Method for pretreating cellulose pulp

Patent metadata

Field	Value
Publication number	US-9315942-B2
Application number	US-201314376875-A
Country	US
Kind code	B2
Filing date	Feb 11, 2013
Priority date	Feb 10, 2012
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

A Method of pretreating native cellulose pulp in the manufacture of nanofibrillated cellulose, and a nanofibrillated cellulose product obtainable by the method.

First claim

The invention claimed is:

1. A method for the manufacture of nanofibrillated cellulose, the method comprising:
pretreating native cellulose pulp, the pretreating comprising
bringing an aqueous suspension of native cellulose pulp into contact with an inorganic or organic acid,
agitating the aqueous suspension of native cellulose pulp and inorganic or organic acid to obtain a pH below about 4,
removing water from the aqueous suspension of native cellulose pulp and inorganic or organic acid to obtain solid matter,
washing the solid matter with water, thereby forming an aqueous suspension of the solid matter,
adding at least one water soluble salt of NH 4 + , alkali metal, alkaline earth metal, or metal to the formed suspension,
agitating the formed suspension,
adjusting the pH of the formed suspension to about 7.5 to 12 using an inorganic base,
removing water to yield solid matter of the formed suspension, and
washing the solid matter of the formed suspension with distilled or deionized water to yield pretreated native cellulose pulp;

forming an aqueous suspension of the pretreated native cellulose pulp; and
disintegrating the aqueous suspension of the pretreated native cellulose pulp mechanically.

2. The method according to claim 1 , wherein the organic acid is selected from C1-C8 carboxylic acids, and the inorganic acid is selected from hydrochloric acid, nitric acid, hydrobromic acid and sulphuric acid.

3. The method according to claim 2 , wherein the organic acid is selected from acetic acid, formic acid, butyric acid, propionic acid, oxalic acid and lactic acid.

4. The method according to claim 2 , wherein the pH is adjusted using the acid to below 3.

5. The method according to claim 2 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is selected from inorganic salts, complexes and salts formed with organic acids, of NH 4 + , alkali metals, alkaline earth metals or metals.

6. The method according to claim 2 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is a salt of NH 4 + , Na, K, Li, Ag or Cu.

7. The method according to claim 1 , wherein the organic acid is selected from acetic acid, formic acid, butyric acid, propionic acid, oxalic acid and lactic acid.

8. The method according to claim 7 , wherein the pH is adjusted using the acid to below 3.

9. The method according to claim 7 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is selected from inorganic salts, complexes and salts formed with organic acids, of NH 4 + , alkali metals, alkaline earth metals or metals.

10. The method according to claim 7 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is a salt of NH 4 + , Na, K, Li, Ag or Cu.

11. The method according to claim 1 , wherein the pH is adjusted using the acid to below 3.

12. The method according to claim 1 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is selected from inorganic salts, complexes and salts formed with organic acids, of NH 4 + , alkali metals, alkaline earth metals or metals.

13. The method according to claim 1 , wherein the water soluble salt of NH 4 + , alkali metal, alkaline earth metal or metal is a salt of NH 4 + , Na, K, Li, Ag or Cu.

14. The method according to claim 1 , wherein the water soluble salt of alkali metal, alkaline earth metal or metal is NaHCO 3 , KNO 3 or AgNO 3 .

15. The method according to claim 1 , wherein the inorganic base is selected from NaOH, KOH, LiOH or NH 3 .

16. The method according to claim 1 , wherein the pH of the suspension is adjusted with the inorganic base to the range from 8 to 9.

17. The method according to claim 1 , wherein the mechanical disintegration comprises a pregrinding step.

18. The method according to claim 1 , wherein the mechanical disintegration is carried out from 1 to 10 passes.

19. The method of claim 1 , wherein the mechanical disintegrating occurs in a fluidizer type disintegrator.

20. The method of claim 1 , wherein the pretreatment provides the nanofibrillated cellulose with gelling properties.

Assignees

• Upm Kymmene Corp

Inventors

• Nuopponen Markus
• Osterberg Monika
• Laine Janne
• Pere Jaakko

Classifications

• D21H11/16

  modified by a particular after-treatment · CPC title

• D21H11/18

  Highly hydrated, swollen or fibrillatable fibres · CPC title

• D21H11/10

  Mixtures of chemical and mechanical pulp · CPC title

• D21B1/16 Primary

  in the presence of chemical agents · CPC title

• D21H17/65

  Acid compounds · CPC title