Resin composition and optical compensation film formed using the same

Patent metadata

Field	Value
Publication number	US-9315659-B2
Application number	US-201214119162-A
Country	US
Kind code	B2
Filing date	Oct 4, 2012
Priority date	Oct 4, 2011
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

There are provided a resin composition and an optical compensation film formed using the same, and more particularly, to a resin composition comprising (a) alkyl (meth)acrylate units, (b) styrene units, (c) 3 to 6 element heterocyclic units substituted with at least one carbonyl group and (d) vinyl cyanide units, and an optical film formed using the resin composition. Further, a resin composition according to the present invention can provide an optical film having excellent optical properties and superior optical transparency, less haze and superior mechanical strength and heat resistance simultaneously. Therefore, an optical film formed using a resin composition of the present invention can be used in various applications, e.g., electronic information devices such as display devices. Particularly, the optical film is suitable for a compensation film used in the IPS mode.

First claim

The invention claimed is:

1. A resin composition comprising a combination of (A) a 2 member copolymer consisting of 80 to 97 weight parts of (a) alkyl (meth)acrylate units and 3 to 20 weight parts of (c) 3 to 6 heterocyclic units substituted with at least one carbonyl group with respect to 100 weight parts of the copolymer (A), and (B) a 2 member copolymer consisting of 50 to 99 weight parts of (b) styrene units and 1 to 50 weight parts of (d) vinyl cyanide units with respect to 100 weight parts of the copolymer (B);
wherein the (c) 3 to 6 heterocyclic units substituted with at least one carbonyl group are selected from the group consisting of maleimide and lactam;
wherein the resin composition further comprises a phenoxy-based resin, and wherein the phenoxy based resin includes 5 to 10,000 of at least one unit represented by the following formula 1:

2. The resin composition of claim 1 , wherein the (a) alkyl (meth)acrylate units have alkyl moieties that are methyl groups or ethyl groups.

3. The resin composition of claim 1 , wherein the (b) styrene units are one or more selected from the group consisting of styrene in which benzene ring or vinyl groups of styrene are substituted with one or more substituents selected from groups consisting of C1-4 alkyl and halogen groups.

4. The resin composition of claim 1 , wherein the (b) styrene units are one or more selected from the group consisting of α-methyl styrene, p-bromo styrene, p-methyl styrene, and p-chloro styrene.

5. The resin composition of claim 1 , wherein the (d) vinyl cyanide units are selected from the group consisting of methacrylonitrile-and acrylonitrile.

6. The resin composition of claim 1 , wherein the phenoxy based resin is mixed in the amount of 1 to 5 weight parts with respect to 100 weight parts of the total resin composition.

7. The resin composition of claim 1 , wherein the copolymer (A) comprises 85 to 95 weight parts of (a) alkyl (meth)acrylate units and 5 to 15 weight parts of (c) 3 to 6 heterocyclic units substituted with at least one carbonyl group with respect to 100 weight parts of the copolymer (A).

8. The resin composition of claim 1 , wherein the copolymer (B) comprises 65 to 95 weight parts of (b) styrene units and 5 to 35 weight parts of (d) vinyl cyanide units with respect to 100 weight parts of the copolymer (B).

9. The resin composition of claim 1 , wherein the copolymer (B) comprises 70 to 90 weight parts of (b) styrene units and 10 to 30 weight parts of (d) vinyl cyanide units with respect to 100 weight parts of the copolymer (B).

10. The resin composition of claim 1 , wherein the copolymer (A) and the copolymer (B) are mixed to a weight ratio of 70:30 to 90:10.

11. The resin composition of claim 1 , wherein the resin composition is a compounding resin.

12. An optical film formed using a resin composition of claim 1 .

13. The optical film of claim 12 , wherein the optical film has −50 nm to −250 nm of a thickness-directional retardation value (Rth) represented by the following Equation 1 under light having a wavelength of 550 nm:
R th =[( n x +n y )/2 −n z ]]× d   [Equation 1]

wherein n x is a refractive index in a direction at which the refractive index is highest in the plane direction of the film, n y is a refractive index of a direction perpendicular in regard to the n x direction in the plane direction of the film, n Z is a thickness-directional refractive index of the film, and d is thickness of the film.

14. The optical film of claim 12 , wherein the optical film has 50 nm to 200 nm of a plane-directional retardation value (Rin) represented by the following Equation 2 under light having a wavelength of 550 nm:
R in =( n x −n y )× d   [Equation 2]

wherein n x is a refractive index in a direction at which the refractive index is highest in the plane direction of the film, n y is a refractive index of a direction perpendicular in regard to the n x direction in the plane direction of the film, n Z is a thickness-directional refractive index of the film, and d is thickness of the film.

15. The optical film of claim 12 , wherein the optical film has 0.4 to 1.5 of an absolute value of the ratio (R in /R th ) of the plane-directional retardation value represented by the following Equation 2 to the thickness-directional retardation value represented by the following Equation 1 under light having a wavelength of 550 nm:
R th =[( n x +n y )/2 −n z ]]× d   [Equation 1]

R in =( n x −n y )× d   [Equation 2]

wherein n x is a refractive index in a direction at which the refractive index is highest in the plane direction of the film, n y is a refractive index of a direction perpendicular in regard to the n x direction in the plane direction of the film, n z is a thickness-directional refractive index of the film, and d is thickness of the film.

16. The optical film of claim 12 , wherein the optical film is a retardation film for in-plane switching (IPS) mode LCD devices.

Assignees

• Lg Chemical Ltd

Inventors

• Um Jun-Geun
• Choi Jeong-Min
• Park Jun-Wuk
• Lee Nam-Jeong

Classifications

• C08L35/06

  Copolymers with vinyl aromatic monomers · CPC title

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08L71/12

  Polyphenylene oxides · CPC title

• C08L35/04

  Homopolymers or copolymers of nitriles (C08L35/06, C08L35/08 take precedence) · CPC title

• C08L2203/16

  used for films · CPC title