Platinum and palladium alloys suitable as fuel cell electrodes

US9312545B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-9312545-B2
Application numberUS-201013383512-A
CountryUS
Kind codeB2
Filing dateJul 16, 2010
Priority dateJul 17, 2009
Publication dateApr 12, 2016
Grant dateApr 12, 2016

How to read this patent

A practical reading order for non-experts. Skip the full description unless you need deep technical detail.

  1. Title

    What the patent document calls the invention.

  2. Abstract

    A short plain-language summary of the technical disclosure.

  3. Assignees and inventors

    Who owns or filed the patent and who is credited as inventor.

  4. Key dates

    Filing, priority, publication, and grant dates set the timeline.

  5. First independent claim

    The legal scope of protection — read this for what is actually claimed.

  6. CPC / IPC classifications

    Technology tags used to group this patent with similar filings.

  7. Citations and related patents

    Prior art links and similar publications in this corpus.

Abstract

Official abstract text for this publication.

The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic efficiency by low level substitution of the noble metal to provide new and innovative catalyst compositions in fuel cell electrodes. The novel electrode catalysts of the invention comprise a noble metal selected from Pt, Pd and mixtures thereof alloyed with a further element selected from Sc, Y and La as well as any mixtures thereof, wherein said alloy is supported on a conductive support material.

First claim

Opening claim text (preview).

The invention claimed is: 1. An electrode comprising an Pt 3 Y alloy wherein said alloy is supported on an electrically conductive support material, wherein said electrode does not also contain 0.1% to 20% by weight of one or more metals selected from the group consisting of molybdenum, tantalum and tungsten, and 0.5% to 25% by weight of one or more elements selected from the group consisting of barium, strontium, and calcium. 2. The electrode according to claim 1 , wherein said alloy comprises at least 70% by weight intermetallic compound. 3. An electrochemical cell comprising the electrode according to claim 1 and an electrolyte, wherein said electrochemical cell is a fuel cell. 4. The electrochemical cell according to claim 3 , wherein said electrode is the cathode. 5. The electrochemical cell according to claim 3 , wherein the alloy of the electrode contains a noble metal skin on the surface. 6. The electrochemical cell according to claim 3 , wherein the electrolyte is an ion conducting membrane. 7. An electrode comprising a Pt 3 Y alloy, wherein said alloy is supported on an electrically conductive support material, wherein said electrode does not also contain 0.1% to 20% by weight of one or more metals selected from the group consisting of molybdenum, tantalum and tungsten, and 0.5% to 25% by weight of one or more elements selected from the group consisting of barium, strontium, and calcium, and, wherein said alloy is crystalline. 8. The electrode according to claim 7 , wherein said alloy comprises at least 70% by weight an intermetallic compound. 9. An electrochemical cell comprising the electrode according to claim 7 and an electrolyte, wherein said electrochemical cell is a fuel cell. 10. An electrode comprising a Pt 5 La alloy, wherein said alloy is supported on an electrically conductive support material, wherein said electrode does not also contain 0.1% to 20% by weight of one or more metals selected from the group consisting of molybdenum, tantalum and tungsten, and 0.5% to 25% by weight of one or more elements selected from the group consisting of barium, strontium, and calcium. 11. The electrode according to claim 10 , wherein said alloy comprises at least 70% by weight intermetallic compound. 12. An electrochemical cell comprising the electrode according to claim 10 and an electrolyte, wherein said electrochemical cell is a fuel cell. 13. The electrochemical cell according to claim 12 , wherein said electrode is the cathode. 14. The electrochemical cell according to claim 12 , wherein the alloy of the electrode contains a noble metal skin on the surface. 15. The electrochemical cell according to claim 12 , wherein the electrolyte is an ion conducting membrane. 16. An electrode comprising a Pt 5 Y alloy, wherein said alloy of said electrode is supported on an electrically conductive support material. 17. The electrode according to claim 16 , wherein said alloy comprises at least 70% by weight intermetallic compound. 18. An electrochemical cell comprising the electrode according to claim 16 and an electrolyte, wherein said electrochemical cell is a fuel cell. 19. The electrochemical cell according to claim 18 , wherein said electrode is the cathode. 20. The electrochemical cell according to claim 18 , wherein the alloy of the electrode contains a noble metal skin on the surface. 21. The electrochemical cell according to claim 18 , wherein the electrolyte is an ion conducting membrane. 22. An electrode comprising a Pt 5 La alloy, wherein said alloy is supported on an electrically conductive support material, wherein said electrode does not also contain 0.1% to 20% by weight of one or more metals selected from the group consisting of molybdenum, tantalum and tungsten, and 0.5% to 25% by weight of one or more elements selected from the group consisting of barium, strontium, and calcium, and, wherein said alloy is crystalline. 23. The electrode according to claim 22 , wherein said alloy comprises at least 70% by weight an intermetallic compound. 24. An electrochemical cell comprising the electrode according to claim 22 and an electrolyte, wherein said electrochemical cell is a fuel cell. 25. An electrode comprising a Pt 5 Y alloy, wherein said alloy of said electrode is supported on an electrically conductive support material, and, wherein said alloy is crystalline. 26. The electrode according to claim 25 , wherein said alloy comprises at least 70% by weight an intermetallic compound. 27. An electrochemical cell comprising the electrode according to claim 25 and an electrolyte, wherein said electrochemical cell is a fuel cell.

Assignees

Inventors

Classifications

  • on carbon or graphite · CPC title

  • Fuel cells · CPC title

  • H01M4/86Primary

    Inert electrodes with catalytic activity, e.g. for fuel cells · CPC title

  • Fuel cells with polymeric electrolytes · CPC title

  • H01M4/921Primary

    Alloys or mixtures with metallic elements · CPC title

Patent family

Related publications grouped by family.

External sources

Frequently asked questions

Answers are generated from the same data shown on this page.

What does patent US9312545B2 cover?
The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic efficiency by low level substitution of the noble metal to provide new and innovative catalyst compositions in fuel cell electrodes. The novel electrode catalysts of the…
Who is the assignee on this patent?
Nørskov Jens, Greeley Jeffrey, Stephens Ifan, and 7 more
What technology area does this patent fall under?
Primary CPC classification H01M4/86. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Apr 12 2016 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).