov 17, 2010
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

A detection system includes a retroreflector and a layer of material over the retroreflector, the material being subject to change in transmission with respect to an optical property of radiation, e.g. wavelength or polarization, with exposure to a phenomenon. The retroreflector and layer are illuminated from a radiation source of multiple aspects of the optical property. A sensor senses radiation retroreflected back through the layer. The retroreflector may, for example, be an array of or individual prisms or an array of or individual cat's eye microspheres. The layer of material above the retroreflector can include a colorimetric dye. In an embodiment, the retroreflector and layer are on the surface of a carrier that moves through a medium, e.g. a projectile or vehicle moving through the air. In a method of detecting a phenomenon, retroreflective elements are distributed in an array, as in the atmosphere or across a region of ground.

First claim

What is claimed is:

1. A detection system comprising:
an array of physically unconnected retroreflective elements distributed over a region to map across the array the presence or absence of a chemical in an environment, each retroreflective element including a material having a chemical composition that changes its chemistry when exposed to the chemical in the environment, the material being subject to a change in light absorption of the material, on exposure to the chemical, that results in a change in transmission of incident radiation through the material having the chemical composition, the retroreflective element being able to retroreflect light from any direction and being exposed to light in all directions;
a radiation source to illuminate the retroreflective elements with radiation at multiple values of an optical property of the radiation; and
a sensor sensing radiation reflected from the retroreflective elements.

2. The detection system of claim 1 wherein the retroreflective elements are projectiles distributed into an aerosol and through the atmosphere.

3. The detection system of claim 1 wherein the retroreflective elements are arranged in a grid across a region of ground.

4. The detection system of claim 1 wherein each retroreflective element comprises a prism.

5. The detection system of claim 1 wherein each retroreflective element comprises a cat's eye microsphere.

6. The detection system of claim 1 wherein the retroreflective elements have a varied response in retroreflected wavelength on exposure to the chemical.

7. The detection system of claim 1 wherein the radiation source illuminates a region of each retroreflective element with radiation at multiple values of the optical property, and wherein the sensor senses radiation being retroreflected from the region.

8. The detection system of claim 1 wherein each retroreflective element is a single cat's eye retroreflector coated with a layer of the material, the retroreflector being a ball that is completely surrounded by the layer of the material, the retroreflector and layer being exposed to light in all directions.

9. The detection system of claim 1 wherein the material is subject to color change on exposure to the chemical and the radiation source emits radiation at multiple wavelengths.

10. The detection system of claim 9 wherein the radiation source comprises plural lasers of different wavelengths.

11. The detection system of claim 9 wherein the sensor comprises plural filters for different wavelengths.

12. The detection system of claim 9 wherein the material comprises a colorimetric dye.

13. A method of detecting a chemical comprising:
distributing an array of physically unconnected retroreflective elements over a region to map across the array the presence or absence of a chemical in an environment, each retroreflective element including a material having a chemical composition that changes its chemistry when exposed to the chemical in the environment, the material being subject to a change in light absorption of the material, on exposure to the chemical, that results in a change in transmission of incident radiation through the material having the chemical composition;
illuminating the array of retroreflective elements with radiation at multiple values of an optical property of the radiation; and
sensing radiation retroreflected from the retroreflective elements.

14. The method of claim 13 wherein the retroreflective elements are illuminated with multiple wavelengths and wherein sensing radiation comprises filtering at different retroreflected wavelengths.

15. The method of claim 13 wherein the retroreflective elements are illuminated with different wavelengths at different times.

16. The method of claim 13 wherein a region of each retroreflective element is illuminated with radiation at multiple values of the optical property, and wherein radiation retroreflected from the region is sensed.

17. The method of claim 13 wherein each retroreflective element is a single cat's eye retroreflector coated with a layer of the material, the retroreflector being a ball that is completely surrounded by the layer of the material, the retroreflector and layer being exposed to light in all directions.

18. The method of claim 13 wherein the retroreflective elements are illuminated with radiation at multiple wavelengths and the material is subject to color change on exposure to the chemical.

19. The method of claim 18 wherein retroreflective elements are illuminated with lasers.

20. A detection device consisting of a single cat's eye retroreflector coated with a layer of material, the material having a chemical composition that changes its chemistry when exposed to a chemical in an environment, the material changing transmission of incident radiation through the material as a result of a change in an intrinsic optical property of the material when exposed to the chemical, the retroreflector being a ball that is completely surrounded by the layer of material and that can retroreflect light from any direction, the retroreflector and layer being exposed to light in all directions.

21. The retroreflector of claim 20 wherein the retroreflector is a microsphere.

22. The retroreflector of claim 20 wherein the material comprises a colorimetric dye.

23. A detection device comprising:
an array of physically unconnected retroreflective elements distributed over a region to map across the array the presence or absence of a chemical in an environment, each retroreflective element including:
a retroreflector that can retroreflect light from any direction; and
a layer of material over the retroreflector, the material having a chemical composition that changes its chemistry when exposed to the chemical in the environment, the material being subject to a change in light absorption of the material, on exposure to the chemical, that results in a change in transmission of incident radiation through the material having the chemical composition, the retroreflector and layer being exposed to light in all directions.

24. The detection device of claim 23 wherein the retroreflector and layer comprise a projectile.

25. The detection device of claim 23 wherein the retroreflector comprises a cat's eye microsphere.

26. The detection device of claim 23 further comprising a radiation source emitting radiation at multiple values of the optical property to illuminate the retroreflector through the layer and a sensor sensing radiation passing through the layer and subsequently being retroreflected.

27. The detection system of claim 26 wherein the radiation source illuminates a region of the retroreflector with radiation at multiple values of the optical property, and wherein the sensor senses radiation being retroreflected from the region.

Assignees

• Switkes Michael
• Rothschild Mordechai
• Massachusetts Inst Technology

Inventors

• Switkes Michael
• Rothschild Mordechai

Classifications

• G01N31/22

  using chemical indicators (G01N31/02 takes precedence) · CPC title

• G01N21/78 Primary

  producing a change of colour · CPC title