Method for producing alkali metal nitride or alkaline earth metal nitride

Patent metadata

Field	Value
Publication number	US-9309120-B2
Application number	US-201013509457-A
Country	US
Kind code	B2
Filing date	Nov 11, 2010
Priority date	Nov 12, 2009
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

There is provided a method for efficiently producing a high-purity alkali metal nitride or alkaline earth metal nitride by simple processes.
Specifically provided is a method for producing an alkali metal nitride, an alkaline earth metal nitride, or a composite thereof, the method including thermally decomposing one or more alkali metal amides or alkaline earth metal amides.

First claim

The invention claimed is:

1. A method for producing a metal nitride, the method comprising:
(i) thermally decomposing a mixture of at least two alkali metal amides at a temperature of 300° C. to 700° C. for 1 hour to 24 hours under vacuum or under an inert gas to form a composite of at least two alkali metal nitrides;
(ii) thermally decomposing a mixture of at least two alkaline earth metal amides at a temperature of 800° C. to 1200° C. for 1 hour to 24 hours under vacuum or under an inert gas to form a composite of at least two alkaline earth metal nitrides.

2. The method according to claim 1 , wherein at least one of the alkali metal amides, at least one of the alkaline earth metal amides, or at least one of the alkali metal amides and at least one of the alkaline earth metal amides, is decomposed as a raw material.

3. The method according to claim 2 , wherein at least one of the alkali metal amides, at least one of the alkaline earth metal amides, or at least one of the alkali metal amides and at least one of the alkaline earth metal amides, is obtained by reacting an alkali metal or an alkaline earth metal with ammonia to form a liquid phase thereof.

4. The method according to claim 1 , wherein the mixture of at least two alkali metal amides is thermally decomposed to form the composite of at least two alkali metal nitrides.

5. The method according to claim 4 , wherein at least one of the alkali metal amides is decomposed as a raw material.

6. The method according to claim 4 , wherein at least one of the alkali metal amides is obtained by reacting an alkali metal with ammonia to form a liquid phase thereof.

7. The method according to claim 4 , wherein lithium amide is one of the alkali metal amides, and is thermally decomposed to form lithium nitride.

8. The method according to claim 1 , wherein the mixture of at least two alkaline earth metal amides is thermally decomposed to form the composite of at least two alkaline earth metal nitrides.

9. The method according to claim 1 , comprising thermally decomposing a mixture of at least two alkaline earth metal amides selected from the group consisting of calcium amide, strontium amide and barium amide, to form a composite of at least two alkaline earth metal nitrides selected from the group consisting of calcium nitride, strontium nitride and barium nitride.

10. A method for producing a metal nitride, the method comprising:
(i) thermally decomposing an alkali metal amide at a temperature of 300° C. to 700° C. for 1 hour to 24 hours under vacuum or under an inert gas to form an alkali metal nitride;
(ii) thermally decomposing an alkaline earth metal amide at a temperature of 800° C. to 1200° C. for 1 hour to 24 hours under vacuum or under an inert gas to form an alkaline earth metal nitride; or
(iii) thermally decomposing a mixture of at least two alkaline earth metal amides at a temperature of 800° C. to 1200° C. for 1 hour to 24 hours under vacuum or under an inert gas to form a composite of at least two alkaline earth metal nitrides,
wherein the alkali metal amide, the alkaline earth metal amide, or both, is obtained by reacting at least one of an alkali metal and an alkaline earth metal with ammonia to form a liquid phase thereof.

11. A method for producing a metal nitride, the method comprising thermally decomposing an alkaline earth metal amide at a temperature of 800° C. to 1200° C. for 1 hour to 24 hours under vacuum or under an inert gas to form an alkaline earth metal nitride.

12. The method according to claim 11 , wherein the alkaline earth metal amide is thermally decomposed as a raw material.

13. The method according to claim 11 , wherein the alkaline earth metal amide is obtained by reacting an alkaline earth metal with ammonia to form a liquid phase thereof.

14. The method according to claim 11 , comprising thermally decomposing at least one alkaline earth metal amide selected from the group consisting of calcium amide, strontium amide and barium amide, to form at least one alkaline earth metal nitride selected from the group consisting of calcium nitride, strontium nitride and barium nitride.

Assignees

• Suzuki Shoji
• Tokoyoda Kazuhiko
• Suzuki Tsutomu
• Taiheiyo Cement Corp

Inventors

• Suzuki Shoji
• Tokoyoda Kazuhiko
• Suzuki Tsutomu

Classifications

• C01B21/0612

  with alkaline-earth metals, beryllium or magnesium · CPC title

• C01B21/0607 Primary

  with alkali metals · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01B21/061

  with lithium · CPC title

• C01B21/0602

  with two or more other elements chosen from metals, silicon or boron · CPC title