Thermoplastic vulcanizate composition, method of producing the same, and articles made therefrom

Patent metadata

Field	Value
Publication number	US-9309396-B2
Application number	US-201013991531-A
Country	US
Kind code	B2
Filing date	Dec 30, 2010
Priority date	Dec 30, 2010
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

A thermoplastic vulcanizate composition comprising from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a first component comprising a first propylene-based polymer selected from the group consisting of (i) propylene/α-olefin copolymers comprising from 1 to 20 wt % α-olefin and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5, and (ii) combinations thereof; and from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a second component selected from the group consisting of curable or vulcanizable rubbers, having a density from 0.85 to 0.88 g/cc, I 2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400, and combinations thereof; wherein at least one of the rubbers is vulcanizable; wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in. is provided. Methods of making the composition and articles made from the composition are also provided.

First claim

We claim:

1. A thermoplastic vulcanizate composition consisting of:
from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a propylene/α-olefin copolymer comprising from 1 to 20 percent by weight of units derived from α-olefin and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5;
from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of an ethylene-propylene-diene-rubber having a density from 0.85 to 0.88 g/cc, I 2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400, and combinations thereof; and
optionally, one or more additives selected from the group consisting of, colored pigments, stabilizers, antidegradants, flame retardants, processing aids, adhesives, tackifiers, plasticizers, waxes, and discontinuous fibers
wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in.

2. The thermoplastic vulcanizate composition according to claim 1 , further comprising one or more fillers.

3. A process for making a thermoplastic vulcanizate composition consisting of first and second components, the process comprising:
selecting a first component consisting of propylene/α-olefin copolymer comprising from 1 to 20 percent by weight of units derived from α-olefin and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5;
selecting a second component consisting of an ethylene-propylene-diene-rubber having a density from 0.85 to 0.88 g/cc, I 2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400; and
mixing the first and second components under dynamic vulcanization conditions to form the thermoplastic vulcanizate composition;
wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in.

4. An article comprised of one or more thermoplastic vulcanizate compositions of claim 1 .

5. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer has a g′ ratio of less than 0.85, measured at interpolymer number average molecular weight (Mn).

6. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer has a g′ ratio of less than 0.80, measured at interpolymer number average molecular weight (Mn).

7. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer comprises at least 80 weight percent (wt %) units derived from propylene, and between 1 and 20 wt % units derived from ethylene.

8. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer is characterized by a relative compositional drift of less than 50%.

9. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer is characterized by a relative compositional drift of less than 40%.

10. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer is characterized by a propylene chain segments having a chain isotacticity triad index of at least 70 mole percent.

11. The thermoplastic vulcanizate composition according to claim 1 wherein the propylene/α-olefin copolymer is characterized by a propylene chain segments having a chain isotacticity triad index of at least 80 mole percent.

12. A thermoplastic vulcanizate composition consisting of:
from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of a propylene/ethylene copolymer comprising from 1 to 20 percent by weight of units derived from ethylene and characterized by a g′ ratio of less than 1, measured at interpolymer number average molecular weight (Mn), an MFR (2.16 kg @ 230° C.) greater than or equal to 0.01, a density greater than or equal to 0.850 g/cc, and a molecular weight distribution, Mw/Mn, less than or equal to 3.5;
from 5 wt % to 95 wt %, based on the total weight of the thermoplastic vulcanizate composition, of an ethylene-propylene-diene-rubber having a density from 0.85 to 0.88 g/cc, I 2 from 0.001 to 5 g/10 min, and a Mooney viscosity from 5 to 400, and combinations thereof; and
optionally, one or more additives selected from the group consisting of, colored pigments, stabilizers, antidegradants, flame retardants, processing aids, adhesives, tackifiers, plasticizers, waxes, and discontinuous fibers;
wherein the thermoplastic vulcanizate composition has a tensile strength at break of greater than or equal to 8 MPa and tear strength at 23° C. of at least 190 lb-f/in.

Assignees

• Sun Yabin
• Hughes Morgan M
• Tai Xiangyang
• Paeglis Arnis U
• Marchand Gary R
• Dow Global Technologies Llc

Inventors

• Sun Yabin
• Hughes Morgan M
• Tai Xiangyang
• Paeglis Arnis U
• Marchand Gary R

Classifications

• C08K5/0025

  Crosslinking or vulcanising agents; including accelerators · CPC title

• C08L23/16 Primary

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L23/26 Primary

  modified by chemical after-treatment (saponified copolymers C08L23/0861; unsaturated acid salts C08L23/0876) · CPC title

• C08L2312/00

  Crosslinking · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title