Solid catalyst component for olefin polymerization, and catalyst

Patent metadata

Field	Value
Publication number	US-9315601-B2
Application number	US-201214130799-A
Country	US
Kind code	B2
Filing date	May 31, 2012
Priority date	Jul 4, 2011
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

A solid catalyst component for olefin polymerization and a catalyst are disclosed that exhibit high catalytic activity when used for gas-phase polymerization, suppress rapid reactions in the initial stage of polymerization relative to the polymerization activity, and can produce a propylene polymer in high yield while maintaining high stereoregularity. The solid catalyst component for olefin polymerization includes magnesium, titanium, a halogen, and an internal electron donor, the solid catalyst component including an asymmetrical phthalic diester represented by the following general formula (1) in a molar ratio of 0.2 to 0.8 relative to the total content of the internal electron donor.

R 1 k (C 6 H 4-k )(COOR 2 )(COOR 3 )  (1)

wherein R 1 is an alkyl group or the like, R 2 is a linear or branched alkyl group having 2 to 6 carbon atoms or an alkenyl group, R 3 is a linear or branched alkyl group having 1 to 5 carbon atoms, the number of carbon atoms included in R 3 being smaller than the number of carbon atoms included in R 2 , and k is an integer from 0 to 4 that indicates the number of substituents R 1 .

First claim

The invention claimed is:

1. A solid catalyst component for olefin polymerization, comprising:
magnesium;
titanium;
a halogen; and
an internal electron donor,
wherein the internal electron donor comprises an asymmetrical phthalic diester represented by formula (1) in a molar ratio of 0.2 to 0.8 relative to a total content of the internal electron donor,
R 1 k (C 6 H 4-k )(COOR 2 )(COOR 3 )  (1)

where R 1 is a halogen atom or an alkyl group having 1 to 20 carbon atoms, R 2 is a linear or branched alkyl group having 2 to 6 carbon atoms, or an alkenyl group, R 3 is a linear or branched alkyl group having 1 to 5 carbon atoms, the number of carbon atoms included in R 3 is smaller than the number of carbon atoms included in R 2 , and k is an integer from 0 to 4.

2. The solid catalyst component according to claim 1 , wherein the internal electron donor further comprises at least one of a phthalic diester represented by formula (2) and a phthalic diester represented by formula (3),
R 4 m (C 6 H 4-m )(COOR 2 ) 2   (2)

where each R 2 is a linear or branched alkyl group having 2 to 6 carbon atoms, or an alkenyl group and is identical to each other, R 4 is a halogen atom or an alkyl group having 1 to 20 carbon atoms, and m is an integer from 0 to 4,
R 5 n (C 6 H 4-n )(COOR 3 ) 2   (3)

where each R 3 is linear or branched alkyl group having 1 to 5 carbon atoms and is identical to each other, R 5 is a halogen atom or an alkyl group having 1 to 20 carbon atoms, and n is an integer from 0 to 4.

3. An olefin polymerization catalyst, comprising:
the solid catalyst component according to claim 1 ;
an organoaluminum compound represented by formula (4),
R 6 p ALQ 3-p   (4)

wherein R 6 is an alkyl group having 1 to 4 carbon atoms, Q is a hydrogen atom or a halogen atom, and p is an integer that satisfies 0<p≦3; and
an external electron donor compound.

4. The olefin polymerization catalyst according to claim 3 , wherein the external electron donor compound is an organosilicon compound represented by formula (5),
R 7 q Si(OR 8 ) 4-q   (5)

where R 7 is an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group, or an aralkyl group, a plurality of R 7 , if present, are either identical or different, R 8 is an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group, or an aralkyl group, a plurality of R 8 , if present, are either identical or different, and q is an integer from 0 to 4.

5. An olefin polymerization catalyst, comprising:
the solid catalyst component according to claim 2 ;
an organoaluminum compound represented by formula (4),
R 6 p AlQ 3-p   (4)

where R 6 is an alkyl group having 1 to 4 carbon atoms, Q is a hydrogen atom or a halogen atom, and p is an integer that satisfies 0<p ≦3; and
an external electron donor compound.

6. The olefin polymerization catalyst according to claim 5 , wherein the external electron donor compound is an organosilicon compound represented by formula (5),
R 7 q Si(OR 8 ) 4-q   (5)

where R 7 is an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group, or an aralkyl group, a plurality of R 7 , if present, are either identical or different, R 8 is an alkyl group having 1 to 4 carbon atoms, a cycloalkyl group, a phenyl group, a vinyl group, an allyl group, or an aralkyl group, a plurality of R 8 , if present, are either identical or different, and q is an integer from 0 to 4.

7. The solid catalyst component according to claim 2 , wherein the internal electron donor further comprises the phthalic diester represented by formula (2) and the phthalic diester represented by formula (3).

8. The solid catalyst component according to claim 1 , wherein the internal electron donor comprises the asymmetrical phthalic diester represented by formula (1) in the molar ratio of 0.3 to 0.8 relative to the total content of the internal electron donor.

9. The solid catalyst component according to claim 1 , wherein the internal electron donor comprises the asymmetrical phthalic diester represented by formula (1) in the molar ratio of 0.45 to 0.7 relative to the total content of the internal electron donor.

10. The solid catalyst component according to claim 1 , wherein the magnesium is included in an amount of 10 to 30 wt %, the titanium is included in an amount of 1 to 8 wt %, the halogen is included in an amount of 45 to 70 wt %, and the internal electron donor is included in an amount of 2 to 25 wt %.

11. The solid catalyst component according to claim 1 , wherein the magnesium is included in an amount of 15 to 25 wt %, the titanium is included in an amount of 2 to 4 wt %, the halogen is included in an amount of 55 to 65 wt %, and the internal electron donor is included in an amount of 5 to 20 wt %.

Assignees

• Tashino Kunihiko
• Fujita Takashi
• Uozumi Toshiya
• HAGA Yuta
• Toho Titanium Co Ltd

Inventors

• Tashino Kunihiko
• Fujita Takashi
• Uozumi Toshiya
• HAGA Yuta

Classifications

• C08F4/6465

  containing silicium · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F4/6548

  magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546 · CPC title