Plated steel sheet having plated layer with excellent stability for hot press molding

Patent metadata

Field	Value
Publication number	US-9314997-B2
Application number	US-201214127350-A
Country	US
Kind code	B2
Filing date	Jun 28, 2012
Priority date	Jun 28, 2011
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

The present invention relates to a plated steel sheet having a plated layer with excellent stability for hot press molding, and more specifically, to a plated steel sheet having a plated layer with excellent stability for hot press molding in which a LME (Liquid Metal Embrittlement) phenomenon caused by a zinc enrichment region included in the plated layer is suppressed during hot press molding.

First claim

The invention claimed is:

1. A plated steel sheet for hot press forming, comprising:
a base steel sheet;
an aluminum (Al)-rich layer formed above the base steel sheet and comprising 30% or more of Al; and
a zinc plating layer formed on the Al-rich layer,
wherein grains of the Al-rich layer comprise fifteen or fewer grains having a grain size of 500 nm or greater per 100 μm 2 on average, and an area percentage of the Al-rich layer between the base steel sheet and the zinc plating layer is 88% or greater; and
wherein the base steel sheet comprises a surface diffusion layer of a metal to a depth of 1 μm or less from a surface thereof, the metal releasing a smaller amount of Gibbs free energy than chromium (Cr) per mole of oxygen during an oxidation reaction.

2. The plated steel sheet for hot press forming of claim 1 , wherein the Al-rich layer has a thickness of 0.1 μm to 1.0 μm.

3. The plated steel sheet for hot press forming of claim 1 , wherein the area percentage of the Al-rich layer between the base steel sheet and the zinc plating layer is 95% or greater.

4. The plated steel sheet for hot press forming of claim 1 , wherein if the plated steel sheet is heated to 900° C., 90 vol % or more of the zinc plating layer comprises 25 wt % to 35 wt % of zinc (Zn).

5. The plated steel sheet for hot press forming of claim 4 , wherein at a temperature of 750° C., the zinc plating layer comprises an iron (Fe)-rich region having a Zn content of 40 wt % or less and a Zn-rich region having a Zn content of greater than 40 wt %.

6. The plated steel sheet for hot press forming of claim 5 , wherein at a temperature of 750° C., the zinc plating layer comprises an Fe-rich region having a Zn content of 30 wt % to 40 wt % and a Zn-rich region having a Zn content of 60 wt % to 90 wt %.

7. The plated steel sheet for hot press forming of claim 1 , wherein the metal, releasing a smaller amount of Gibbs free energy than Cr per mole of oxygen during an oxidation reaction, comprises at least one selected from nickel (Ni), Fe, cobalt (Co), copper (Cu), tin (Sn), and antimony (Sb).

8. The plated steel sheet for hot press forming of claim 1 , wherein the zinc plating layer comprises 15 wt % or less of Fe.

9. The plated steel sheet for hot press forming of claim 1 , wherein the zinc plating layer comprises, Fe: 15.0% or less, the metal releasing a smaller amount of Gibbs free energy than Cr per mole of oxygen during an oxidation reaction: 0.01 wt % to 2.0 wt %, the balance of Zn and inevitable impurities.

10. The plated steel sheet for hot press forming of claim 1 , wherein an annealing oxide formed on the base steel sheet has a thickness of 150 nm or less.

11. The plated steel sheet for hot press forming of claim 1 , wherein the base steel sheet comprises, by wt %, carbon (C): 0.1% to 0.4%, silicon (Si): 2.0% or less (excluding 0%), manganese (Mn): 0.1% to 4.0%, and the balance of Fe and inevitable impurities.

12. The plated steel sheet for hot press forming of claim 11 , wherein the base steel sheet further comprises at least one selected from the group consisting of nitrogen (N): 0.001% to 0.02%, boron (B): 0.0001% to 0.01%, titanium (Ti): 0.001% to 0.1%, niobium (Nb): 0.001% to 0.1%, vanadium (V): 0.001% to 0.1%, Cr: 0.001% to 1.0%, molybdenum (Mo): 0.001% to 1.0%, Sb: 0.001% to 0.1%, and tungsten (W): 0.001% to 0.3%.

13. The plated steel sheet for hot press forming of claim 1 , wherein the metal is nickel (Ni).

Assignees

• Sohn Il-Ryoung
• Posco

Inventors

• Sohn Il-Ryoung

Classifications

• C22C38/002

  containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60 · CPC title

• B32B15/013 Primary

  one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium · CPC title

• C23C2/02

  Pretreatment of the material to be coated, e.g. for coating on selected surface areas (C23C2/30 takes precedence) · CPC title

• B32B15/012

  one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy · CPC title

• Y10T428/12757

  Fe · CPC title