Catalysts for the production of hydroxy ether hydrocarbons by vapor phase hydrogenolysis of cyclic acetals and ketals
US-9056313-B2 · Jun 16, 2015 · US
US9315485B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9315485-B2 |
| Application number | US-201414459875-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 14, 2014 |
| Priority date | Jun 24, 2011 |
| Publication date | Apr 19, 2016 |
| Grant date | Apr 19, 2016 |
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Cyclic acetals can be produced in a reactive distillation apparatus by combining a polyhydroxyl compound and an aldehyde. High concentrations of cyclic acetals are removed as liquid products from the column while water is removed as an overhead vapor stream.
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What we claim is: 1. A liquid composition comprising water in an amount from 0 to 8 mole %, aldehyde compounds in an amount from 0 to 5 mole %, cyclic acetal compounds in an amount from 25 mole % to 75 mole %, polyhydroxyl compounds in an amount from 25 mole % to 75 mole %, and a catalyst in an amount from 0-0.5 mole %, wherein the stated mole percentages are based on the moles of all ingredients within the liquid composition. 2. A liquid composition comprising water in an amount from 0 to 0.5 mole %, aldehyde compounds in an amount from 0 to 0.25 mole %, cyclic acetal compounds in an amount from 50 mole % to 60 mole %, polyhydroxyl compounds in an amount from 40 mole % to 50 mole %, and catalyst in an amount from 0-0.1 mole %, wherein the stated mole percentages are based on the moles of all ingredients within the liquid composition. 3. The composition according to claim 1 , which comprises water in an amount of 0 to 3 mole %. 4. The composition according to claim 1 , which comprises aldehyde compounds in an amount of 0 to 2 mole %.
with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms · CPC title
not condensed with other rings · CPC title
Process efficiency · CPC title
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