Fuel cell

Patent metadata

Field	Value
Publication number	US-9312543-B2
Application number	US-201213354977-A
Country	US
Kind code	B2
Filing date	Jan 20, 2012
Priority date	Jul 21, 2009
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

In one embodiment, in a fuel cell, a first electrode supplied with an oxidant gas includes a first gas diffusion layer having a first porous base material and a first catalyst layer having a second porous base material. The first catalyst layer is stacked to the first gas diffusion layer. The second porous base material has a pore diameter distribution with a peak in a range of 0.04 μm to 0.12 μm, and a volume ratio of pores with diameters of 0.04 μm to 0.12 μm to all the pores being 17% or more. A second electrode supplied with a fuel includes a second gas diffusion layer having a third porous base material and a second catalyst layer having a fourth porous base material. The second catalyst layer is stacked to the second gas diffusion layer. An electrolyte film is held between the first and second catalyst layers.

First claim

What is claimed is:

1. A fuel cell comprising:
a first electrode including a first gas diffusion layer having a first porous base material and a first catalyst layer having a second porous base material, the first electrode being supplied with an oxidant gas, the first catalyst layer being stacked to the first gas diffusion layer, the second porous base material containing a catalyst-activating material, an electrically-conductive material, and a proton-conductive material, the second porous base material having a pore diameter distribution with a first peak in a range of 0.04 μm to 0.12 μm, both inclusive, and a second peak in a range of 0.02 μm to 0.04 μm, both inclusive, the second porous base material having a volume ratio of pores with diameters of 0.04 μm to 0.12 μm, both inclusive, to all the pores being 17% or more, and the second porous base material having a total volume of the pores with diameters of not less than 0.1 μm being not more than 0.01 mL/g, the total volume being measured by a mercury penetration method;
a second electrode including a second gas diffusion layer having a third porous base material and a second catalyst layer having a fourth porous base material, the second electrode being supplied with a fuel, the second catalyst layer being stacked to the second gas diffusion layer; and
an electrolyte film held between the first catalyst layer of the first electrode and the second catalyst layer of the second electrode,
wherein the catalyst-activating material includes catalysts that are only particles, and
the first catalyst layer does not substantially include a fibrous supported catalyst.

2. The fuel cell of claim 1 , further comprising a micro-porous layer between the first gas diffusion layer and the first catalyst layer, the micro-porous layer including a mixture of carbon powder and a ate repellent agent.

3. The fuel cell of claim 1 , wherein
the pore diameter distribution has a peak in a range of 0.06 μm to 0.12 μm, both inclusive.

4. The fuel cell of claim 1 , wherein
a dimension change of the first catalyst layer under application of a compression load of 160 N/cm 2 is not greater than 10%.

5. The fuel cell of claim 1 , wherein the second peak is in a range of 0.03 μm to 0.04 μm, both inclusive.

6. The fuel cell of claim 1 , wherein the volume ratio of pores with diameters of 0.04 μm to 0.12 μm, both inclusive, is below 50%.

7. The fuel cell of claim 1 , wherein the volume ratio of pores with diameters of 0.04 μm to 0.12 μm, both inclusive, is equal to or below 35%.

8. The fuel cell of claim 1 , wherein a value of differential intrusion at the first peak is larger than a value of differential intrusion at the second peak.

9. The fuel cell of claim 1 , wherein the second porous base material is subjected to heat treatment at a temperature more than about 160° C.

10. A fuel cell comprising:
a first electrode including a first gas diffusion layer having a first porous base material and a first catalyst layer having a second porous base material, the first electrode being supplied with an oxidant gas, the first catalyst layer being stacked to the first gas diffusion layer, the second porous base material containing a catalyst-activating material, an electrically-conductive material, and a proton-conductive material, the second porous base material having a pore diameter distribution with a first peak in a range of 0.04 μm to 0.12 μm, both inclusive, and a second peak in a range of 0.02 μm to 0.04 μm, both inclusive, the second porous base material having a volume ratio of pores with diameters of 0.04 μm to 0.12 μm, both inclusive, to all the pores being 17% or more, and the second porous base material having a volume of the pore with diameter of 0.1 μm being not more than 0.01 mL/g, the volume being measured by a mercury penetration method;
a second electrode including a second gas diffusion layer having a third porous base material and a second catalyst layer having a fourth porous base material, the second electrode being supplied with a fuel, the second catalyst layer being stacked to the second gas diffusion layer; and
an electrolyte film held between the first catalyst layer of the first electrode and the second catalyst layer of the second electrode,
wherein the catalyst-activating material includes catalysts that are only particles, and the first catalyst layer does not substantially include a fibrous supported catalyst.

11. The fuel cell of claim 10 , wherein the second porous base material is subjected to heat treatment at a temperature more than about 160° C.

Assignees

• Akasaka Yoshihiro
• Akita Masato
• Yagi Ryosuke
• Toshiba Kk

Inventors

• Akasaka Yoshihiro
• Akita Masato
• Yagi Ryosuke

Classifications

• H01M8/1004

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• Y02E60/521

  Cross-Sectional Technologies · mapped topic

• H01M8/0245

  in the form of layered or coated products · CPC title

• H01M4/861 Primary

  with a gradient in the porosity · CPC title

• Y02E60/50

  Fuel cells · CPC title